[1]陈永康①②,陈明华②,张力①,等.用快速筛选仪研究发射药的热分解[J].爆破器材,2014,43(03):48-51.[doi:10.3969/j.issn.1001-8352.2014.03.011]
　CHEN Yongkang,CHEN Minghua,ZHANG Li,et al.Study on the Thermal Decomposition of Propellant Using Rapid Screening Device[J].EXPLOSIVE MATERIALS,2014,43(03):48-51.[doi:10.3969/j.issn.1001-8352.2014.03.011]
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用快速筛选仪研究发射药的热分解()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
43
期数:
2014年03
页码:
48-51
栏目:
出版日期:
2014-06-20

文章信息/Info

Title:
Study on the Thermal Decomposition of Propellant Using Rapid Screening Device
文章编号:
4714
作者:
陈永康①②; 陈明华②; 张力①; 贾昊楠①②; 于毅成③; 刘立④
①军械工程学院（河北石家庄，050000）
②军械技术研究所（河北石家庄，050000)
③哈尔滨军代室（黑龙江哈尔滨，150000）
④中国人民解放军68128部队（甘肃兰州，730046）
Author(s):
CHEN Yongkang①②; CHEN Minghua①; ZHANG Li①; JIA Haonan①②; YU Yicheng③; LIU Li④
①Ordnance Engineering College ( Hebei Shijiazhuang, 050000)
②Ordnance Technology Research Institute (Hebei Shijiazhuang, 050000)
③Haerbin Military Representative Office (Heilongjiang Haerbin,150000 )
④68128 Troops of PLA (Gansu Lanzhou, 730046)
关键词:
快速筛选仪; 发射药; 热分解; 热分析动力学
Keywords:
rapid screening device;  8/1 propellant;  GATo-3 propellant;  propellant;  thermal decomposition;  thermal analysis kinetics
分类号:
TQ562
DOI:
10.3969/j.issn.1001-8352.2014.03.011
文献标志码:
A
摘要:
文章采用了一种新的热分析仪器——快速筛选仪（RSD），来研究两种发射药改铵铜推进剂和单基8/1推进剂的热分解过程，分析所得数据得到相应的热分解特性参数以及热动力学参数，发现改铵铜的起始分解温度在150~168 ℃左右，而8/1在175~185 ℃左右。8/1单基药活化能E=238.30 kJ/mol，指前因子A=3.7×1017s-1；改铵铜推进剂活化能E=216.67kJ/mol，指前因子A=2.1×1017 s-1。
Abstract:
Rapid screening device (RSD), a new calorimeter, was used to test the thermal decomposition progress of GATo-3 propellant and 8/1 propellant. The thermal decomposition characteristic data and kinetic parameters obtained from RSD curves show that the initial decomposition temperature of GATo-3 is about 150～168 ℃, and that of 8/1 is about 175～185℃.The kinetic parameters of 8/1 are E=238.30 kJ/mol and A=3.7×1017s－1, while those of GATo-3 are E=216.67kJ/mol and A=2.1×1017 s－1 .

参考文献/References:

［1］郭洪. 利用加速量热仪(ARC)研究热分析动力学反应机理［J］. 曲靖师范学院学报, 2005，24(3): 1-3.
Guo Hong. Application of accelerating rate calorimeter(ARC)to the thermoanalytic study on dynamics mechanism［J］. Journal of Qujing Teachers College, 2005，24(3): 1-3.
［2］傅智敏. 绝热加速量热法在反应性物质热稳定性评价中的应用［D］. 北京:北京理工大学, 2002.
Fu Zhimin. Evaluating thermal stability for reactive chemical by accelerating rate calorimeter［D］. Beijing: Beijing Institute of Technology, 2002.
［3］王霁. 硝酸铵长期存放后热稳定性研究［J］. 科技导报,2012, 30(1): 60-64.
Wang Ji. Study on thermal characteristics of ammonium nitrate after longterm storage［J］. Science & Technology Review, 2012, 30(1): 60-64. 
［4］Matthias Wagner.热分析应用基础［M］. 陆立明,译.上海: 东华大学出版社, 2011.Matthias Wagner. Thermal Analysis in Practice［M］. Lu Liming, translate.Shanghai: Donghua University Press, 2011.
［5］谭惠平, 薛金根. DSC法研究高氯酸钾的催化热分解反应［J］. 中南林业科技大学学报, 2007, 27(3): 114-116.
 Tan Huiping, Xue Jingen. Catalyzed thermal decomposition of potassium perchlorate［J］. Journal of Central South University of Forestry and Technology, 2007, 27(3): 114-116.
［6］ 袁存光, 祝优珍, 田晶, 等. 现代仪器分析［M］. 北京: 化学工业出版社, 2012. 
Yuan Cunguang, Zhu Youzhen, Tian Jing, et al. Modern Instruments Analysis［M］. Beijing: Chemistry Industry Press, 2012.
［7］ 周霖. 爆炸化学基础［M］. 北京: 北京理工大学出版社, 2005.
 Zhou Lin. Base of explosive chemistry［M］. Beijing: Beijing Institute of Technology Press, 2005.
［8］ 徐抗震, 赵凤起, 杨冉, 等. GNTO的热分解动力学和比热容及绝热至爆时间研究［J］. 固体火箭技术, 2009, 32(1): 74-78. 
Xu Kangzhen, Zhao Fengqi, Yang Ran, et al. Nonisothermal decomposition kinetics, specific heat capacity and adiabatic timetoexplosive of GNTO［J］. Journal of Solid Rocket Technology, 2009, 32(1): 74-78.
［9］ You J S,Kang S C, Kweon S K, et al. Thermal decomposition kinetics of GAP ETPE/RDXbased solid propellant［J］. Thermochimica Acta, 2012, 537: 51-56.
［10］Hu Rongzu, Gao Hongxu, Zhao Fengqi,et al. Theory and numerical method of calculating the kinetic parameters of exothermic decomposition reaction of energetic materials from peak temperature of DSC curves at constant heating rates［J］. Chinese Journal of Energetic Materials,2009, 17(6): 643-649.
［11］Kissiger H E. Reaction kinetics in differential thermal analysis［J］. Analytical Chemistry, 1957, 29(11): 1702-1706.
［12］胡荣祖, 高胜利, 赵凤起. 热分析动力学［M］. 北京: 科学出版社, 2008.
Hu Rongzu, Gao Shengli, Zhao Fengqi. Thermal analysis kinetics［M］. Beijing: Science Press, 2008.
［13］刘子如, 阴翠梅, 刘艳, 等. RDX和HMX的热分解Ⅱ.动力学参数和动力学补偿效应［J］. 火炸药学报, 2004，27(4): 72-75.
 Liu Ziru, Yin Cuimei, Liu Yan, et al. Thermal decomposition of RDX and HMX part Ⅱ:kinetic parameters and kinetic compensation effects［J］. Chinese Journal of Explosives and Propellants, 2004，27(4): 72-75.

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备注/Memo

备注/Memo:
收稿日期：2013-10-12
作者简介：陈永康（1991~），男，硕士研究生，主要从事含能材料性能检测的研究。E-mail：sharpions@126.com
更新日期/Last Update: 2014-06-11