[1]陈永康①②,陈明华②,张力①,等.用快速筛选仪研究发射药的热分解[J].爆破器材,2014,43(03):48-51.[doi:10.3969/j.issn.1001-8352.2014.03.011]
　CHEN Yongkang,CHEN Minghua,ZHANG Li,et al.Study on the Thermal Decomposition of Propellant Using Rapid Screening Device[J].EXPLOSIVE MATERIALS,2014,43(03):48-51.[doi:10.3969/j.issn.1001-8352.2014.03.011]
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用快速筛选仪研究发射药的热分解()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
43
期数:
2014年03
页码:
48-51
栏目:
出版日期:
2014-06-20

文章信息/Info

Title:
Study on the Thermal Decomposition of Propellant Using Rapid Screening Device
文章编号:
4714
作者:
陈永康①②; 陈明华②; 张力①; 贾昊楠①②; 于毅成③; 刘立④
①军械工程学院（河北石家庄，050000）
②军械技术研究所（河北石家庄，050000)
③哈尔滨军代室（黑龙江哈尔滨，150000）
④中国人民解放军68128部队（甘肃兰州，730046）
Author(s):
CHEN Yongkang①②; CHEN Minghua①; ZHANG Li①; JIA Haonan①②; YU Yicheng③; LIU Li④
①Ordnance Engineering College ( Hebei Shijiazhuang, 050000)
②Ordnance Technology Research Institute (Hebei Shijiazhuang, 050000)
③Haerbin Military Representative Office (Heilongjiang Haerbin,150000 )
④68128 Troops of PLA (Gansu Lanzhou, 730046)
关键词:
快速筛选仪; 发射药; 热分解; 热分析动力学
Keywords:
rapid screening device;  8/1 propellant;  GATo-3 propellant;  propellant;  thermal decomposition;  thermal analysis kinetics
分类号:
TQ562
DOI:
10.3969/j.issn.1001-8352.2014.03.011
文献标志码:
A
摘要:
文章采用了一种新的热分析仪器——快速筛选仪（RSD），来研究两种发射药改铵铜推进剂和单基8/1推进剂的热分解过程，分析所得数据得到相应的热分解特性参数以及热动力学参数，发现改铵铜的起始分解温度在150~168 ℃左右，而8/1在175~185 ℃左右。8/1单基药活化能E=238.30 kJ/mol，指前因子A=3.7×1017s-1；改铵铜推进剂活化能E=216.67kJ/mol，指前因子A=2.1×1017 s-1。
Abstract:
Rapid screening device (RSD), a new calorimeter, was used to test the thermal decomposition progress of GATo-3 propellant and 8/1 propellant. The thermal decomposition characteristic data and kinetic parameters obtained from RSD curves show that the initial decomposition temperature of GATo-3 is about 150～168 ℃, and that of 8/1 is about 175～185℃.The kinetic parameters of 8/1 are E=238.30 kJ/mol and A=3.7×1017s－1, while those of GATo-3 are E=216.67kJ/mol and A=2.1×1017 s－1 .

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备注/Memo

备注/Memo:
收稿日期：2013-10-12
作者简介：陈永康（1991~），男，硕士研究生，主要从事含能材料性能检测的研究。E-mail：sharpions@126.com
更新日期/Last Update: 2014-06-11