[1]张袁斌,陈文靖,叶志文.N2O5/HNO3体系硝解三（N-乙酰基）六氢化均三嗪制备RDX[J].爆破器材,2012,41(04):9-11、15.
　ZHANG Yuanbin,CHEN Wenjing,YE Zhiwen.Preparation of RDX by Nitrolysis of 1,3,5-Triacetyl Hexahydro-1,3,5-Triazaine with N2O5/HNO3[J].EXPLOSIVE MATERIALS,2012,41(04):9-11、15.
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N2O5/HNO3体系硝解三（N-乙酰基）六氢化均三嗪制备RDX()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
41
期数:
2012年04
页码:
9-11、15
栏目:
基础理论
出版日期:
2012-08-20

文章信息/Info

Title:
Preparation of RDX by Nitrolysis of 1,3,5-Triacetyl Hexahydro-1,3,5-Triazaine with N2O5/HNO3
文章编号:
4464
作者:
张袁斌; 陈文靖; 叶志文
南京理工大学化工学院（江苏南京，210094）
Author(s):
ZHANG Yuanbin;  CHEN Wenjing;  YE Zhiwen
School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
N2O5; RDX ; 硝解; 炸药
Keywords:
N2O5;  RDX;  nitration;  explosive
分类号:
TJ55 TD235.2+1
文献标志码:
A
摘要:
采用乙腈和三聚甲醛为原料、浓硫酸为催化剂合成三（N-乙酰基）六氢化均三嗪（TRAT），再以N2O5/HNO3 为硝解剂合成黑索今（RDX）。实验表明： 当摩尔比n（N2O5）n（HNO3）n(TRAT)=60∶6∶1，硝解温度50℃,反应时间为1h时，RDX的最高产率可达87.4%。产品通过红外光谱、核磁共振进行了表征，并对副产物进行了研究，副产物通过质谱验证。
Abstract:
1,3,5-Triacetyl hexahydro-1,3,5-triazaine (TRAT) was prepared from acetonitrile and 1,3,5-trioxane in the presence of sulfuric acid as catalyst according to a literature process, and TRAT was then nitrated with N2O5/HNO3 as nitrating agent to RDX. Experiment results showed that when the reaction temperature was 50℃, reaction time 1h and molar ratio of n(N2O5)n(HNO3)n(TRAT)=6∶60∶1, the yield of the RDX was up to 87.4%. The structure of the compound was characterized by NMR and IR. The main side product was researched and confirmed by MS.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2012-03-08
基金项目：国家大学生创新创业训练计划（njust016）
作者简介：张袁斌（1991~），男，在读本科。
通讯作者：叶志文(1968~)，男，教授，博士生导师，主要从事药物中间体和含能材料的合成及应用研究。
更新日期/Last Update: 2012-08-30