[1]卜令涛①,董波②,钱华②③,等.表面活性剂催化硝化TAIW制备CL-20[J].爆破器材,2016,45(02):25-28.[doi:10.3969/j.issn.1001-8352.2016.02.006]
　BU Lingtao,DONG Bo,QIAN Hua,et al.Economic Preparation of CL-20 by Nitrolysis of TAIW Using Surfactants as Catalyst[J].EXPLOSIVE MATERIALS,2016,45(02):25-28.[doi:10.3969/j.issn.1001-8352.2016.02.006]
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表面活性剂催化硝化TAIW制备CL-20()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
45
期数:
2016年02
页码:
25-28
栏目:
爆炸材料
出版日期:
2016-03-27

文章信息/Info

Title:
Economic Preparation of CL-20 by Nitrolysis of TAIW Using Surfactants as Catalyst
文章编号:
5020
作者:
卜令涛①; 董波②; 钱华②③; 郑俊杰②③
①山东天宝化工股份有限公司（山东平邑，273300）
②南京理工大学化工学院（江苏南京，210094）
③国家民用爆破器材质量监督检验中心（江苏南京，210094）
Author(s):
BU Lingtao①;  DONG Bo②;  QIAN Hua②③;  ZHEN Junjie②③
①Shandong Tianbao Chemical Co., Ltd. (Shandong Pingyi, 273300)
②School of Chemical Engineering, Nanjing University of Science and Technology(Jiangsu Nanjing, 210094)
③National Supervision and Inspection Center for Industrial Explosive Materials(Jiangsu Nanjing, 210094)
关键词:
应用化学; CL-20; N2O5; TAIW; 绿色合成; 表面活性剂
Keywords:
applied chemistry;  CL-20;  N2O5;  TAIW;  green synthesis;  surfactants
分类号:
TJ55
DOI:
10.3969/j.issn.1001-8352.2016.02.006
文献标志码:
A
摘要:
针对工业混酸法制备CL-20废酸污染大及N2O5/HNO3法收率低的现状，研究将成本低廉的表面活性剂引入到CL-20制备中，可大幅度提高产品收率。文章考察了表面活性剂种类、用量、反应时间及反应温度的影响，当反应温度为80 ℃，反应时间为4 h，物料比m(SDSN)：m(TAIW)：m(N2O5)：V(HNO3)=0.3 g：3.0 g：4.0 g：15.0 mL时，CL-20收率为89.6%，纯度为95.1%。该方法收率高，成本低，污染小，催化剂无需回收，有较强的应用前景。
Abstract:
The preparation process of CL-20 by nitration with concentrated nitric and sulfuric acid in industrial scale is seriously hazardous to the environment due to a large number of waste acids. N2O5 is an environmentally friendly nitrating agent, but it is not fully satisfied on account of low yield. Inexpensive surfactants were introduced into the preparation of CL-20, and it was found that surfactants are propitious to the synthesis of CL-20 in N2O5/HNO3 system using TAIW as raw material. The effects of species and amount of surfactants, reaction time and temperature have been discussed. The optimum conditions are as follows: reaction temperature is 80 ℃, reaction time is 4 h, m(SDSN)：m(TAIW)：m(N2O5)：V(HNO3)=0.3 g：3.0 g：4.0 g：15.0 mL, and the yield and purity is 89.6% and 95.1%, respectively. This method shows a good prospect with high yield, low costs, less pollution and noneed recycle of catalysts.

参考文献/References:

［1］NIELSEN A T.Caged polynitramine compound:US 5693794［P］.1997-12-02.
［2］公绪宾，孙成辉，庞思平,等. 异伍兹烷衍生物的研究进展［J］. 有机化学，2012，32：486-496.
GONG X B，SUN C H，PANG S P,et al. Research progress in study of isowurtzitane derivatives［J］. Chinese Journal of Organic Chemistry，2012，32：486- 496.
［3］赵信岐，方涛，孙成辉. 六硝基六氮杂异伍兹烷制备工艺研究开发新进展［J］. 兵工学报，2004，25(3)：354-358.
ZHAO X Q,FANG T,SUN C H. Research and development of HNIW synthesis［J］. Acta Armamentarii,2004,25(3):354-358.
［4］王昕，彭翠枝. 国外六硝基六氮杂异伍兹烷的发展现状［J］. 火炸药学报，2007，30(5)：4548.
WANG X，PENG C Z. Development of hexanitro hexaazaisowurtaitane at abroad［J］. Chinese Journal of Explosives and Propellants，2007，30(5)：4548.
［5］王振宇. 国外高能量密度化合物研究新进展［J］. 飞航导弹，2003（2）：34-37.
［6］赵信岐，施倪承.ε -六硝基六氮杂异伍兹烷的晶体结构［J］. 科学通报，1995，40(23)：2158-2160.
［7］AGRAWAL J P. Some new high energy materials and their formulations for specialized applications［J］. Propellants，Explosives，Pyrotechnics，2005，30(5)：316-328.
［8］MANDAL A K，PANT C S，KASAR S M，et al. Process optimization for synthesis of CL-20［J］. Journal of Energetic Materials，2009，27(4)：231- 246.
［9］钱华，吕春绪，叶志文. 绿色硝解合成六硝基六氮杂异伍兹烷［J］. 火炸药学报，2006，29(3)：52-53. 
QIAN H，LǚC X，YE Z W. Synthesis of CL-20 by clean nitration［J］. Chinese Journal of Explosives and Propellants，2006,29(3)：52-53.
［10］钱华，叶志文，吕春绪. N2O5/HNO3硝化硝解TAIW制备CL-20［J］. 应用化学，2008，25(3)：378-380. 
QIAN H ，YE Z W，LǚC X. Nitration and nitrolysis of TAIW with N2O5/HNO3 to synthesize CL-20［J］. Chinese Journal of Applied Chemistry，2008，25(3)：378-380.
［11］胡小玲，吴秋洁，钱华. N2O5/HNO3硝解TAIW合成CL-20［J］. 火炸药学报，2015，38(2)：35-38. 
HU X L，WU Q J，QIAN H. Synthesis of CL-20 by nitrolysis of TAIW with N2O5/HNO3［J］. Chinese Journal of Explosives and Propellant，2015，38(2)：35-38.
［12］ZHU J，TSANG S C. Micellar catalysis for partial oxidation of toluene to benzoic acid in supercritical CO2: Effects of fluorinated surfactants［J］. Catalysis Today，2003，81(4)：673 - 679.
［13］SEMAGINA N V，BYKOV A V，SULMAN E M，et al. Selective dehydrolinalool hydrogenation with poly(ethylene oxide) block-poly-2-vinylpyridine micelles filled with Pd nanoparticles［J］. Journal of Molecular Catalysis A: Chemical，2004，208(1/2)：273-284.
［14］KWAN C Y，CHU W. Reaction mechanism of photoreduction of 2, 4-dichlorophenoxyacetic acid in surfactant micelles［J］. Industrial and Engineering Chemistry Research，2005，44（6）：1645-1651.
［15］MARIANO N，EDGARDO N，JUANA J S. Influence of anionic and cationic reverse micelles nucleophilic aromatic substitution reaction between 1-fluoro-2, 4-dinitrobenzene and piperidine［J］. Journal of Organic chemistry,2000，65（20）：6427-6433.
［16］宋艳民，陆明. 表面活性剂催化间二甲苯的硝化反应研究［J］. 含能材料，2007，15(5)：505-508.
SONG Y M，LU M. Surfactant-catalyzed m-xylene nitration［J］. Chinese Journal of Energetic Materials，2007，15(5)：505-508.

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备注/Memo

备注/Memo:
收稿日期：2015-09-07
基金项目：国家自然科学基金（21406116），南京理工大学卓越计划-紫金之星及江苏高校优势学科建设工程资助项目
作者简介：卜令涛（1974~），男，工程师，从事含能材料的工业化生产工艺研究。E-mail: bltbzq@126.com
通信作者：郑俊杰（1973~），女，工程师，主要从事含能材料的合成及应用研究。E-mail: 1159002140@qq.com
更新日期/Last Update: 2016-03-28