[1]马平,李国仲.粉状乳化炸药热分解动力学研究[J].爆破器材,2009,38(03):1-3、7.
　MA Ping,LI Guozhong.Research on the Thermal Decomposition Kinetics of Powdery Emulsion Explosive[J].EXPLOSIVE MATERIALS,2009,38(03):1-3、7.
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粉状乳化炸药热分解动力学研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
38
期数:
2009年03
页码:
1-3、7
栏目:
基础理论
出版日期:
2009-06-20

文章信息/Info

Title:
Research on the Thermal Decomposition Kinetics of Powdery Emulsion Explosive
文章编号:
4154
作者:
马平; 李国仲
（北京矿冶研究总院，北京100044）
Author(s):
MA Ping;  LI Guozhong
Beijing General Research Institute of Mining and Metallurgy (Beijing, 100044)
关键词:
粉状乳化炸药; 热分解; 反应动力学; 反应机理
Keywords:
powdery emulsion explosive (PEE);  thermal decompositionl;  decomposition kinetic;  reaction mechanism
分类号:
TD235.21
文献标志码:
A
摘要:
利用热重法（TG）研究了粉状乳化炸药的热分解过程和非等温反应动力学, 采用Ozawa法和非线性等转化率积分法获得了其热分解动力学参数和机理函数。结果表明，粉状乳化炸药初始分解温度稍高于乳化炸药基质，分解活化能为97 kJ/mol，是热稳定性良好的工业炸药。粉状乳化炸药的热分解机理属随机成核和随后成长，热分解动力学方程为dα/dt=1×1010×（1-α）exp（-1.2×104/T）。
Abstract:
The thermal decomposition process and the non-isothermal technique kinetic of the powdery emulsion explosive (PEE) are studied by TG. The thermal decomposition kinetic parameter and the mechanism function of the PEE are obtained by Ozawa’s method and the integral isoconversional nonlinear method. The results show that the initial temperature of thermal decomposition of the PEE is a little higher than that of emulsion explosive matrix and the activation energy of the PEE is 97 kJ/mol. It is believed that the PEE has excellent thermal stability performance. The result also shows that the thermal decomposition mechanism of the PEE is classified as random nucleation and growth. The thermal decomposition kinetic equation is dα/dt=1×1010×(1－α)exp(－1.2×104/T ).

参考文献/References:

［1］康廷璋, 张晓智，李子强,等.粉状乳化炸药的生产与应用［J］.工程爆破,2003，9(1)：48~52.［2］倪欧琪，俞明熊.粉状乳化炸药的研究与发展［J］.爆破器材,2000，29(2)：12~15.［3］倪欧琪.粉状乳化炸药安全性能研究［J］.爆破器材,1997，26(6)：16~19.［4］曹海峰，王国利. 粉状乳化炸药静电安全性研究［J］.矿冶，2004，13（3）9~14.［5］李建军，汪旭光，欧育湘,等.乳化炸药热分解动力学研究［J］.北京理工大学学报,1996，16(6)：636~643. ［6］金韶华，松全才.炸药的热分解——等温和非等温数据的对比［J］.火炸药学报，1997，（2）：43~47.［7］高大元，何松伟，沈永兴,等.GI920炸药的热分解动力学研究［J］.含能材料，2008，16（1）：1~4.［8］楚士晋.炸药热分析［M］.北京：科学出版社，1994.172~190.［9］陆　明,刘惠英.膨化硝酸铵的热分解动力学研究［J］. 火炸药学报，2000，（1）：62~64.

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备注/Memo

备注/Memo:
收稿日期：2008-12-5基金项目：北京市西城区科技计划项目（2008026）作者简介：马平（1979~），男，工程师，硕士，主要从事含能材料的研究与应用。
更新日期/Last Update: 2011-05-17