[1]张凯铭①②,倪欧琪①②,俞珍权①②.硝酸钾抑制硝酸铵ANⅣ~ANⅢ相变的效应及其在粉状乳化炸药中的应用[J].爆破器材,2012,41(03):4-7.
 ZHANG Kaiming,NI Ouqi,YU Zhenquan.The Effect of Potassium Nitrate on Inhabiting ANⅣ~ANⅢ Phase Transition of Ammonium Nitrate and Its Application in Powdery Emulsion Explosive[J].EXPLOSIVE MATERIALS,2012,41(03):4-7.
点击复制

硝酸钾抑制硝酸铵AN~AN相变的效应及其在粉状乳化炸药中的应用()
分享到:

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
41
期数:
2012年03
页码:
4-7
栏目:
基础理论
出版日期:
2012-06-20

文章信息/Info

Title:
The Effect of Potassium Nitrate on Inhabiting AN~AN Phase Transition of Ammonium Nitrate and Its Application in Powdery Emulsion Explosive
文章编号:
4465
作者:
张凯铭①②倪欧琪①②俞珍权①②
①南京理工大学化工学院(江苏南京,210094)
②国家民用爆破器材质量监督检验中心(江苏南京,210094)
Author(s):
ZHANG Kaiming①② NI Ouqi①② YU Zhenquan①②
①School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing,210094)
②National Quality Supervision and Inspection Center for Industrial Explosive Materials (Jiangsu Nanjing, 210094)
关键词:
硝酸钾硝酸铵相变粉状乳化炸药
Keywords:
potassium nitrate ammonium nitrate phase transition powdery emulsion explosive
分类号:
TD235.2+1 TQ560.72
文献标志码:
A
摘要:
探讨了硝酸钾抑制硝酸铵AN~AN相变的效应,并且研究了其在提高粉状炸药抗结块性中的作用。通过DSC、高低温试验和抗压强度测试证实,在硝酸铵中添加2%硝酸钾能完全抑制硝酸铵的AN~AN相变,能够提高粉状乳化炸药中硝酸铵的结晶稳定性,降低药体的抗压强度,有效地减少结块现象。
Abstract:
This paper studies the effect of potassium nitrate (KNO3) on inhabiting the AN~ANphase transition of ammonium nitrate (NH4NO3) and its application on improving anti-caking property for powdery emulsion explosive. Experiment results from differential scanning calorimetry (DSC), high-low temperature and compressive strength test show that the addition of 2% KNO3 could inhabit AN~AN phase transition totally, improve the crystallization and thermal stability of NH4NO3, reduce the compressive strength of powder emulsion explosive and resolve its caking phenomenon effectively.

参考文献/References:

[1]Velardez G. F., Alavi S., Thompson D.L. Molecular Dynamics Studies of Melting and Solidstate Transitions of Ammonium Nitrate[J]. J. Chem. Phys., 2004,120:9151-9159.
[2]Sorescu D.C., Thompson D.L. Classical and Quantum Mechanical Studies of Crystalline Ammonium Nitrate[J]. J. Phys. Chem. A,2001,105(4):720-733.
[3]Vargeese A. A., Joshi S. S., Krishnamurthy V.N. Effect of Method of Crystallization on the IVIII and IVII Polymorphic Transitions of Ammonium Nitrate[J]. J. Hazard. Mater., 2009,161(1):373-379.
[4]Lang A. J., Vyazovkin S. Phase and Thermal Stabilization of Ammonium Nitrate in the Form of PVPAN Glass[J]. Mater. Lett.,2008,62(12-13):1757-1760.
[5]Oommen C., Jain S.R. Ammonium Nitrate: A Promising Rocket Propellant Oxidizer[J]. J.Hazard. Mater., 1999,67(3):253-281.
[6]Wu H. B., Chan C. K. Effects of Potassium Nitrate on the Solid Phase Transition of Ammonium Nitrate Particles[J]. Atmos. Environ., 2008,42(2):313-322.
[7]Lang A. J., Vyazovkin S. Ammonium NitratePolymer Glasses: A New Concept for Phase and Thermal Stabilization of Ammonium Nitrate[J]. J. Phys. Chem. B, 2008,112(36):11236-11243. 
[8]倪欧琪,张兴明,孔德让,等.岩石粉状乳化炸药及其制造方法:中国,1566039[P].2005-01-19.
[9]倪欧琪,吴洁红,张兴明,等.煤矿许用粉状乳化炸药及其制造方法:中国,1336355[P].2002-02-20.
[10]倪欧琪,张兴明,唐双凌,等.粉状乳化炸药的制备方法:中国,1765853[P].2006-05-03.
[11]李艺,惠君明. 几种添加剂对硝酸铵热稳定性的影响[J].火炸药学报,2005,28(1):76-80.

相似文献/References:

[1]张建亮.露天改性铵油炸药配方的研制和应用[J].爆破器材,2011,40(01):22.
 ZHANG Jianliang.Research on Development and Application of Opencast Modified Ammonium Nitrate Explosive[J].EXPLOSIVE MATERIALS,2011,40(03):22.
[2]张建亮,张保国.提高改性铵油炸药流散性的研究[J].爆破器材,2011,40(03):19.
 ZHANG Jianliang,ZHANG Baoguo.Research on Improving the Fluidity of Modified Ammonium Nitrate Fuel Oil Explosive[J].EXPLOSIVE MATERIALS,2011,40(03):19.
[3]刘杰,莫元玲,占必文.硝酸钠及亚硝酸钠对乳化炸药生产安全性的影响[J].爆破器材,2011,40(04):9.
 LIU jie,MO Yuanling,ZHAN Biwen.Influence of Sodium Nitrate and Sodium Nitrite on the Production Safety of Emulsion Explosive[J].EXPLOSIVE MATERIALS,2011,40(03):9.
[4]陆明.提高硝酸铵炸药威力的途径研究[J].爆破器材,2011,40(05):1.
 LU Ming.Study on the Improving Strength for Ammonium Nitrate Explosive[J].EXPLOSIVE MATERIALS,2011,40(03):1.
[5]郑俊杰①②,蔡宝虎①,卫延安①.硝酸铵的表面改性研究[J].爆破器材,2011,40(06):19.
 ZHENG Junjie,CAI Baohu,WEI Yanan.Study on Surface Modification of Ammonium Nitrate[J].EXPLOSIVE MATERIALS,2011,40(03):19.
[6]宋日,郭占江,王丽杰.非洲AEL公司乳化炸药现场混制和装药技术分析[J].爆破器材,2008,37(04):11.
 Song Ri,Guo Zhanjiang,Wang Lijie.Analysis of Emulsion Explosive On-site Mixing and Loading Technology of African Explosives Limited (AEL)[J].EXPLOSIVE MATERIALS,2008,37(03):11.
[7]刘杰①,徐志祥②,孔煜③.乳化炸药稳定性及其破乳机理研究[J].爆破器材,2015,44(06):38.[doi:10.3969/j.issn.1001-8352.2015.06.009]
 LIU Jie,XU Zhixiang,KONG Yu.Storage Stability and Demulsion Mechanism of Emulsion Explosives[J].EXPLOSIVE MATERIALS,2015,44(03):38.[doi:10.3969/j.issn.1001-8352.2015.06.009]
[8]李家宽,马小霞,胡艳,等.KNO3/GO复合含能材料的制备与表征[J].爆破器材,2016,45(02):1.[doi:10.3969/j.issn.1001-8352.2016.02.001]
 LI Jiakuan,MA Xiaoxia,HU Yan,et al.Preparation and Characterization of KNO3/GO Composite Energetic Materials[J].EXPLOSIVE MATERIALS,2016,45(03):1.[doi:10.3969/j.issn.1001-8352.2016.02.001]
[9]施金秋,邓国栋,汪庆华,等.微米级硝酸钾粉体的制备及防结块研究[J].爆破器材,2016,45(02):38.[doi:10.3969/j.issn.1001-8352.2016.02.009]
 SHI Jinqiu,DENG Guodong,WANG Qinghua,et al.Preparation and Anti-caking Study on Micron Potassium Nitrate Powder[J].EXPLOSIVE MATERIALS,2016,45(03):38.[doi:10.3969/j.issn.1001-8352.2016.02.009]
[10]刘万义①,耿图禹①,徐森①,等.硝酸铵溶液析晶点测量方法研究[J].爆破器材,2021,50(03):60.[doi:10.3969/j.issn.1001-8352.2021.03.012]
 LIU Wanyi,GENG Tuyu,XU Sen,et al.Study on Measurement Method of Crystallization Point of Ammonium Nitrate Solution[J].EXPLOSIVE MATERIALS,2021,50(03):60.[doi:10.3969/j.issn.1001-8352.2021.03.012]
[11]吕兆坤①,张凯铭①,倪欧琪①②,等.提高粉状乳化炸药储存稳定性的方法研究[J].爆破器材,2013,42(06):24.[doi:10.3969/j.issn.1001-8352.2013.06.005]
 LV Zhaokun,ZHANG Kaiming,NI Ouqi,et al.Study on Storage Stability of Powdery Emulsion Explosive[J].EXPLOSIVE MATERIALS,2013,42(03):24.[doi:10.3969/j.issn.1001-8352.2013.06.005]

备注/Memo

备注/Memo:
收稿日期:2012-03-09
作者简介:张凯铭(1983~),男,博士,主要从事工业炸药相关领域研究。
通讯作者:倪欧琪(1953~),男,教授,主要从事工业炸药相关领域研究。
更新日期/Last Update: 2012-06-21