[1]武威,陈军,杨月,等.双基推进剂用硅橡胶材料包覆设计研究[J].爆破器材,2016,45(05):29-34.[doi:10.3969/j.issn.1001-8352.2016.05.006]
　WU Wei,CHEN Jun,YANG Yue,et al.Study on Inhibition of Double-based Propellant by Silicone Rubber[J].EXPLOSIVE MATERIALS,2016,45(05):29-34.[doi:10.3969/j.issn.1001-8352.2016.05.006]
点击复制

双基推进剂用硅橡胶材料包覆设计研究()
分享到：

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
45
期数:
2016年05
页码:
29-34
栏目:
爆炸材料
出版日期:
2016-09-30

文章信息/Info

Title:
Study on Inhibition of Double-based Propellant by Silicone Rubber
文章编号:
5056
作者:
武威; 陈军; 杨月; 李艳春; 成一
南京理工大学化工学院（江苏南京，210094）
Author(s):
WU Wei;  CHEN Jun;  YANG Yue;  LI Yanchun;  CHENG Yi
Chemical Engineering School,Nanjing University of Science and Technology (Jiangsu Nanjing,210094)
关键词:
应用化学; 硅橡胶; 双基推进剂; 热分析; 高低温冲击试验; 发动机静态点火试验; p-t曲线
Keywords:
applied chemistry;  silicone rubber;  double-based propellant;  thermal analysis;  alternating high and low temperature experiments;  engine ignition experiments of the static; p-t curve
分类号:
TJ55
DOI:
10.3969/j.issn.1001-8352.2016.05.006
文献标志码:
A
摘要:
以自制涂层、硅橡胶为包覆层对双基推进剂进行包覆，采用热分析法对迁移进硅橡胶包覆层的硝化甘油（NG）含量进行分析,结果表明NG含量极少；并对其黏结性能进行测试，试验数据表明其黏结可靠、良好。将此包覆设计用于实际装药包覆，将包覆装药装填到自制火药启动器后，在常温（25 ℃）、低温（－50 ℃× 12 h）、高温（60 ℃× 12 h）条件下和经过高低温冲击试验后进行发动机静态点火试验，测试燃烧室压力时间曲线（p-t曲线），结果表明工作曲线均正常。
Abstract:
The doublebased propellant was inhibited by homemade barrier coat and silicone rubber. Nitroglycerin (NG) migration from double-based propellant into silicone rubber inhibitor was studied by thermal analysis.Experimental results show the content of NG in silicone rubber is minimum. Evaluation of bonding performance of propellant was also performed by tensile test, which shows that the bonding is reliable. Design of inhibition was used in cartridge starter.p-t curve of the engine combustor was also tested, and it shows that the engines work very well no matter at room temperature (25 ℃), low temperature(－50 ℃×12 h), high temperature (60 ℃×12 h) or alternating high and low temperature by inhibition for propellant.

参考文献/References:

［1］AGRAWAL J P, POLHARAKAR R D. Inhibition of rocket propellant［J］. Journal of Scientific & Industrial Research, 1980, 39(1): 633-640.
［2］于洋，范红雨，王宁飞，等．自由装填式药柱贮存过程中的变形分析［J］．含能材料,2007,15(5):524-528.
 YU Y, FANG H Y, WANG N F,et al. Deformation analysis of free loading propellant in storage［J］. Chinese Journal of Energetic Materials, 2007,15(5):524-528.
［3］詹惠安，郑邯勇，赵文忠，等．固体推进剂包覆层的研究进展［J］．舰船防化,2009(3):1-5.
ZHAN H A, ZHENG H Y, ZHAO W Z, et al.Research progress on inhibitor of solid propellant［J］. Chemical Defence on Ships, 2009(3):1-5.
［4］姚楠，王江宁，刘子如，等．热塑性聚氨酯弹性体对高固体含量改性双基推进剂力学性能的影响［J］．含能材料,2008,16(2):196-200.
 YAO N, WANG J N, LIU Z R, et al. Effect of thermoplastic polyurethane elastomer on mechanical properties of modified doublebase propellants［J］. Chinese Journal of Energetic Materials, 2008,16(2):196-200.
［5］刘艳芳，张大伦，贾继书，等．分子筛改性NEPE推进剂丁羟包覆层研究［J］．化学推进剂与高分子材料,2006,4 (5):47-49.
 LIU Y F, ZHANG D L, JIA J S, et al. Study on HTPB liner modified with molecular sieve for NEPE propellant［J］. Chemical Propellants Polymeric Materials, 2006,4 (5):47-49.
［6］杨云．绝热包覆材料综述［J］．上海航天,1990(3):48-51,9.
［7］詹惠安，郑邯勇，赵文忠，等．填料对推进剂用RTV-2硅橡胶包覆材料性能的影响［J］．固体火箭技术,2010,33(4):463-466.
ZHAN H A, ZHENG H Y, ZHAO W Z, et al. Effect of fillers on properties of RTV2 silicone rubber used in inhibitor of propellants［J］. Journal of Solid Rocket Technology, 2010,33(4):463-466.
［8］DAVID C S S,SAYLE S. Silicone for aerospace insulation:US 4953476［P］. 1986-06-20.
［9］冯圣玉，张杰，李美江，等．有机硅高分子及其应用［M］．北京:化学工业出版社,2004:116-151.
［10］李东林，牛西江，崔伟．双基系推进剂与包覆层之间的迁移和脱粘问题［J］．火炸药学报,1996(3):41-45.
LI D L, NIU X J, CUI W. The migration and debonding between double base propellant and inhibitor coating［J］. Chinese Journal of Explosives & Propellants, 1996(3):41-45.
［11］上海橡胶制品研究所.胶粘剂对接接头拉伸强度的测定:GB/T 6329—1996［S］.北京：国家技术监督局,1996.
［12］中国船舶工业总公司第七研究院.军用设备环境试验方法 温度冲击试验：GJB150.5—86［S］.北京：国防科学技术工业委员会，1986.
［13］刘子如.含能材料热分析［M］.北京：国防工业出版社，2012：52.
LIU Z R. Thermal analyses for energetic materials［M］. Beijing: National Defense Industry Press, 2012:52.
［14］刘洪波，杨荔，陈惠，等．偶联剂对石墨/酚醛树脂复合双极板性能的影响［J］．湖南大学学报（自然科学版）,2011,38(7):53-58.
 LIU H B, YANG L, CHEN H, et al. Effect of coupling agent on the properties of phenolic resin/graphite composite bipolar plates［J］. Journal of Hunan University(Natural Sciences), 2011,38(7):53-58.
［15］陈宝喜，李建军，苗彩琴．丁腈橡胶对三元乙丙橡胶包覆剂抗硝化甘油迁移性能的影响［J］．火炸药学报,2004,27(1):56-58.
CHEN B X, LI J J,MIAO C Q. Effect of acrylonitrilebutadiene rubber on nitroglycerin migration from propellant to EPDM inhibitor［J］. Chinese Journal of Explosives & Propellants, 2004,27(1):56-58.
［16］赵凤起，单文刚，李上文．有机硅烷偶联剂在固体火箭发动机装药中应用及其作用机理综述［J］．含能材料,1998,6(1):37-42.
 ZHAO F Q, SHAN W G, LI S W. A review on silane couping agents used in solid rocket motor charges and their action mechanism［J］. Chinese Journal of Energetic Materials, 1998,6(1):37-42.
［17］李瑞琦，姜兆华，王福平，等．推进剂与硅橡胶包覆层间粘接性能研究［J］．材料科学与工艺,2003,11(3):265-267.
 LI R Q, JIANG Z H, WANG F P, et al. Binding property of silicone rubber inhibitor and propellant［J］. Material Science and Technology, 2003,11(3):265-267.
［18］孟征，欧育湘．含包覆ε-HNIW的NEPE推进剂的力学性能［J］．含能材料,2008,16(1):60-62.
 MENG Z, OU Y X. Mechanical properties of NEPE propellant containing two coated ε-HNIW［J］. Chinese Journal of Energetic Materials, 2008,16(1):60-62.
［19］邹德荣．双基推进剂用丁羟胶包覆层研制［J］．含能材料,2004,12(1):52-55.
 ZOU D R. Development of HTPB liner for double-based propellant［J］. Chinese Journal of Energetic Materials, 2004,12(1):52-55.
［20］AGRAWAL J P, VERGNAUD J M. Genesis of development of inhibition technology for rocket propellants and recent work［J］.Journal of Scientific & Industrial Research,1992,51(5):375-382.
［21］PILATO L. Phenolic resins: a century of progress［M］. New York: Springker-Verlag Berlin Heidelberg,2010:1-4.
［22］蒋颂波，王云英，孟江燕，等．白炭黑偶联处理对硅橡胶性能的影响［J］．表面技术, 2008,37(5):21-23.
 JIANG S B, WANG Y Y, MENG J Y, et al. The reseach of silicone rubber reinforced by fumed silica which modified by silane coupling agent［J］. Surface Technology, 2008, 37(5):21-23.
［23］陈国辉，常海．硅橡胶包覆层的研究进展［J］．含能材料,2005,13(3):200-203.
CHEN G H, CHANG H. Progress in silicone rubber inhibitor［J］. Chinese Journal of Energetic Materials, 2005,13(3):200-203.

相似文献/References:

[1]李鸿宾,王建灵,张为鹏,等.铝粉比表面积与质量分数对浆状温压炸药爆炸冲击波影响的实验研究[J].爆破器材,2013,42(01):5.[doi:10.3969/j.issn.1001-8352.2013.01.002]
　LI Hongbin,WANG Jianling,ZHANG Weipeng,et al.Experiment Study on the Effect of Specific Surface Area and Content of Aluminum Powder on Shock Wave Output of Slurry TBE[J].EXPLOSIVE MATERIALS,2013,42(05):5.[doi:10.3969/j.issn.1001-8352.2013.01.002]
[2]沈盼盼①,杜富贵②,刘祖亮①.超细DADNBF的性能研究[J].爆破器材,2014,43(01):19.[doi:10.3969/j.issn.1001-8352.2014.01.004]
　SHEN Panpan,DU Fugui,LIU Zuliang.Properties Research of Ultrafine DADNBF[J].EXPLOSIVE MATERIALS,2014,43(05):19.[doi:10.3969/j.issn.1001-8352.2014.01.004]
[3]周敬,杨丽侠,陈晓明,等.发射药落锤撞击试验及评价方法研究[J].爆破器材,2014,43(02):15.[doi:10.3969/j.issn.1001-8352.2014.02.004]
　ZHOU Jing,YANG Lixia,CHEN Xiaoming,et al.Research on the Experiment and Evaluation Methods of Propellants in Dropping Hammer Impact Test[J].EXPLOSIVE MATERIALS,2014,43(05):15.[doi:10.3969/j.issn.1001-8352.2014.02.004]
[4]唐祥斌,朱顺官,张琳,等.高氯酸胍的合成、表征及性能[J].爆破器材,2015,44(04):6.[doi:10.3969/j.issn.1001-8352.2015.04.002]
　TANG Xiangbin,ZHU Shunguan,ZHANG Lin,et al.Synthesis, Characterization and Performances of Guanidine Perchlorate[J].EXPLOSIVE MATERIALS,2015,44(05):6.[doi:10.3969/j.issn.1001-8352.2015.04.002]
[5]卜令涛①,董波②,钱华②③,等.表面活性剂催化硝化TAIW制备CL-20[J].爆破器材,2016,45(02):25.[doi:10.3969/j.issn.1001-8352.2016.02.006]
　BU Lingtao,DONG Bo,QIAN Hua,et al.Economic Preparation of CL-20 by Nitrolysis of TAIW Using Surfactants as Catalyst[J].EXPLOSIVE MATERIALS,2016,45(05):25.[doi:10.3969/j.issn.1001-8352.2016.02.006]
[6]周敬,杨丽侠,张邹邹,等.高能发射药动态力学强度的影响因素研究[J].爆破器材,2016,45(02):29.[doi:10.3969/j.issn.1001-8352.2016.02.007]
　ZHOU Jing,YANG Lixia,ZHANG Zouzou,et al.Study on the Influence Factors of Dynamic Mechanical Properties of Highenergy Gun Propellant[J].EXPLOSIVE MATERIALS,2016,45(05):29.[doi:10.3969/j.issn.1001-8352.2016.02.007]
[7]赵宝明①,郭丹②,辛凯迪①,等.环切杆状发射装药的点传火试验研究[J].爆破器材,2017,46(04):30.[doi:10.3969/j.issn.1001-8352.2017.04.006]
　ZHAO Baoming,GUO Dan,XIN Kaidi,et al.Experimental Study on Ignition of Curve-cut Stick Gun Propellant[J].EXPLOSIVE MATERIALS,2017,46(05):30.[doi:10.3969/j.issn.1001-8352.2017.04.006]
[8]韩冰,魏伦,于慧芳,等.CD-3发射装药低易损性能试验研究[J].爆破器材,2022,51(02):26.[doi:10.3969/j.issn.1001-8352.2022.02.004]
　HAN Bing,WEI Lun,YU Huifang,et al.Experimental Study on Low Vulnerability of CD-3 Propellant Charge[J].EXPLOSIVE MATERIALS,2022,51(05):26.[doi:10.3969/j.issn.1001-8352.2022.02.004]

备注/Memo

备注/Memo:
收稿日期：2015-12-25
基金项目：国家自然科学基金资助（NSFC51202113）
作者简介：武威（1991－），男，硕士研究生，主要从事双基推进剂包覆研究。E-mail：wuwei00yjf@163.com
更新日期/Last Update: 2016-09-30