[1]李强,任家桐,石先锐,等.GAP基含能热塑性弹性体的研究进展[J].爆破器材,2026,55(05):1-10.[doi:10.3969/j.issn.1001-8352.2026.05.001]
 LI Qiang,REN Jiatong,SHI Xianrui,et al.Research Progress on GAP-Based Energetic Thermoplastic Elastomers[J].EXPLOSIVE MATERIALS,2026,55(05):1-10.[doi:10.3969/j.issn.1001-8352.2026.05.001]
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GAP基含能热塑性弹性体的研究进展()

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
55
期数:
2026年05
页码:
1-10
栏目:
基础理论
出版日期:
2026-10-19

文章信息/Info

Title:
Research Progress on GAP-Based Energetic Thermoplastic Elastomers
文章编号:
7007
作者:
李强; 任家桐; 石先锐; 张衡; 贾永杰
西安近代化学研究所(陕西西安,710065)
Author(s):
LI Qiang;  REN Jiatong;  SHI Xianrui;  ZHANG Heng;  JIA Yongjie
Xi’an Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
关键词:
含能材料; GAP;  含能热塑性弹性体; 结构;  性能
Keywords:
energetic material;  GAP;  energetic thermoplastic elastomer;  structure;  performance
分类号:
TQ560.7; TJ510
DOI:
10.3969/j.issn.1001-8352.2026.05.001
文献标志码:
A
摘要:
作为一种新型火炸药黏结剂,聚叠氮缩水甘油醚基含能热塑性弹性体(GAP-ETPE)兼具较高的能量密度、良好的力学性能、可逆加工性以及可回收特性,已成为含能材料领域的研究热点。系统综述了GAP-ETPE合成方法的发展历程。详细阐述了软、硬段结构设计策略与功能化改性途径。重点探讨了分子结构对微相分离行为、氢键网络形成及宏观性能的调控机制。在此基础上,对GAP-ETPE未来的研究方向进行了展望。为GAP-ETPE的精准分子设计、绿色规模化制备及工程化应用提供理论依据与技术参考。

参考文献/References:

[1]罗运军, 夏敏. 火炸药用功能材料发展趋势的思考[J]. 含能材料, 2021, 29(11): 1021-1024.

[2]Amado J C Q, Ross P G, Murakami L M S, et al. Properties of hydroxyl-terminal polybutadiene (HTPB) and its use as a liner and binder for composite propellants: a review of recent advances [J]. Propellants, Explosives, Pyrotechnics, 2022, 47(5): e202100283.
[3]陈淼, 徐明辉, 刘宁, 等. 含能热塑性黏合剂的研究进展[J]. 爆破器材, 2020, 49(6): 1-8, 14.
Chen Miao, Xu Minghui, Liu Ning, et al. Research progress of energetic thermoplastic binders [J]. Explosive Materials, 2020, 49(6): 1-8, 14.
[4]Wen Yujia, Mo Hongchang, Tan Bojun, et al. Progress in synthesis and properties of oxetane-based energetic polymers [J]. European Polymer Journal, 2023, 194: 112161.
[5]闫镒腾, 白森虎, 钱露, 等. GAP型含能热塑性弹性体的合成及研究进展[J]. 化学推进剂与高分子材料, 2023, 21(5): 1-11.
Yan Yiteng, Bai Senhu, Qian Lu, et al. Synthesis and research progress of GAP-type energetic thermoplastic elastomer [J]. Chemical Propellants & Polymeric Materials, 2023, 21(5): 1-11.
[6]申卫峰. GAP黏合剂合成与改性的研究进展[J]. 爆破器材, 2024, 53(6): 1-11.
Shen Weifeng. Research progress on the synthesis and modification of GAP binders [J]. Explosive Materials, 2024, 53(6): 1-11.
[7]左海丽. GAP基含能热塑性弹性体研究[D]. 南京: 南京理工大学, 2011.
[8]罗运军, 丁善军, 张弛. 含能热塑性弹性体研究进展[J]. 中国材料进展, 2022, 41(2): 117-128.
Luo Yunjun, Ding Shanjun, Zhang Chi. Research progress on energetic thermoplastic elastomers [J]. Materials China, 2022, 41(2): 117-128.
[9]左海丽, 肖乐勤, 菅晓霞, 等. GAP/MDI/DEG含能热塑性弹性体的合成与性能[J]. 高分子材料科学与工程, 2010, 26(12): 20-23.
Zuo Haili, Xiao Leqin, Jian Xiaoxia, et al. Synthesis and properties of GAP/MDI/DEG energetic thermoplastic elastomer [J]. Polymer Materials Science and Engineering, 2010, 26(12): 20-23.
[10]刘丽平, 黄振亚, 王鑫. GAP基含能热塑性弹性体的合成与表征[J]. 火炸药学报, 2014, 37(5): 62-66.
Liu Liping, Huang Zhenya, Wang Xin. Synthesis and characterization of GAP-based energetic thermoplastic elastomer [J]. Chinese Journal of Explosives & Propellants, 2014, 37(5): 62-66.
[11]卢先明, 陈淼, 莫洪昌, 等. GAP基含能热塑性弹性体可控聚合与应用[J]. 含能材料, 2022, 30(6): 542-549.
Lu Xianming, Chen Miao, Mo Hongchang, et al. Controllable polymerization and application of GAP-based energetic thermoplastic elastomers [J]. Chinese Journal of Energetic Materials, 2022, 30(6): 542-549.
[12]Yuan Junming, Liu Yan, Wang Jinying, et al. Nonisothermal simulation and safety analysis of twin-screw extrusion process for synthetizing glycidyl azide polymer-based energetic thermoplastic elastomer [J]. Polymers, 2023, 15(18): 3662.
[13]Diaz E, Brousseau P, Ampleman G, et al. Heats of combustion and formation of new energetic thermoplastic elastomers based on GAP, poly NIMMO and polyGLYN [J]. Propellants, Explosives, Pyrotechnics, 2003, 28(3): 101-106.
[14]宋晓庆, 王文浩, 周集义, 等. GAP基热塑性弹性体的合成与表征[J]. 化学推进剂与高分子材料, 2011, 9(4): 70-72.
Song Xiaoqing, Wang Wenhao, Zhou Jiyi, et al. Synthesis and characterization of GAP-based thermoplastic elastormer [J]. Chemical Propellants & Polymeric Materials, 2011, 9(4): 70-72.
[15]酒永斌, 罗运军, 葛震, 等. 以混合聚醚为软段的含能热塑性聚氨酯弹性体的性能研究[J]. 固体火箭技术, 2010, 33(5): 537-540.
Jiu Yongbin, Luo Yunjun, Ge Zhen, et al. Studies on properties of ETPUEs containing PET and GAP as soft-segment [J]. Journal of Solid Rocket Technology, 2010, 33(5): 537-540.
[16]徐明辉, 杨伟涛, 卢先明, 等. GAP/PET嵌段型热塑性聚氨酯弹性体的低温力学性能[J]. 火炸药学报, 2022, 45(1): 67-72.
Xu Minghui, Yang Weitao, Lu Xianming, et al. Cryogenic mechanical properties of GAP/PET block thermoplastic elastomers [J]. Chinese Journal of Explosives & Propellants, 2022, 45(1): 67-72.
[17]张磊, 张明权, 刘红雨, 等. 具有双软段的GAP基热塑性弹性体的合成与表征[J]. 化学推进剂与高分子材料, 2023, 21(1): 36-39.
Zhang Lei, Zhang Mingquan, Liu Hongyu, et al. Synthesis and characterization of GAP-based thermoplastic elastomers with double soft segments [J]. Chemical Propellants & Polymeric Materials, 2023, 21(1): 36-39.
[18]You J S, Noh S T. Thermal and mechanical properties of poly(glycidyl azide)/polycaprolactone copolyol-based energetic thermoplastic polyurethanes [J]. Macromolecular Research, 2010, 18(11): 1081-1087.
[19]王娟. 叠氮型热塑性聚氨酯弹性体的制备及性能研究[D]. 南京: 南京理工大学, 2016.
Wang Juan. Preparation and properties of azid thermoplastic polyurethane elastomers [D]. Nanjing: Nanjing University of Science and Technology, 2016.
[20]胡义文. 基于叠氮粘合剂的弹性体和推进剂力学性能研究[D]. 南京: 南京理工大学, 2018.
Hu Yiwen. Research on the mechanical properties of azide polyurethane elastomers and its propellant [D]. Nanjing: Nanjing University of Science and Technology, 2018.
[21]Hu Yiwen, Jian Xiaoxia, Xiao Leqin, et al. Microphase separation and mechanical performance of thermoplastic elastomers based on poly(glycidyl azide)/poly(oxytetramethylene glycol) [J]. Polymer Engineering and Science, 2018, 58(S1): E167-E173.
[22]Lin Mingchieh, Cheng Wenkai, Mohamed M G, et al. Photoresponsive azobenzene-grafted thermoplastic elastomers with controlled hard segment ratios for fastrewritable and tunable surface relief gratings [J]. Chemical Engineering Journal, 2025, 522(13): 167803.
[23]Liu Keyu, Zhou Yanqiu, Luo Liqiong, et al. Dualcuring enhances mechanical performance of GAP-based fluorinated polytriazole-polyurethane elastomers [J]. Journal of Applied Polymer Science, 2026, 143(9): e70157.
[24]Kojio K, Nozaki S, Takahara A, et al. Influence of chemical structure of hard segments on physical properties of polyurethane elastomers: a review [J]. Journal of Polymer Research, 2020, 27(6): 140.
[25]菅晓霞. 发射药用热塑性弹性体的研究[D]. 南京: 南京理工大学, 2009.
Jian Xiaoxia. Study on thermoplastic elastomers for gun propellant [D]. Nanjing: Nanjing University of Science and Technology, 2009.
[26]丁海琴. 用于弹药的聚合物合成、改性与性能研究[D]. 南京: 南京理工大学, 2013.
Ding Haiqin. Study on synthesis, modification and properties of polymers for ammunition [D]. Nanjing: Nanjing University of Science and Technology, 2013.
[27]菅晓霞, 肖乐勤, 左海丽, 等. GAP基热塑性弹性体的合成及表征[J]. 含能材料, 2008, 16(5): 614-617.
Jian Xiaoxia, Xiao Leqin, Zuo Haili, et al. Synthesis and characterization of GAPbased thermoplastic elastomer [J]. Chinese Journal of Energetic Materials, 2008, 16(5): 614-617.
[28]酒永斌, 罗运军, 葛震, 等. 一种含能热塑性聚氨酯弹性体的性能[J]. 高分子材料科学与工程, 2011, 27(6): 34-37.
Jiu Yongbin, Luo Yunjun, Ge Zhen, et al. Properties of new energetic thermoplastic polyurethane elastomer [J]. Polymer Materials Science and Engineering, 2011, 27(6): 34-37.
[29]Tsai Mingyen, Lin Mingchieh, Hong Shi, et al. Rational design of glycidyl azide polymer-based triblock copolymers for high-performance energetic thermoplastic elastomers [J]. Polymer, 2025, 327: 128403.?
[30]郑梦泽, 张宁, 刘双, 等. 共混GAP基含能热塑性弹性体的氢键行为与力学性能[J]. 火炸药学报, 2024, 47(4): 365-371.
Zheng Mengze, Zhang Ning, Liu Shuang, et al. Hydrogen bond behavior and mechanical properties of blended GAP based energetic thermoplastic elastomers [J]. Chinese Journal of Explosives & Propellants, 2024, 47(4): 365-371.
[31]张在娟, 罗运军, 李国平. 变温红外光谱法研究GAP与三种异氰酸酯的反应动力学[J]. 含能材料, 2014, 22(3): 382-385.
Zhang Zaijuan, Luo Yunjun, Li Guoping. Reaction kinetics of GAP and three kinds of isocyanates with variable temperature FTIR spectrum method [J]. Chinese Journal of Energetic Materials, 2014, 22(3): 382-385.
[32]张在娟, 罗运军. 含不同扩链剂的聚叠氮缩水甘油醚基含能热塑性弹性体的合成与力学性能[J]. 高分子材料科学与工程, 2014, 30(11): 40-44.
Zhang Zaijuan, Luo Yunjun. Synthesis and mechanical properties of glycidyl azide polymer-based energetic thermoplastic polyurethane eiastomers with different chain extender [J]. Polymer Materials Science and Engineering, 2014, 30(11): 40-44.
[33]张在娟. 含能热塑性聚氨酯弹性体的合成与表征[D]. 北京: 北京理工大学, 2015.
Zhang Zaijuan. Synthesis and characterization of energetic thermoplastic polyurethane elastomers [D]. Beijing: Beijing Institute of Technology, 2015.
[34]Sun Shixiong, Liu Haoyu, Wang Yang, et al. A novel method of improving the mechanical properties of propellant using energetic thermoplastic elastomers with bonding groups [J]. Polymers, 2024, 16: 792.
[35]Zhang Zaijuan, Wang Gang, Wang Zhen, et al. Synthesis and characterization of novel energetic thermoplastic elastomers based on glycidyl azide polymer (GAP) with bonding functions [J]. Polymer Bulletin, 2015, 72(8): 1835-1847.
[36]Zhang Zaijuan, Luo Nan, Deng Jingke, et al. A kind of bonding functional energetic thermoplastic elastomers based on glycidyl azide polymer [J]. Journal of Elastomers & Plastics, 2016, 48(8): 728-738.
[37]Sun Qili, Yang Xiaomei, Yin Guangzhong. Mechanical properties and thermal decomposition mechanism of glycidyl azide polyol energetic thermoplastic elastomer binder with RDX composite [J]. Polymers, 2024, 16(18): 2626.
[38]Lee M W, An S, Yoon S S, et al. Advances in self-healing materials based on vascular networks with mechanical self-repair characteristics [J]. Advances in Colloid and Interface Science, 2018, 252: 21-37.
[39]菅晓霞, 宋育芳, 赵盟辉, 等. GAP基自修复粘结剂的制备及性能[J]. 含能材料, 2019, 27(2): 131-136.
Jian Xiaoxia, Song Yufang, Zhao Menghui, et al. Preparation and performance of self healing binder based on GAP [J]. Chinese Journal of Energetic Materials, 2019, 27(2): 131-136.
[40]Ding Shanjun, Zhang Jun, Zhu Guocui, et al. Rationally constructed surface energy and dynamic hard domains balance mechanical strength and selfhealing efficiency of energetic linear polymer materials [J]. Langmuir, 2021, 37(30): 8997-9008.
[41]Yang Jing, Zhou Xin, Yang Junqing, et al. A microscale regulation strategy for strong, tough, and efficiently self-healing energetic adhesives [J]. Chemical Engineering Journal, 2023, 451(3): 138810.
[42]Qiu Mianji, Geng Zhi, Ruan Xin, et al. Construction of a high-toughness energetic self-healing adhesive based on dynamic disulfide and multiple hydrogen bonds [J]. ACS Applied Polymer Materials, 2025, 7(12): 7751-7766.
[43]酒永斌. 新型粘合剂的合成及在固体推进剂中的应用[D]. 北京: 北京理工大学, 2010.
Jiu Yongbin. Synthesis and application of new adhesive solid propellant [D]. Beijing: Beijing Institute of Technology, 2010.
[44]郑入滔. 2,6-二硝基对二苄醇热塑性弹性体合成与性能研究[D]. 绵阳: 西南科技大学, 2021.
Zheng Rutao. Synthesis and properties of 2,6-dinitro-1,4-diphen-methyol thermoplastic elastomer [D]. Mianyang: Southwest University of Science and Technology, 2021.
[45]Tang Gang, Wang Dongli, Luo Yunjun, et al. Novel azide-rich fluorinated energetic polyurethane with excellent mechanical properties by a one-pot facile strategy [J]. European Polymer Journal, 2022, 177: 111428.

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备注/Memo

备注/Memo:
收稿日期:2026-01-27
基金项目:陕西省自然科学基础研究计划(2025JC-YBQN-188)
第一作者:李强(1995—),博士,助理研究员,主要从事发射药配方及工艺研究。E-mail: qiangli8694@163.com
通信作者:贾永杰(1971—),研究员,主要从事发射药配方及工艺研究。E-mail: 1535349526@163.com
更新日期/Last Update: 2026-09-29