[1]张涛,陈明华,贾昊楠,等.热分解动力学在含能材料中的应用[J].爆破器材,2013,42(06):52-56.[doi:10.3969/j.issn.1001-8352.2013.06.011]
　ZHANG Tao,CHEN Minghua,JIA Haonan,et al.Application of Thermal Decomposition Kinetics in Energetic Materials[J].EXPLOSIVE MATERIALS,2013,42(06):52-56.[doi:10.3969/j.issn.1001-8352.2013.06.011]
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热分解动力学在含能材料中的应用()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
42
期数:
2013年06
页码:
52-56
栏目:
出版日期:
2013-12-20

文章信息/Info

Title:
Application of Thermal Decomposition Kinetics in Energetic Materials
文章编号:
4653
作者:
张涛; 陈明华; 贾昊楠; 贾晓彪; 常文平; 陈永康
军械工程学院军械技术研究所（河北石家庄,050000）
Author(s):
ZHANG Tao;  CHEN Minghua;  JIA Haonan;  JIA Xiaobiao;  CHANG Wenping;  CHEN Yongkang
Ordnance Institute of Technology, Ordnance Engineering College (Hebei Shijiazhuang, 050000)
关键词:
含能材料; 热分解动力学; 反应机理; 动力学补偿效应; 寿命预测
Keywords:
energetic materials;  thermal decomposition kinetics;  reaction mechanism;  kinetic compensation effect;  prediction of service life
分类号:
TQ560.7
DOI:
10.3969/j.issn.1001-8352.2013.06.011
文献标志码:
A
摘要:
文章主要介绍了热分解动力学在含能材料中的重要性，列举了热分解动力学的主要分析方法及几种常用的反应机理，并对其进行简要分析。热分析技术具有快捷简便、准确度高以及适用范围广的特点，在含能材料的热分解动力学中发挥重要作用。热分解动力学广泛应用于含能材料的动力学参数的求解、反应机理的推断以及动力学补偿效应的确定，为其有效使用寿命的预测以及安全性能的评定等提供科学依据。同时，热分析技术的自身完善以及与其他技术的联机使用将促进热分解动力学的不断发展。
Abstract:
The importance of thermal decomposition kinetics in energetic materials was introduced. The main analysis methods of thermal decomposition kinetics and several kinds of reaction mechanism were enumerated and analyzed. Because thermal analysis technology has many advantages including simple and quick operation, high accuracy and extensive application, it plays an important role in the thermal decomposition kinetics of energetic materials. Thermal decomposition kinetic is widely applied in the obtaining of kinetic parameters, the inference of reaction mechanism and kinetic compensation effect for energetic materials. It provides scientific basis for the prediction of service life and evaluation of safety performance of energetic material. Meanwhile, selfimprovement of thermal analysis techniques and combination with other laboratory instruments will promote the development of thermal analysis kinetics.

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备注/Memo

备注/Memo:
收稿日期：2013-05-30
作者简介：张涛(1988~)，男，硕士研究生，研究方向：发射药热分析。
通信作者：陈明华(1965~)， 男，高级工程师，研究方向:含能材料性能检测与评估。
更新日期/Last Update: 2014-01-06