[1]李祥志①,吴敏杰①,陆洪林①,等.二硝基乙腈钾与火药组分相容性的DSC法评估[J].爆破器材,2021,50(03):1-6.[doi:10.3969/j.issn.1001-8352.2021.03.001]
　LI Xiangzhi,WU Minjie,LU Honglin,et al.Compatibility of Potassium Dinitroacetonitrile with Propellant Components Evaluated by DSC Method[J].EXPLOSIVE MATERIALS,2021,50(03):1-6.[doi:10.3969/j.issn.1001-8352.2021.03.001]
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二硝基乙腈钾与火药组分相容性的DSC法评估()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
50
期数:
2021年03
页码:
1-6
栏目:
基础理论
出版日期:
2021-05-25

文章信息/Info

Title:
Compatibility of Potassium Dinitroacetonitrile with Propellant Components Evaluated by DSC Method
文章编号:
5496
作者:
李祥志①; 吴敏杰①; 陆洪林①; 刘巧娥②; 毕福强①③; 王伯周①③
①西安近代化学研究所（陕西西安，710065）
②甘肃银光化学集团工业有限公司（甘肃白银，730900）
③氟氮化工资源高效开发与利用国家重点实验室（陕西西安，710065）
Author(s):
LI Xiangzhi①;  WU Minjie①;  LU Honglin①;  LIU Qiaoe②;  BI Fuqiang①③;  WANG Bozhou①③
① Xian Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
② Gansu Yinguang Chemical Industry Group Co., Ltd. (Gansu Baiyin, 730900)
③State Key Laboratory of Fluorine & Nitrogen Chemicals (Shaanxi Xi’an, 710065)
关键词:
物理化学; 二硝基乙腈钾; 相容性; 差示扫描量热法（DSC）
Keywords:
physical chemistry;  potassium dinitroacetonitrile;  compatibility;  DSC
分类号:
TQ560;V512
DOI:
10.3969/j.issn.1001-8352.2021.03.001
文献标志码:
A
摘要:
为了了解二硝基乙腈钾(DNCK)与火药常用组分之间的相容性，采用差示扫描量热法（DSC）研究了DNCK与这些组分之间的相互作用。结果表明：DNCK与DAGR吸收药、DA吸收药、硝化棉（NC）、硝基胍（NQ）、叠氮硝胺（DIANP）、1,3-二甲基-1,3-二苯基脲（C2）、2-硝基二苯胺（2-NDPA）相容性良好；与六硝基六氮杂异戊兹烷（CL-20）和N甲基-4-硝基苯胺（MNA）轻微敏感；与黑索今（RDX）、三羟甲基乙烷三硝酸酯（TMETN）和间苯二酚（Res）敏感；DNCK与奥克托今（HMX）和N-丁基硝氧乙基硝胺（BUNENA）混合体系的分解峰温较HMX和BUNENA单质组分分别提前了35.2 ℃和17.4 ℃，因此，与HMX和BUNENA不相容。
Abstract:
In order to study the compatibility between potassium dinitroacetonitrile（DNCK）and common propellant components, the DSC method was used to study the interaction of DNCK with these components. Results show that the systems of DNCK with DAGR absorbent powder, DA absorbent powder, nireocellulose(NC), nitroguanidine(NQ), 1,5-diazido-3-nitrazapentane(DIANP), 1,3-dimethyl1,3diphenylurea(C2) and 2-nitrodianiline(2-NDPA) are compatible, DNCK with hexanitrohexaazaiso-wurtzitane (CL-20) and Nmethyl-4-nitroanline(MNA) are slightly sensitive, and DNCK with cyclotrimethylene-trinitramine (RDX), trimethylolpropane trinitrate(TMETN) and resorcinol(Res) are sensitive. Decomposition peak temperature of the systems of DNCK with cyclotetramethylenete-tranitramine (HMX) and N-butyl-N-nitratoethylnitramine(BUNENA) are 35.2 ℃ and 17.4 ℃ earlier than that of HMX and BUNENA,respectively. Therefore, DNCK are incompatible with HMX and BUNENA.

参考文献/References:

［1］彭翠枝，范夕萍，任晓雪，等．国外火炸药技术发展新动向分析［J］. 火炸药学报，2013,36(3):1-5.
PENG C Z, FAN X P, REN X X, et al. Analysis on recent trends of foreign propellants and explosives technology development［J］. Chinese Journal of Explosives & Propellants, 2013,36(3):1-5.
［2］张晓鹏.高能高燃速发射药研究［D］. 南京:南京理工大学，2013.
ZHANG X P.Investigation of high energy and high burning rate gun propellant［D］. Nanjing:Nanjing University of Science & Technology, 2013.
［3］李玉祥. 高燃速发射药及其燃烧性能研究［D］. 南京:南京理工大学，2015. LI Y X. Investigation of high burning rate gun propellant and its burning performances［D］. Nanjing:Nanjing University of Science & Technology, 2015.
［4］CHAILLE J L, WALKER R W. Solid nitrocellulosenitroglycerin propellant with burning rate modifiers containing dinitrocetonitrile salts: US3450583 ［P］.1969-06-17.
［5］宋育芳，肖乐勤，菅晓霞，等. 低分子量聚丙烯酸钾的合成及其应用［J］.爆破器材，2019, 48(5): 40-45.SONG Y F, XIAO L Q, JIAN X X, et al. Synthsis of potassium polyacrylate with low molecular weight and itsapplication［J］.Explosive Matericals, 2019, 48(5):40-45.
［6］韩冰，王琼林，于慧芳，等.一种含纳米钾盐的新型消焰药性能测试［J］.兵器装备工程学报，2017, 38(4): 160-163.
HAN B, WANG Q L, YU H F, et al. Performance test on a new flash reducing propellant containing the nanometer organic potassium salt AK［J］.Journal of Ordnance -Equipment-Engineering, 2017, 38(4): 160-163.
［7］KETTNER M A, KLAPOTKE T M. New energetic polynitrotetrazoles［J］. Chemistry A European Journal, 2015, 21(9): 3755-3765.
［8］HAIGES R, CHRISTE K O. 5-(Fluorodinitromethyl)-2H-tetrazole and its tetrazolates：preparation and characterization of new high energy compounds［J］. Dalton Transactions, 2015, 44(22): 10166-10176.
［9］李祥志，毕福强，周诚，等. 二硝基乙腈钾盐的合成、热行为及晶体形貌［J］.含能材料，2019, 27(3): 225-229.
LI X Z, BI F Q, ZHOU C, et al.Synthesis, thermal behavior and crystal morphology of potassium dinitroacetonitrile［J］. Chinese Journal of Energetic Materials, 2019, 27(3): 225-229.
［10］BEACH N E, CANFIELD V K. Compatibility of explosives with polymers(Ⅲ):AD721004 ［R］. Springfield: NTIS, 1971.
［11］PEI J F, ZHAO F Q, LU H L, et al. Compatibility study of BAMO-GAP copolymer with some energetic materials［J］. Journal of Thermal Analysis and Calorimetry, 2016, 124(3): 1301-1307.
［12］严启龙，李笑江，廖林泉，等. 四硝基并哌嗪（TNAD）与推进剂组分相容性的DSC法评估［J］.含能材料，2008, 16(3): 309-314.
YAN Q L, LI X J, LIAO L Q, et al. Compatibility of trans-1,4,5,8-tetranitro-1,4,5,8-tetraazadacalin (TNAD) with some propellant components evaluated by DSC method［J］. Chinese Journal of Energetic Materials，2008, 16(3): 309-314.
［13］刘子如. 含能材料热分析［M］. 北京：国防工业出版社，2008.LIU Z R. Thermal analyses for energetic materials［M］.Beijing:National Defense Industry Press,2008.
［14］丁玉奎，吴翼，王海丹，等.TNT对RDX热分解行为影响的研究［J］.爆破器材，2014, 43(5):21-25.
DING Y K, WU Y, WANG H D, et al. Effects of TNT on the thermal decompositon performance of RDX［J］. Explosive Materials, 2014, 43(5): 21-25.
［15］贾林，陆洪林，韩芳，等. 叠氮硝胺对硝基胍发射药热行为的影响［J］. 火炸药学报，2015, 38(3)：90-93.
JIA L， LU H L, HAN F, et al. Influence of azidonitramine on the thermal behavior of the nitroguanidine-base gun propellant［J］. Chinese Journal of Explosives & Propellants, 2015, 38(3)：90-93.
［16］赵凤起，陈沛，李上文，等.三羟甲基乙烷三硝酸酯的热分解性能研究［J］. 火炸药学报，1999, 22(3):8-11.
ZHAO F Q, CHEN P, LI S W, et al. Investigation on Thermal decomposition characteristics of trimethylolethane trinitrate (TMETN) ［J］. Chinese Journal of Explosives & Propellants, 1999, 22(3): 8-11.

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备注/Memo

备注/Memo:
收稿日期：2020-06-22
基金项目：国家自然科学基金（21805224）
第一作者：李祥志（1988－），男，助理研究员，主要从事含能材料的合成及应用性能研究。E-mail :2006294032@163.com
通信作者：王伯周（1967－），男，研究员，博导，主要从事含能材料合成与应用研究。E-mail :wbz600@163.com
更新日期/Last Update: 2021-05-25