[1]唐秋明,张爱军,任卫东,等.乳化炸药乳化的爆炸危险性研究[J].爆破器材,2018,47(01):1-9.[doi:10.3969/j.issn.1001-8352.2018.01.001]
 TANG Qiuming,ZHANG Aijun,REN Weidong,et al.Study on Explosion Hazard of Emulsification of Emulsion Explosive[J].EXPLOSIVE MATERIALS,2018,47(01):1-9.[doi:10.3969/j.issn.1001-8352.2018.01.001]
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乳化炸药乳化的爆炸危险性研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
47
期数:
2018年01
页码:
1-9
栏目:
基础理论
出版日期:
2018-01-03

文章信息/Info

Title:
Study on Explosion Hazard of Emulsification of Emulsion Explosive
文章编号:
5196
作者:
唐秋明张爱军任卫东吴应飚王木申
石家庄成功机电有限公司(河北石家庄,051530)
Author(s):
TANG Qiuming ZHANG Aijun REN Weidong WU Yingbiao WANG Musheng
Shijiazhuang Successful Electro-mechanical Co., Ltd (Hebei Shijiazhuang, 051530)
关键词:
乳化炸药爆炸危险性生成热动能硬摩擦压强能
Keywords:
emulsion explosives explosion hazard thermal formation kinetic energy dry friction pressure energy
分类号:
TJ510.5;TQ560;TD235.2+1
DOI:
10.3969/j.issn.1001-8352.2018.01.001
文献标志码:
A
摘要:
对乳化炸药乳化的动能(转动搅拌)、硬摩擦、压强能(微射流)3种作用下的生成热的构成进行了归纳分析,并叙述了上述3种生成热的热升温试验测定及爆炸危害推导结果。结果表明:乳化搅拌线速度为11.4、14.8 m/s和22.4 m/s时,可能发生爆炸的干运转时间分别为125、48 min和5 min;单螺杆泵以1.0 m/s的线速度输送胶体时的摩擦热升温相当于乳化线速度15.1 m/s时的热升温;压强能2.3 MPa(射流流速35 m/s)作用下的乳化受体几乎不升温。以上说明,中国相关法规标准关于乳化器线速度不大于15 m/s、胶体螺杆泵转速不大于100 r/min的规定具有一定合理性;但就本质安全而言,上述指标下的动能(转动搅拌)、硬摩擦两种作用的爆炸危险性仍较大,而压强能较低时(压力2.3 MPa)的原料射流乳化的爆炸危险性则较低。因此,在当前乳化炸药生产线、地面站与混装车生产产能状况和质量要求下,乳化器及胶体螺杆泵线速度不宜进一步降低,淘汰乳化器搅拌和胶体螺杆泵湍流的乳化方式,代之以原料射流的乳化方式(即全静态乳化),是提高乳化炸药安全生产水平的根本措施。
Abstract:
Heat of formation from kinetic energy caused by rotational mixing, dry friction and low pressure energy of micro jetin emulsification of emulsion explosive was summarized and analyzed. Results of temperature rising test and explosion hazard derivation of these three heats of formation were described. Test results indicate that when the linear velocity reaches 11.4, 14.8 m/s, and 22.4 m/s, the dry-running time of the explosion is 125, 48 min, and 5 min respectively. Friction heat of the mono pump with the linear velocity of 1.0 m/s is equivalent to the kinetic energy of the blender at 15.1 m/s. At the pressure energy of 2.3 MPa (flow velocity at 35m/s), the emulsion system barely heats up. Those results demonstrate rationality of the laws and regulations about linear speed of emulsifier no more than 15 m/s and speed of colloidal screw pump no more than 100 r/min. But, there is high risk of dry friction and the kinetic energy caused by rotational mixing. Explosion risk of jet emulsification of raw material is acceptable with lower pressure energy (pressure at 2.3 MPa). Under current requirement of production line of emulsion explosive, ground station, production capability and quality of mixed loading vehicle, linear speed of emulsifier and colloidal screw pump should not be reduced too low. Jet emulsification of raw material (full static emulsification) is the key method to improve the safety production level of emulsion explosive.

参考文献/References:

[1]TRAUTMAN I W.Investigation on the danger and maneuverability of emulsion explosive plants[C]//Translations of Selected Papers and Accident Reports at the 13th Session of SAFEX.2001:46-49.
[2]吕春绪.工业炸药理论[M].北京:兵器工业出版社,2003.
 Lǔ C X. Industrial explosive theory[M].Beijing: Ordnance Industry Press,2003.
[3]徐永北,梁国珠.微射流乳化技术[J].日用化学工业,1990(3):42-43.
[4]ATS Industrial (HK) Co., Ltd.AMH-3 ultra-high pressure micro jet homogenizer[Z/OL].[2017-11-28].http://www.gmdu.net/corp-225790.html/.
[5]ELLIS D, SMITH J G B, HALLIDAY, P S J.Method and means for making an explosive in the form of an emulsion:US4491489[P]1985-01-01.
[6]POWER H H. Static line mixer:US4441823A[P].1984-04-10.
[7]石家庄成功机电有限公司.一种静态乳化敏化无装药泵的乳化炸药连续生产方法:CN104109057A[P].2014-10-22.
[8]李建军,汪旭光,欧育湘,等.乳化炸药热分解动力学研究[J].北京理工大学学报,1996(6):636-642.
[9]周新利,刘祖亮,吕春绪.岩石乳化炸药绝热分解安全性的加速量热法分析[J].火炸药学报,2003,26(2):62-65.
 ZHOU X L, LIU Z L, Lǔ C X. Analysis on adiabatic decomposition safety of rock emulsion explosives using accelerating rate calorimeter[J]. Chinese Journal of Explosives and Propellants,2003,26(2):62-65.
[10]颜事龙,陈峰,马志刚.乳化炸药基质燃烧机理的研究[J].爆破器材,2006,35(6):7-10.
YAN S L, CHEN F, MA Z G. Research on the burning mechanism of emulsion matrix[J].Explosive Materials,2006,35(6):7-10.
[11]PERLID H, NILIMAA F. Safety testing of a mono bump with emulsions by DYNO NOBEL CO. and JIMIT CO.[C]//Translations of Selected Papers and Accident Reports at the 13th Session of SAFEX.2001:50-69.
[12]谈选民,唐秋明.乳化器和螺杆泵爆炸事故原因分析及其防范对策[J].爆破器材,2007,36(3):31-33.
 TAN X M, TANG Q M. Cause analysis and prevention measure of explosion accidents of emulsifier and screw pump[J].Explosive Materials,2007,36(3):31-33.
[13]杨民刚.螺杆泵输送乳化炸药基质安全性探讨[J].含能材料,2004(增刊2):648-650.
 YANG M G. Inquire into the conveying security of base substance of EE with screw pump[J]. Chinese Journal of Energetic Materials,2004(suppl. 2):648-650.
[14]徐志祥,叶志文,胡毅亭,等.基于有限元分析的泵送过程螺杆泵受热研究[J].爆破器材, 2009,38(6):9-13.
 XU Z X, YE Z W, HU Y T, et al. Study of screw pump heated in pumping process based on finite element method[J]. Explosive Materials,2009,38(6):9-13.
[15]孙荣康.猛炸药的化学与工艺学:下册[M].北京:国防工业出版社,1981:35-36.
[16]郑旭煦,杜长海.化工原理[M].2版.武汉:华中科技大学出版社,2016.
 ZHENG X X, DU C H. Principles of chemical engineering[M].2nd ed.Wuhan:Huazhong University of Science and Technology Press,2016.
[17]童秉纲,尹协远,朱克勤.涡运动理论[M].2版.合肥:中国科学技术大学出版社,2009.
[18]章梓雄,董曾南.粘性流体力学[M].2版.北京:清华大学出版社,2011.
ZHANG Z X, DONG Z N. Viscous fluid mechanics[M].2nd ed.Beijing:Tsinghua University Press,2011.
[19]特伦斯?科斯格雷夫.胶体科学原理、方法与应用[M].李牛,李姝,译.北京:化学工业出版社,2009.
 COSGROVE T. Colloid science: principles, methods and applications[M].LI N,LI S, Translated. Beijing:Chemical Industry Press,2009.
[20]温诗铸,黄平.摩擦学原理[M].3版.北京:清华出版社,2008.
 WEN S Z, HUANG P. Principles of tribology[M].3rd ed.Beijing:Tsinghua University Press,2008
[21]鲍登F P,泰伯D.固体的摩擦与润滑[M].陈绍澧,译.北京:机械工业出版社,1982. 
BOWDEN F P, TABOR D. The friction and lubrication of solids[M].CHEN S L,Franslated.Beijing:Machinery Industry Press,1982.

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备注/Memo

备注/Memo:
收稿日期:2017-07-21
作者简介:唐秋明(1963-),男,高级工程师,主要从事工业炸药的研究。E-mail:2298597614@qq.com
更新日期/Last Update: 2018-01-02