[1]唐祥斌,朱顺官,张琳,等.高氯酸胍的合成、表征及性能[J].爆破器材,2015,44(04):6-10.[doi:10.3969/j.issn.1001-8352.2015.04.002]
　TANG Xiangbin,ZHU Shunguan,ZHANG Lin,et al.Synthesis, Characterization and Performances of Guanidine Perchlorate[J].EXPLOSIVE MATERIALS,2015,44(04):6-10.[doi:10.3969/j.issn.1001-8352.2015.04.002]
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高氯酸胍的合成、表征及性能()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
44
期数:
2015年04
页码:
6-10
栏目:
基础理论
出版日期:
2015-08-20

文章信息/Info

Title:
Synthesis, Characterization and Performances of Guanidine Perchlorate
文章编号:
4888
作者:
唐祥斌; 朱顺官; 张琳; 陶培培
南京理工大学化工学院（江苏南京，210094）
Author(s):
TANG Xiangbin;  ZHU Shunguan;  ZHANG Lin;  TAO Peipei
School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
应用化学; 高氯酸胍; 热性能; 爆速
Keywords:
applied chemistry;  perchlorate guanidine;  thermal behavior;  detonation velocity
分类号:
TJ55；TQ564
DOI:
10.3969/j.issn.1001-8352.2015.04.002
文献标志码:
A
摘要:
以碳酸胍和HClO4为原料制备了高氯酸胍。利用XRD、元素分析仪、红外光谱分析、SEM、TG和DSC对产物进行了结构、形貌、热分解性和热安定性研究，并测定了感度和主要爆炸性能。碳酸胍和HClO4投料摩尔比为1∶2或1∶4时，产物的红外光谱和XRD图像峰型几乎完全相同，结合元素分析结果说明为同一物质，均为CH6O4N3Cl。加入铝粉后，高氯酸胍流散性显著增加。观察纯品和加入5%铝粉（质量分数）的高氯酸胍的形貌发现：相对纯品，加入铝粉后颗粒表面变得光滑。高氯酸胍的感度明显低于SY和PETN，是一种比较钝感的炸药。不同密度下，纯品和加入铝粉的高氯酸胍的爆速为5 500 m/s左右，加入5%铝粉对爆速的影响较小。
Abstract:
Guanidine perchlorate was synthesized with guanidine carbonate and HClO4 as raw materials. The structure, morphology, thermal decomposition and thermal stability of guanidine perchlorate were detected by XRD, elemental analyzer, Infrared spectrum analysis, SEM, TG and DSC. Its sensitivity and main blast performance were also measured. The XRD and infrared spectrum images of the products were almost the same when the molar ratio of guanidine carbonate and HClO4 was 1∶2 or 1∶4. In combination with elemental analysis, they are all identified as CH6O4N3Cl. In the addition of aluminum powder, the freeflowing property increases significantly, and the surface of guanidine perchlorate particles becomes smooth under morphology observation. Guanidine perchlorate is a relatively insensitive explosive, and its sensitivity is significantly less than that of SY and PETN. With different density, detonation velocities of pure and aluminum doped guanidine perchlorate are about 5 500 m/s. The addition of 5% aluminum powder(mass fraction)has little effect on detonation velocity.

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备注/Memo

备注/Memo:
收稿日期：2014-10-19
作者简介：唐祥斌 (1989~)，男，硕士研究生，主要从事含能材料合成及性能研究。E-mail:609646557@qq.com
通信作者：朱顺官 (1962~)，男，研究员，主要从事火工药剂技术研究。E-mail:zhusg@mail.njust.edu.cn
更新日期/Last Update: 2015-06-25