[1]王瑞钧,董振,叶志文.典型含能共晶材料的研究进展[J].爆破器材,2025,54(02):1-13.[doi:10.3969/j.issn.1001-8352.2025.02.001]
　WANG Ruijun,DONG Zhen,YE Zhiwen.Research Progress on Typical Energetic Co-crystal Materials[J].EXPLOSIVE MATERIALS,2025,54(02):1-13.[doi:10.3969/j.issn.1001-8352.2025.02.001]
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典型含能共晶材料的研究进展()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
54
期数:
2025年02
页码:
1-13
栏目:
基础理论
出版日期:
2025-04-07

文章信息/Info

Title:
Research Progress on Typical Energetic Co-crystal Materials
文章编号:
5980
作者:
王瑞钧; 董振; 叶志文
南京理工大学化学与化工学院（江苏南京，210094）
Author(s):
WANG Ruijun; DONG Zhen; YE Zhiwen
School of Chemistry and Chemical Engineering，Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
含能材料; 共晶; 共晶制备; 性能表征; 含能共晶分类
Keywords:
energetic material;  co-crystal;  cocrystal preparation;  performance characterization;  classification of energetic co-crystal
分类号:
TQ560; TJ55
DOI:
10.3969/j.issn.1001-8352.2025.02.001
文献标志码:
A
摘要:
含能材料的能量和感度是一对天然共生的矛盾体，一般可以应用共晶技术实现能量与安全性的平衡。综述了含能共晶材料的研究进展，重点关注了TNT、HMX和CL-20这3种典型含能材料的共晶。首先，介绍了含能共晶的形成机理，包括氢键、π-π堆积作用和卤键等分子间的相互作用；接着，讨论了含能共晶的制备方法、性能表征及分类，涵盖物理化学性能、爆轰性能和安全性能等方面；通过分析含能材料和含能氧化剂共晶、两组分含能材料共晶及多组分含能共晶的研究进展，总结了当前含能共晶材料发展中面临的主要问题；最后，提出了扩展含能共晶研究的策略，包括改进制备工艺、扩大含能共晶组分的选择范围、开发更多含能共晶单晶、设计更复杂的多组分含能共晶以及结合人工智能等。
Abstract:
The energy and sensitivity of energetic materials are a natural symbiotic contradiction. Co-crystal technology can generally be applied to achieve a balance between energy and safety. The research progress of energetic co-crystal materials was reviewed, with a focus on three typical energetic materials: TNT, HMX, and CL-20. Firstly, the formation mechanisms of energetic co-crystals were introduced, including intermolecular interactions such as hydrogen bonding, π-π stacking, and halogen bonding. Subsequently, the preparation methods, performance characterization, and classification of energetic co-crystals were discussed, covering aspects such as physical and chemical properties, detonation performance, and safety performance. By analyzing the research progress of energetic materials and energetic oxidizer co-crystals, two-component energetic co-crystals, and multi-component energetic co-crystals, the main challenges faced in the development of energetic co-crystal materials were summarized. Finally, strategies for expanding the research on energetic co-crystals were proposed, including improving preparation processes, expanding the selection range of components for energetic co-crystals, developing more single crystals of energetic co-crystals, designing more complex multi-component energetic co-crystals, and integrating artificial intelligence.

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备注/Memo

备注/Memo:
收稿日期：2024-10-10
第一作者：王瑞钧（2000— ），女，博士研究生，主要从事含能材料结晶的研究。E-mail：wangruijun@njust.edu.cn
通信作者：叶志文（1968—），男，教授，博导，主要从事含能材料的研究。E-mail：yezw@njust.edu.cn
更新日期/Last Update: 2025-04-07