[1]何志伟①,朱文宇①,葛玉强①,等.铝灰替代含铝乳化炸药中铝粉的可行性研究[J].爆破器材,2023,52(02):26-32.[doi:10.3969/j.issn.1001-8352.2023.02.006]
　HE Zhiwei,ZHU Wenyu,GE Yuqiang,et al.Feasibility Study on Substitution of Aluminum Powder in Aluminized Emulsion Explosive with Aluminum Ash[J].EXPLOSIVE MATERIALS,2023,52(02):26-32.[doi:10.3969/j.issn.1001-8352.2023.02.006]
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铝灰替代含铝乳化炸药中铝粉的可行性研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
52
期数:
2023年02
页码:
26-32
栏目:
爆炸材料
出版日期:
2023-03-30

文章信息/Info

Title:
Feasibility Study on Substitution of Aluminum Powder in Aluminized Emulsion Explosive with Aluminum Ash
文章编号:
5697
作者:
何志伟①; 朱文宇①; 葛玉强①; 熊佳文②; 汪扬文①; 孟涛①
①安徽理工大学化学工程学院（安徽淮南，232000）
②芜湖海螺水泥有限公司（安徽芜湖，241000）
Author(s):
HE Zhiwei①;  ZHU Wenyu①;  GE Yuqiang①;  XIONG Jiawen②;  WANG Yangwen①;  MENG Tao①
① School of Chemical Engineering, Anhui University of Science and Technology (Anhui Huainan, 232000)
② Wuhu Conch Cement Co., Ltd. (Anhui Wuhu, 241000)
关键词:
乳化炸药; 铝灰; 热安全性; 爆轰性能; 储存稳定性
Keywords:
emulsified explosive;  aluminum ash;  thermal safety;  detonation performance;  storage stability
分类号:
TJ55；TQ560
DOI:
10.3969/j.issn.1001-8352.2023.02.006
文献标志码:
A
摘要:
采用工业制铝过程中产生的废弃副产物铝灰作为铝粉的替代物来制备乳化炸药，能够有效地降低含铝乳化炸药的制备成本，同时也是对于铝灰的一种新型节能回收利用方式。使用TGA-FTIR联用热分析、铅柱压缩法、爆破漏斗法、电测法及高低温循环等方法对新型铝灰替代含铝乳化炸药的热安全性、爆轰性能及储存稳定性进行了研究。结果表明：添加质量分数10％一次铝灰制备所得的乳化炸药，与普通含铝乳化炸药的热分解性能差异较小，且较基础乳化炸药的做功能力方面有较大幅度的提高，爆破容积提高约50%，而猛度、爆速及机械感度等性能无明显差距；在储存稳定性方面，与添加铝粉的乳化炸药和基础乳化炸药性能差距较小。铝灰替代铝粉制备含铝乳化炸药具有可行性。
Abstract:
Aluminum ash, the waste by-product produced in the process of industrial aluminum production, is used as a substitute for aluminum to make emulsified explosive. It can effectively reduce the production cost of emulsified explosive containing aluminum, and it is also a new way of energy saving and recycling of aluminum ash. Thermal safety, detonation performance and storage stability of the new type of aluminum-ash emulsion explosive were studied by TGA-FTIR thermal analysis, lead column compression, blasting funnel method, electrical measurement and high and low temperature cycle. Results show that the thermal decomposition performance of the emulsion explosive prepared by adding 10% (mass fraction) primary aluminum ash has little difference from that of the ordinary aluminized emulsion explosive. In addition, compared with the ordinary emulsion explosive, the work capacity of the emulsion explosive with aluminum ash has been greatly improved, and the blasting volume has been increased by about 50%, while there is no obvious difference in the performance of the strength, detonation speed and mechanical sensitivity. There is little difference between the storage stability of emulsion explosive with aluminum ash and that of emulsion explosive with aluminum powder or that of ordinary emulsion explosive. It is feasible to prepare aluminumcontaining emulsion explosive with aluminum ash instead of aluminum powder.

参考文献/References:

［1］冯倩. 水平管道中铝粉爆炸冲击波传播特性研究［D］. 淮南: 安徽理工大学, 2020. FENG Q. Study on propagation characteristics of shock wave of aluminum dust explosion in horizontal pipe ［D］. Huainan: Anhui University of Science and Technology, 2020.
［2］吴晔康. 工业纯铝表面等离子电解氧化膜层生长机理及耐蚀性能研究［D］. 秦皇岛: 燕山大学, 2019.
WU Y K. Investigation on growth mechanism and corrosion resistance of plasma electrolytic oxidation coatings on commercial pure aluminium ［D］. Qinhuangdao: Yanshan University, 2019.
［3］黄开书, 万力伦, 陈洋, 等. 含某金属粉炸药爆轰性能分析［J］. 兵工自动化, 2020, 39(9): 94-96.
HUANG K S, WANG L L, CHEN Y, et al. Analysis of detonation performance of explosives containing metal powder ［J］. Ordnance Industry Automation, 2020, 39(9): 94-96.
［4］VOSKOBOINIKOV I M, KOTOMIN A A. Calculation of detonation parameters for explosive mixtures with inert additions［J］. Combustion, Explosion, and Shock Waves,1986, 21(5): 93-97.
［5］龚悦. 高能添加剂对乳化炸药爆轰性能及热分解特性的影响研究［D］. 淮南: 安徽理工大学, 2017.
GONG Y. Influence of high energy additive on detonation properties and thermal decomposition characteristics of emulsion explosive［D］. Huainan: Anhui University of Science and Technology, 2017.
［6］王娜峰. 乳化炸药能量提高及能量输出结构的若干因素研究［D］. 北京: 北京理工大学, 2014.
WANG N F. Studies on energy improvement and energy output structure of emulsion explosives［D］. Beijing: Beijing Institute of Technology, 2014.
［7］许祖熙, 段卫东, 刘瑞, 等. 铝粉含量及颗粒度对乳化炸药做功能力的影响［J］. 工程爆破, 2017, 23(6): 86-90.
XU Z X, DUAN W D, LIU R, et al. The effect of aluminum content and granularity on workability of emulsion explosives ［J］. Engineering Blasting, 2017, 23(6): 86-90.
［8］SATONKINA N P, BORDZILOVSKY S A, DANILKO D A, et al. Influence of aluminum on the characteristics of detonating emulsion explosives［J］. Journal of Physics: Conference Series, 2018, 1128: 012063.
［9］钱海. 铝粉对乳化炸药爆炸性能和热安定性的影响［D］. 淮南: 安徽理工大学, 2017.
QIAN H. Effect of aluminum powder on detonation performance and thermal stability of emulsion explosives［D］. Huainan: Anhui University of Science and Technology, 2017.
［10］胡浩川. 含铝乳化炸药爆炸性能研究［D］. 武汉: 武汉科技大学,2016.
HU H C. Explosion perfo ertormance researchlosion researcll on aluminum-contating emulsion explosive［D］. Wuhan: Wuhan University of Science and Technology, 2016.
［11］曹云霄, 王志强, 李国锋, 等. 工业铝灰资源化利用及管理政策研究现状与展望［J］. 环境保护科学, 2020, 46(4): 128-136.
CAO Y X, WANG Z Q, LI G F, et al. Research status and prospects of industrial aluminum dross utilization and management［J］. Environmental Protection Science, 2020, 46(4): 128-136.
［12］邢修君, 吴跃东. 国内外铝灰资源化利用技术发展现状［J］. 环境工程,2021, 39(3): 148-152.
XING X J, WU Y D. Review on development on the utilization of aluminum dross［J］. Environmental Engineering, 2021, 39(3): 148-152.
［13］MESHRAM A, SINGH K K. Recovery of valuable products from hazardous aluminum dross: a review ［J］. Resources, Conservation and Recycling, 2018, 130: 95-108.
［14］李远兵, 孙莉, 赵雷, 等. 铝灰的综合利用［J］. 中国有色冶金, 2008, 4(6): 63-67.
LI Y B, SUN L, ZHAO L, et al. Utilization of aluminum ash［J］. China Nonferrous Metallurgy, 2008, 4(6): 63-67.
［15］沈凌峰, 王丽, 徐芮, 等. 铝灰的处理技术、环境评价及相应管理政策［J］. 金属矿山, 2021(7): 16-26.
SHEN L F, WANG L, XU R, et al. Treatment technology, environmental evaluation and the corresponding management policies of aluminum ash ［J］. Metal Mine,2021(7):16-26.
［16］李勇, 彭莉, 王海斌, 等. 二次铝灰高温焙烧脱氮固氟试验研究［J］. 矿产保护与利用, 2020, 40(6): 133-140.
LI Y, PENG L, WANG H B, et al. Study on removal of fluoride and nitride in secondary aluminum dross by high temperature roasting ［J］. Conservation and Utilization of Mineral Resources, 2020, 40(6): 133-140.
［17］张虎, 谢兴华, 郭子如, 等. 铝粉含量对乳化炸药性能影响［J］. 含能材料, 2008, 16(6): 738-740.
ZHANG H, XIE X H, GUO Z R, et al. Effect of aluminum powder content on performance of emulsion explosive ［J］. Chinese Journal of Energetic Materials, 2008, 16(6): 738-740.
［18］ADEOSUN S O, SEKUNOWO O I, TAIWO O O, et al. Physical and mechanical properties of aluminum dross［J］. Advances in Materials, 2014, 3(2): 48-51.

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备注/Memo

备注/Memo:
收稿日期：2022-01-29
基金项目：国家自然科学基金（51404006）;安徽理工大学研究生创新基金(2021CX2097)
第一作者：何志伟（1979－），男，副教授，硕导，主要从事含能材料配方的研究。E-mail: 751601138@qq.com
更新日期/Last Update: 2023-03-30