[1]姚李娜,王彩玲,韩仲熙,等.黏结剂对TKX-50基压装炸药机械感度和成型性的影响[J].爆破器材,2020,49(06):36-41.[doi:10.3969/j.issn.1001-8352.2020.06.007]
 YAO Lina,WANG Cailing,HAN Zhongxi,et al.Effects of Binders on Mechanical Sensitivity and Molding Properties of TKX-50-based Pressed Explosive[J].EXPLOSIVE MATERIALS,2020,49(06):36-41.[doi:10.3969/j.issn.1001-8352.2020.06.007]
点击复制

黏结剂对TKX-50基压装炸药机械感度和成型性的影响()
分享到:

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
49
期数:
2020年06
页码:
36-41
栏目:
爆炸材料
出版日期:
2020-12-02

文章信息/Info

Title:
Effects of Binders on Mechanical Sensitivity and Molding Properties of TKX-50-based Pressed Explosive
文章编号:
5505
作者:
姚李娜王彩玲韩仲熙戴致鑫赵省向
西安近代化学研究所(陕西西安,710065)
Author(s):
YAO Lina WANG Cailing HAN Zhongxi DAI Zhixin ZHAO Shengxiang
Xi’an Modem Chemistry Research Institute (Shaanxi Xi’an, 710065)
关键词:
TKX-50基压装炸药机械感度成型相对密度
Keywords:
TKX-50-based explosive mechanical sensitivity relative density of molding
分类号:
TJ55
DOI:
10.3969/j.issn.1001-8352.2020.06.007
文献标志码:
A
摘要:
为了研究黏结剂对TKX50单质炸药的机械感度和成型性能的影响,通过粒度分布试验分析了高速剪切粉碎机处理TKX-50原料后的形貌和粒度。借助机械感度试验研究了TKX-50原料、TKX-50预处理样品、黏结剂氟橡胶和含能热塑性弹性体ETPE包覆处理后TKX-50炸药的安全性能;利用压制成型试验分析了压力、温度对含不同黏结剂的TKX-50基压装炸药成型性的影响规律。结果表明,预处理后TKX-50的粒度变小,分布变窄,形貌比较规整,机械感度降低;氟橡胶或ETPE包覆处理TKX-50炸药的机械感度降低,在一定程度上提高了炸药的安全性;压力、温度对含氟橡胶或ETPE黏结剂的TKX-50基压装炸药的成型性影响较大,且ETPE黏结剂的TKX-50基混合炸药的成型性较好,特定压力和温度条件下其相对密度可达98.1%以上。
Abstract:
A series of experiments was conducted in current research to better understand the influence of binder on the mechanical sensitivity and molding performance of TKX-50-based pressed explosive. They were focused on the morphology and particle size of TKX-50 raw material processed by high-speed shearing mill using scanning electron microscopy, the safety performance of TKX-50 explosive at different stages of raw material, after treatment and coating by various binders such as fluororubber and ETPE by mechanical sensitivity test, and the moldability of TKX-50-based pressed explosives with different binders under assigned pressures or temperatures by press molding test. Results show smaller particle size, narrower size range, more regular appearance, and reduced mechanical sensitivity of TKX-50 after treatment. The lower mechanical sensitivity of TKX-50 explosives coated with fluororubber or ETPE may improve its safety to a certain extent. Pressure and temperature have a greater impact on the moldability of TKX-50-based pressed explosives containing fluororubber or ETPE binder. TKX-50-based explosive with ETPE binder has good moldability and can reach a relative density of more than 98.1% under specific pressure and temperature.

参考文献/References:

[1]刘佳辉,范桂娟,卢校军,等.TKX-50 基混合炸药的爆轰及安全性能[J].含能材料,2019,27(11):902-907.

LIU J H, FAN G J, LU X J, et al. Detonation and safety performance of TKX-50 based PBX [J]. Chinese Journal of Energetic Materials, 2019, 27(11): 902-907.
[2]熊晓雪,薛向贵,杨海君,等. 1,1’-二羟基-5,5’-联四唑二羟胺盐(TKX-50)研究进展[J]. 含能材料,2020,28(8):810-816.
XIONG X X, XUE X G, YANG H J, et al. Review on dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate(TKX-50)[J]. Chinese Journal of Energetic Materials, 2020, 28(8):810-816.
[3]FISCHER N, FISCHER D, KLAP-TKE T M, et al. Pushing the limits of energetic materials the synthesis and characterization of dihydroxylammonium 5,5’-bistetrazole-1,1’-diolate [J]. Journal of Materials Chemistry, 2012, 22 (38) : 20418-0422.
[4]余晨,李苗,李倩,等.新型含能材料TKX-50的力学性能研究[J].化学与生物工程,2019,36(8):49-53.
YU C, LI M, LI Q, et al. Mechanical property of novel enetgetic material TKX-50[J]. Chemistry & Bioengineering, 2019, 36 (8):49-53.
[5]葛忠学,毕富强.高能不敏感含能材料:HATO[J].含能材料,2014,22(4):434-435.
GE Z X, BI F Q. High-energy insensitive energetic materials:HATO [J]. Chinese Journal of Energetic Materials,2014, 22 (4) :434-435.
[6]许诚,张敏,赵娟,等.重结晶工艺对1,1’-二羟基-5,5’-联四唑二羟胺盐热性能和机械感度的影响[J].含能材料,2017,25(5):409-412.
XU C, ZHANG M, ZHAO J, et al. Influence of recrystallization process on the thermal properties and mechanical sensitivity of dihydroxylam-monium 5, 5’-bistetrazole-1,1’-diolate(HATO) [J]. Chinese Journal of Energetic Materials, 2017, 25 (5): 409-412.
[7]彭泓静,黄开书,万力伦,等.高氮含能化合物TKX-50侵彻安全性试验研究[J].兵工自动化,2018,37(12):89-96.
PENG H J, HUANG K S, WAN L L, et al. Experiment research on security of TKX50 energetic compound high content nitrogen during penetration [J]. Ordnance Industry Automation, 2018, 37 (12): 89-96.
[8]郝彩丽,赵子祯,曹端林,等. TKX-50 的合成工艺研究[J].山西化工,2016,36(2):25-28.
HAO C L, ZHAO Z Z, CAO D L, et al. Synthesis techniques research of TKX-50 [J]. Shanxi Chemical Industry, 2016, 36 (2): 25-28.
[9]梁华琼,韩超,雍炼,等.高聚物黏结炸药的压制成型性[J].火炸药学报,2010,33(4):44-48.
LIANG H Q, HAN C, YONG L, et al. Pressing mechanism of polymer-bonded explosive[J]. Chinese Journal of Explosives & Propellants, 2010, 33(4):44-48.
[10]罗运军,葛震.含能黏合剂合成研究新进展[J].火炸药学报,2011,34(2):1-5.
LUO Y J, GE Z. New research progress in the synthesis of energetic binders [J]. Chinese Journal of Explosives & Propellants, 2011, 34 (2): 1-5.
[11]毕家林,王士民,韩春,等.氟橡胶的并用改性研究进展[J].弹性体,2014,24(5):81-84.
BI J L, WANG S M, HAN C, et al. Research on blending modification of fluoroelastomers[J]. China Elastomerics, 2014, 24 (5): 81-84.

相似文献/References:

[1]刘瑶,王建华,刘玉存,等.薄片橡胶炸药的制备及性能研究[J].爆破器材,2014,43(02):24.[doi:10.3969/j.issn.1001-8352.2014.02.006]
 LIU Yao,WANG Jianhua,LIU Yucun,et al.Preparation and Performance Study of Thin Rubber Explosive[J].EXPLOSIVE MATERIALS,2014,43(06):24.[doi:10.3969/j.issn.1001-8352.2014.02.006]
[2]施金秋①,邓国栋①,朱陈森①,等.降低超细高氯酸铵感度的方法研究[J].爆破器材,2014,43(03):9.[doi:10.3969/j.issn.1001-8352.2014.03.003]
 SHI Jinqiu,DENG Guodong,ZHU Chensen,et al.Study on the Method of Reducing the Sensitivity of Ammonium Perchlorate Superfine Powder[J].EXPLOSIVE MATERIALS,2014,43(06):9.[doi:10.3969/j.issn.1001-8352.2014.03.003]
[3]沈盼盼①,杜富贵②,刘祖亮①.7-氨基-4,6-二硝基苯并氧化呋咱的精制及性能研究[J].爆破器材,2014,43(03):21.[doi:10.3969/j.issn.1001-8352.2014.03.005]
 SHEN Panpan,DU Fugui,LIU Zuliang.Research on Recrystallization and Performance of 7-amino-4,6-dinitrobenzofuroxan[J].EXPLOSIVE MATERIALS,2014,43(06):21.[doi:10.3969/j.issn.1001-8352.2014.03.005]
[4]王彩玲,赵省向,戴致鑫,等.CL-20晶体粒度和形貌对其机械感度及火焰感度的影响[J].爆破器材,2014,43(05):1.[doi:10.3969/j.issn.1001-8352.2014.05.001]
 WANG Cailing,ZHAO Shengxiang,DAI Zhixin,et al.Effect of the Particle Size and Surface Appearance on Mechanical Sensitivity and Flame Sensitivity of CL-20[J].EXPLOSIVE MATERIALS,2014,43(06):1.[doi:10.3969/j.issn.1001-8352.2014.05.001]
[5]杨雪芹①②,常双君①,赵芦奎②,等.包覆改性RDX及其在CMDB推进剂中的应用[J].爆破器材,2014,43(06):22.[doi:10.3969/j.issn.1001-8352.2014.06.005]
 YANG Xueqin,CHANG Shuangjun,ZHAO Lukui,et al.Coating of RDX and Its Application in CMDB Propellant[J].EXPLOSIVE MATERIALS,2014,43(06):22.[doi:10.3969/j.issn.1001-8352.2014.06.005]
[6]金大勇①,王亲会①,蒋秋黎①,等.一种DNAN基熔铸炸药压滤装药工艺安全性分析[J].爆破器材,2015,44(03):16.[doi:10.3969/j.issn.1001-8352.2015.03.004]
 JIN Dayong,WANG Qinhui,JIANG Qiuli,et al.Safety Analysis for Filter Press Process of a DNAN Based Meltcast Explosive[J].EXPLOSIVE MATERIALS,2015,44(06):16.[doi:10.3969/j.issn.1001-8352.2015.03.004]
[7]雷伟,罗一鸣,张蒙蒙,等.3,4-二硝基吡唑(DNP)的研究进展[J].爆破器材,2020,49(05):1.[doi:doi:10.3969/j.issn.1001-8352.2020.05.002]
 LEI Wei,LUO Yiming,ZHANG Mengmeng,et al.Research Progress of 3,4-Dinitropyrazole (DNP)[J].EXPLOSIVE MATERIALS,2020,49(06):1.[doi:doi:10.3969/j.issn.1001-8352.2020.05.002]
[8]高杰,王红星,金大勇,等.DNAN/DNTF二元共熔物在热和机械刺激下的安全性研究[J].爆破器材,2021,50(03):35.[doi:10.3969/j.issn.1001-8352.2021.03.007]
 GAO Jie,WANG Hongxing,JIN Dayong,et al.Safety of DNAN/DNTF Binary Eutectic under Thermal Stimulation and Mechanical Stimulation[J].EXPLOSIVE MATERIALS,2021,50(06):35.[doi:10.3969/j.issn.1001-8352.2021.03.007]
[9]罗西,刘红妮,周文静,等.重结晶对PYX热性能和机械感度的影响[J].爆破器材,2022,51(03):38.[doi:10.3969/j.issn.1001-8352.2022.03.007]
 LUO Xi,LIU Hongni,ZHOU Wenjing,et al.Influence of Recrystallization on Thermal Properties and Mechanical Sensitivity of PYX[J].EXPLOSIVE MATERIALS,2022,51(06):38.[doi:10.3969/j.issn.1001-8352.2022.03.007]
[10]张正中,谢五喜,刘运飞,等.高氯酸铵降感技术研究进展[J].爆破器材,2023,52(01):1.[doi:10.3969/j.issn.1001-8352.2023.01.001]
 ZHANG Zhengzhong,XIE Wuxi,LIU Yunfei,et al.Research Progress of the Desensitization Technology of Ammonium Perchlorate[J].EXPLOSIVE MATERIALS,2023,52(06):1.[doi:10.3969/j.issn.1001-8352.2023.01.001]

备注/Memo

备注/Memo:
收稿日期:2020-07-25
基金项目:院级青年科技创新项目
第一作者:姚李娜(1983-),女,硕士,副研究员,从事含能材料的研究。E-mail:yaolina0503@163.com
通信作者:赵省向(1963-),男,博士,研究员,从事含能材料的研究。E-mail:zsx58@sina.com
更新日期/Last Update: 2020-12-02