[1]高娜①,胡毅亭①,张延松②.初始温度对甲烷-空气爆炸压力影响的试验研究[J].爆破器材,2016,45(03):26-30.[doi:10.3969/j.issn.1001-8352.2016.03.006]
 GAO Na,HU Yiting,ZHANG Yansong.Experimental Research on Methane-air Mixtures Explosion Pressure under Normal and Elevated Initial Temperatures[J].EXPLOSIVE MATERIALS,2016,45(03):26-30.[doi:10.3969/j.issn.1001-8352.2016.03.006]
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初始温度对甲烷-空气爆炸压力影响的试验研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
45
期数:
2016年03
页码:
26-30
栏目:
基础理论
出版日期:
2016-05-13

文章信息/Info

Title:
Experimental Research on Methane-air Mixtures Explosion Pressure under Normal and Elevated Initial Temperatures
文章编号:
5041
作者:
高娜胡毅亭张延松
①南京理工大学化工学院(江苏南京,210094) 
②中煤科工集团重庆研究院有限公司(重庆,400037)
Author(s):
GAO Na HU Yiting ZHANG Yansong
①School of Chemical Engineering, Nanjing University of Science & Technology (Jiangsu Nanjing, 210094)
②Chongqing Research Institute of China Coal Technology & Engineering Group Corporation(Chongqing,400037)
关键词:
初始温度甲烷-空气最大爆炸压力压力上升速率最大压力到达时间
Keywords:
initial temperature methane-air mixtures the maximum explosion pressure rising rate of explosion pressure reach time of the maximum explosion pressure
分类号:
TD712;X932
DOI:
10.3969/j.issn.1001-8352.2016.03.006
文献标志码:
A
摘要:
借助特殊环境20 L爆炸特性测试系统,研究了初始温度对甲烷-空气爆炸压力的影响,初始压力为0.1 MPa,初始温度变化范围为298~473 K。结果表明,甲烷-空气爆炸的最大爆炸压力随初始温度的升高而降低,初始温度由298 K升高到473 K,最大爆炸压力由0.783 3 MPa下降到0.501 2 MPa,下降幅度为35.89%。初始温度的升高加快了反应速率,缩短了最大爆炸压力到达时间,由298 K时的127.1 ms缩短到473 K时的85.0 ms。初始温度升高,甲烷-空气最大爆炸压力的上升速率(dp/dt)max呈上升趋势。当初始温度由298 K上升至473 K时,(dp/dt)max升幅并不大,仅为9.16%;爆炸特征值KG不断增大,其爆炸危险性也随之增大。从反应开始到到达最大爆炸压力这段时间内,爆炸压力上升速率的变化在一定程度上可以反映甲烷-空气爆炸反应速率的变化情况。
Abstract:
The influence of initial temperature on the explosion pressure of methaneair mixtures was experimentally investigated at different initial temperature from 298 K to 473 K under the constant initial pressure of 0.1 MPa. Experiments were performed in a closed spherical 20 L vessel with the ignition electrode at the center, which could heat the experimental gas. The results show that the maximum explosion pressure of methane-air mixtures decreases along with the rise of initial temperature. When the initial temperature increases from 298 K to 473 K, the maximum explosion pressure drops from 0.783 3 MPa to 0.501 2 MPa, decreased by 35.89%. Higher initial temperature accelerates the reaction rate, so the reach time of the maximum explosion pressure is shortened from 127.1 ms at 298 K to 85.0 ms at 473 K. In the experimental temperature range, the maximum pressure rise rate (dp/dt)max increases at elevated initial temperature, but the increase is not large, which is only 9.16%. So the explosion eigen value KG also increases. During the period from the beginning of the reaction to the time reaching the maximum pressure, the rising rate of explosion pressure, to a certain extent, can reflect the change of the methaneair explosion reaction rate.

参考文献/References:

[1]GUNTER W D, GENTZIS T, ROTTENFUSSER B A, et al. Deep coalbed methane in Alberta, Canada:a fuel resource with the potential of zero greenhouse gas emissions[J]. Energy Conversion and Management, 1997, 38: S217-S222.
[2]KARACAN C , RUIZ F A, COT M, et al. Coal mine methane: a review of capture and utilization practices with benefits to mining safety and to greenhouse gas reduction[J]. International Journal of Coal Geology, 2011, 86(2/3): 121-156.
[3]李志凯,秦张峰,吴志伟,等.煤层气治理与利用技术研究开发进展[J].燃料化学学报,2013,41(7):787-796.
LI Z K, QIN Z F, WU Z W, et al. Research and development progresses in the mitigation and utilization of coal bed methane[J]. Journal of Fuel Chemistry and Technology, 2013, 41(7):787-796.
[4]国家发展和改革委员会.煤层气(煤矿瓦斯)开发利用“十一五”规划[Z]. 北京:国家发展和改革委员会, 2006.
[5]国家发展和改革委员会.煤层气(煤矿瓦斯)开发利用“十二五”规划[Z]. 北京:国家发展和改革委员会, 2011.
[6]周福勋,赵建涛,张磊,等.含氧煤层气流化床催化燃烧脱氧特性研究[J]. 燃料化学学报, 2013,41(5): 523-529.
ZHOU F X, ZHAO J T, ZHANG L, et al. Catalytic deoxidization characteristic of oxygen-bearing coal mine methane in the fluidized bed reactor[J]. Journal of Fuel Chemistry and Technology, 2013, 41(5):523-529.
[7]CASHDOLLAR K L, ZLOCHOWER I A, GREEN G M, et al. Flammability of methane, propane, and hydrogen gases[J]. Journal of Loss Prevention in the Process Industries,2000,13(3/4/5): 327-340.
[8]GIERAS M, KLEMENS R, RARATA G, et al. Determination of explosion parameters of methane-air mixtures in the chamber of 40 dm3 at normal and elevated temperature[J]. Journal of Loss Prevention in the Process Industries, 2006, 19(2/3):263-270.[9]WIEMANN W. Influence of temperature on the explosion characteristics and the neutralisation of methane-air mixture[C]//International Conference of Safety in Mine Research Institutes.English, 1983.
[10]赵衡阳.气体和粉尘爆炸原理[M].北京:北京理工大学出版社,1996:23-45.
[11]王新,陈网桦,都振华.初始温度和初始压力对气体爆轰参数影响的研究[J].中国安全科学学报,2010,20(2):75-79.
 WANG X, CHEN W H, DU Z H. Influence of initial temperature and initial pressure on gas detonation parameters[J]. China Safety Science Journal, 2010, 20(2):75-79.
[12]伯纳德?刘易斯,京特·冯·埃尔贝.燃气燃烧与瓦斯爆炸:第3版[M].王方,译.北京:中国建筑工业出版社,2010.
 LEWIS B, Von Elbe G. Combustion, flame and explosion of gases:3rd ed[M].WANG F, translated. Beijing: China Architecture & Building Press, 2010.
[13]李润之,黄子超,司荣军.环境温度对瓦斯爆炸压力及压力上升速率的影响[J].爆炸与冲击,2013,33(4):415-419.
 LI R Z,HUANG Z C, SI R J. Influence of environmental temperature on gas explosion pressure and its rise rate[J]. Explosion and Shock Waves,2013,33(4):415-419.
[14]路林,常铭,苗海燕,等.天然气在不同初始温度和初始压力下的燃烧特性研究[J].工程热物理学报,2009,30(10):1771-1774.
 LU L, CHANG M, MIAO H Y, et al. Combustion cha racteristics of natural gas at various initial temperature and pressure[J]. Journal of Engineering Thermophysics, 2009, 30 (10):1771-1774.
[15]RAZUS D, MOVILEANUA C, OANCEA D. The rate of pressure rise of gaseous propylene-air explosions in spherical and cylindrical enclosures[J].Journal of Hazardous Materials, 2007,139(1):1-8.

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备注/Memo

备注/Memo:
收稿日期:2015-11-16
作者简介:高娜(1986-),女,博士,主要从事气体爆炸方面的研究。E-mail:gaona_mxd@163.com
更新日期/Last Update: 2016-05-13