[1]张咪咪①,卫延安①②.糠蜡型复合油相专用乳化剂的研制和应用[J].爆破器材,2015,44(03):39-42.[doi:10.3969/j.issn.1001-8352.2015.03.009]
　ZHANG Mimi,WEI Yanan.Preparation and Application of Special Emulsifier for Composite Oil Phase Containing Bran Wax[J].EXPLOSIVE MATERIALS,2015,44(03):39-42.[doi:10.3969/j.issn.1001-8352.2015.03.009]
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糠蜡型复合油相专用乳化剂的研制和应用()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
44
期数:
2015年03
页码:
39-42
栏目:
爆炸材料
出版日期:
2015-06-20

文章信息/Info

Title:
Preparation and Application of Special Emulsifier for Composite Oil Phase Containing Bran Wax
文章编号:
4845
作者:
张咪咪①; 卫延安①②
①南京理工大学化工学院（江苏南京，210094）
②国家民用爆破器材质量监督检验中心（江苏南京，210094）
Author(s):
ZHANG Mimi①;  WEI Yanan①②
①School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
②National Quality Supervision and Inspection Center for Industrial Explosive Materials (Jiangsu Nanjing, 210094)
关键词:
乳化剂; Span80; 马来酸酐（MA）; 聚异丁烯双丁二酰亚胺（T152）; 稳定性; 乳化炸药
Keywords:
emulsifier;  Span80; maleic anhydride(MA);  T152;  stability;  emulsion explosive
分类号:
TQ561;TD235.2+1
DOI:
10.3969/j.issn.1001-8352.2015.03.009
文献标志码:
A
摘要:
文章介绍了一种新型乳化剂的制备及其在乳化炸药中的应用。采用马来酸酐(MA)和Span80反应制备双子型非离子乳化剂MA-Span80，并与聚异丁烯双丁二酰亚胺（T152）以质量比1∶1制备复合乳化剂，来研究糠蜡型复合油相专用乳化剂。用乳化剂与复合油相制备乳胶基质，测试乳胶基质的黏度和储存稳定性。通过测定MA-Span80及其复合乳化剂在乳化炸药中的爆轰性能，探讨其在乳化炸药中的应用。结果表明：相比于Span80乳化剂，MA-Span80及其复合乳化剂更适用于糠蜡型复合油相，制备的乳化炸药具有更长的储存期。
Abstract:
Preparation of a new type of emulsifier and its applications in emulsion explosive was described. The gemini nonionic emulsifier MA-Span80 was synthesized through the reaction of maleic anhydride and Span80, which subsequently was used for the preparation of compound emulsifier together with T152 at the mass ratio of 1:1. By such formula, special emulsifiers for composite oil phase containing bran wax were researched. Emulsion matrix was prepared by the emulsifiers with composite oil phase, and the viscosity and storage stability was tested. The detonation performance of MA-Span80 and the compound emulsifier were inspected for their practical applications on emulsion explosives. The results show that MA-Span80 and its compound emulsifier are more suitable for composite oil phase containing bran wax, and the emulsion explosives made from them have longer storage period in comparison with Span80.

参考文献/References:

［1］Menger F M, Littau C A. Gemini surfactants: a new class of selfassembling molecules［J］. Journal of the American Chemical Society, 1993, 115（22）:10083-10090.
［2］唐世华, 黄建滨，李子臣，等. Gemini表面活性剂研究的新进展［J］. 自然科学进展：国家重点实验室通迅, 2001, 11(12) : 1240-1251.
［3］Menger F M, Littau C A. Geminic surfactants: synthesis and properties［J］. Journal of the American Chemical Society,1991, 113(4): 1451-1452.
［4］鲍利红, 兰云军, 张淑芬. 蓖麻油与马来酸酐酯化反应的研究［J］. 中国皮革, 2006, 35(13): 13-15.
Bao Lihong, Lan Yunjun, Zhang Shufen. Study on esterification of castor oil and maleic anhydride［J］. China Leather, 2006, 35(13): 13-15.
［5］崔希丽. 马来酸单酯的环氧化及双酯化反应的动力学研究［D］. 济南：山东轻工业学院, 2006.
［6］鲁德平, 龚涛，管蓉，等.马来酸酐双醋型阳离子可聚合乳化剂的制备方法：中国， CN1490077A［P］. 2004-04-21.
［7］乔卫红, 朱明月, 李宗石. 马来酸型阴离子可聚合乳化剂及其制备方法：中国， CN1966135A［P］. 2007-05-23.
［8］张毓, 卫延安, 苏丽娟，等. 糠蜡在乳化炸药中的应用［J］.爆破器材，2013,42(4):32-35.
Zhang Yu, Wei Yanan,Su Lijuan, et al. The application of bran wax in emulsion explosive ［J］. Explosive Materials，2013, 42(4): 32-35. 
［9］汪旭光. 乳化炸药 ［M］. 2版. 北京 : 冶金工业出版社, 2008.
［10］樊国栋, 刘香云.非离子双子表面活性剂的合成研究进展［J］. 科技导报, 2010(4):118-123.
?Fan Guodong, Liu Xiangyun. Research progress of synthesis of nonionic gemini surfactants［J］. Science & Technology Review, 2010(4):118-123.
［11］夏斌, 宋家良, 翟廷海.双子型乳化剂及其制作方法:中国，CN101053798 B［P］. 2011-06-01.
［12］郭晓晶, 谢丽, 李斌栋，等. 新型高分子乳化剂的合成 及其乳化性能研究［J］. 化工时刊, 2011(11): 1-4.
Guo Xiaojing, Xie Li, Li Bindong，et al. Synthesis and emulsion characteristics of the polyisobutylene succinic esters bsaed on sorbitol［J］. Chemical Industry Times, 2011(11): 1-4.
［13］陈银良. 影响乳化炸药稳定性的因素分析［J］. 爆破器材, 2011, 40(2): 17-19.
?Chen Yinliang. Analysis on the factors affecting the stability of emulsion explosive ［J］. Explosive Materials, 2011, 40(2): 17-19.
［14］张凯铭, 倪欧琪, 俞珍权，等.醇胺乳化剂的合成及其在乳化炸药中的应用［J］. 爆破器材, 2013,42(4): 6-9.
Zhang Kaiming, Ni Ouqi, Yu Zhenquan， et al. Synthesis of alkylol amine emulsifiers and their application in emulsion explosive［J］. Explosive Materials, 2013,42(4): 6-9.

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备注/Memo

备注/Memo:
收稿日期：2014-07-14
作者简介：张咪咪(1990~)，女，硕士研究生，主要从事乳化炸药油相和乳化剂应用研究。E-mail：377598305@qq.com
通信作者：卫延安(1969~)，男，副教授，主要从事含能材料、安全评价和应用化学研究。E-mail：weiya_69@163.com
更新日期/Last Update: 2015-05-11