[1]席鹏,王晓峰,孙培培.HNIW炸药钝感包覆工艺研究进展[J].爆破器材,2020,49(04):6-12.[doi:10.3969/j.issn.1001-8352.2020.04.002]
 XI Peng,WANG Xiaofeng,SUN Peipei.Research Progress on Insensitively Coating Technology of HNIW Explosive[J].EXPLOSIVE MATERIALS,2020,49(04):6-12.[doi:10.3969/j.issn.1001-8352.2020.04.002]
点击复制

HNIW炸药钝感包覆工艺研究进展()
分享到:

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
49
期数:
2020年04
页码:
6-12
栏目:
基础理论
出版日期:
2020-07-03

文章信息/Info

Title:
Research Progress on Insensitively Coating Technology of HNIW Explosive
文章编号:
5431
作者:
席鹏王晓峰孙培培
西安近代化学研究所(陕西西安,710065)
Author(s):
XI Peng WANG Xiaofeng SUN Peipei
Xi’an Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
关键词:
材料科学六硝基六氮杂异伍兹烷包覆机理钝感工艺
Keywords:
materials science hexanitrohexaazaisowurtzitane explosive coating mechanism insensitive technology
分类号:
TQ564
DOI:
10.3969/j.issn.1001-8352.2020.04.002
文献标志码:
A
摘要:
阐述了六硝基六氮杂异伍兹烷(HNIW)炸药的钝感包覆机理。总结了核壳结构包覆技术、水悬浮分散包覆技术和反应性涂膜等3种HNIW炸药包覆工艺的研究状况。分析并比较了不同工艺的作用机理和实际效果。介绍了炸药包覆效果的表征技术和适用范围。评述了目前HNIW炸药钝感及包覆技术的研究现状和不足,并对未来研究方向进行展望。
Abstract:
Insensitively coating mechanism of hexanitrohexaazaisowurtzitane (HNIW) particle was described. Three types of coating and desensitizing technologies including deposition coating technology, aqueous suspension coating technology and interactive film coating technology were analyzed. The corresponding coating mechanisms and actual outcomes were compared. A variety of test technologies which can characterize the coating effect of HNIW particles were also described. Then, the current situation and insufficiency of current coating research were commented. Finally, the research forecast of coating technology of HNIW particle was proposed.

参考文献/References:

[1]BAZAKI H, KAWAKE S, MIYA H, et al. Synthesis and sensitivity of hexanitrohexaazaisowurtzitane (HNIW)[J]. Propellants, Explosives, Pyrotechnics, 1998,23(6):333-336.
[2]曾贵玉,聂福德,刘晓东,等.六硝基六氮杂异伍兹烷(CL-20)的研究进展[J].含能材料,2000,8(3):130-134. ZENG G Y, NIE F D,LIU X D, et al. The developments of hexanitrohexaazaisowurtzitane[J].Chinese Journal of Energetic Materials, 2000,8(3):130-134.
[3]董璐阳,盛涤伦,陈利魁,等.TATB原位包覆CL-20的研究[J].火工品,2016(1):41-44.
DONG L Y, SHENG D L, CHEN L K, et al. In-stiu coating of TATB on CL-20[J]. Initiators & Pyrotechnics, 2016(1):41-44.
[4]NIELSEN A T, NISSAN R A, VANDERAH D J, et al. Polyazapo1ycyclics by condensation of aldehydes with -amines-. Part 2. Formation of 2,4,6,8,10,12-hexabenzyl-2,4,6,8,10,12-hexaazatetracyclo[5.5.0.05.9.03.11]dodecanes from glyoxal and benzylamines[J].The Journal of Organic Chemistry,1990,21(32):1459-1466.
[5]BIRCHER H R,MADER P,MATHIECC J. Properties of CL-20 based high explosives[C]//Proceedings of 29th International Annual Conference of ICT.Karlsruhe,1998:1-94.
[6]于卫龙,王晶禹,侯聪花.六硝基六氧杂异伍兹烷/Estane-微球制备及其表征[J].科学技术与工程, 2016,16(9): 192-194.
YU W L, WANG J Y, HOU C H. Preparation and cha-racterization of CL-20/Estane microsphere[J]. Science Technology and Engineering, 2016,16(9): 192-194.
[7]冀威,李小东,王晶禹,等.纳米ε-CL-20/Estane制备与表征[J].含能材料, 2015,23(11):1084-1088.
JI W,LI X D,WANG J Y,et al.Preparation and characterization of nano-ε-CL-20/Estane explosive[J].Chinese Journal of Energetic Materials, 2015,23(11):1084-1088.
[8]李俊龙,王晶禹,安崇伟,等.EPDM对CL-20的包覆及表征[J].火炸药学报,2012,35(1):23-26.
LI J L,WANG J Y,AN C W,et al.Coating of CL-20 by EPDM and its characterization[J].Chinese Journal of Explosives & Propellants,2012,35(1):23-26.
[9]欧育湘,孟征,刘进全.高能量密度化合物CL-20的合成和制备工艺进展[J].化工进展,2007,26(6):762-768.
OU Y X,MENG Z,LIU J Q. Advance in high energy density compound CL-20:developments of synthesis route and production technologies of CL-20[J].Chemical Industry and Engineering Progress, 2007,26(6):762-768.
[10]杨志剑,刘晓波,何冠松,等.混合炸药设计研究进展 [J].含能材料,2017,25(1):2-11.
YANG Z J,LIU X B,HE G S,et al. Advances in design and research of composite explosives [J].Chinese Journal of Energetic Materials,2017,25(1):2-11.
[11]陈冰虹,刘建忠,梁导伦,等.氧化剂包覆硼颗粒对硼基推进剂点火燃烧特性的影响[J].含能材料,2016,24(8): 774-780.
CHEN B H,LIU J Z,LIANG D L,et al.Effect of oxidant coating boron particle on the ignition and combustion characteristics of boron-based propellant [J].Chinese Journal of Energetic Materials,2016,24(8):774-780.
[12]MANNING T G, STRAUSS B. Reduction of energetic filler sensitivity in propellants through coating: US 6524706[P].2003-02-25.
[13]姜夏冰,任慧,于兰,等.黏结剂和石墨对ε-HNIW感度的影响[C]//全国危险物质与安全应急技术研讨会论文集.重庆,2011:125-130.
[14]YANG Z J, LI J S, HUANG B,et al.Preparation and properties study of core-shell CL-20/TATB composites[J].Propellants,Explosives,Pyrotechnics,2014,39(1): 51-58.
[15]徐容,田野,刘春.TATB对CL-20降感研究[J].含能材料,2003,11(4): 219-221.
XU R, TIAN Y, LIU C. Study on the desensitization of CL-20 with TATB[J].Chinese Journal of Energetic -Materials, 2003,11(4): 219-221.
[16]屈晨曦,葛忠学,张敏,等.CL-20/HATO复合物的制备、表征及性能[J].含能材料,2018,26(10): 850-855.
QU C X,GE Z X,ZHANG M,et al.Preparation,characterization and properties of CL-20/HATO composite[J].Chinese Journal of Energetic Materials,2018,26(10): 850-855.
[17]王新全,边红莉,张锡铭,等.CL-20/NQ复合含能微球的制备及其表征[J].科学技术与工程,2018,18(1): 234-239.
WANG X Q,BIAN H L,ZHANG X M, et al. Preparation and characterization of CL-20/NQ composite energetic microspheres[J].Science Technology and Engineering,2018,18(1): 234-239.
[18]王小军,尚凤琴,王霞,等.1-甲基-4,5-二硝基咪唑包覆钝感CL-20研究[J].四川兵工学报,2013,34(5):120-122.
WANG X J,SHANG F Q,WANG X,et al.Study on -insensitivity- CL-20 coated with 4,5-MDNI[J].Journal of Sichuan Ordnance,2013,34(5):120-122.
[19]何强,梁车平,荆肖凡.CL-20基PBX炸药包覆技术研究[J].科技与创新,2018 (14):77-78.
[20]马婷婷,苟瑞君.PBX的制备及包覆工艺研究[J].山西化工,2010,30(4):13-16.
MA T T,GOU R J.Preparation and coating technology of pressed PBX[J].Shanxi Chemical Industry,2010,30(4):13-16.
[21]MEZGER M J,NICHOLICH S M,GEISS D A,et a1.Performance and hazard characterzation of CL-20 formulations [C]// Proceedings of 30th International Annual Conference of ICT. Karlsruhe,1999,14:1-4.
[22]DUDEK K, MARECEK P, VAVRA P. Laboratory testing of HNIW mixtures[C]//Proceedings of 31st International Annual Conference of ICT. Karlsruh,2000.
[23]宋原,李小东,王晶禹.喷雾干燥法制备ε-CL-20/EPDM复合炸药及其性能表征[J].中国胶粘剂,2016,25 (1):16-19,50.
SONG Y,LI X D,WANG J Y.The ε-CL-20/EPDM composite explosive prepared by spray drying method and its characterization in properties[J].China Adhesives,2016,25(1): 16-19,50.
[24]魏华,焦清介,郭学永.石蜡/Estane 5703复合钝感包覆CL-20的研究[J].含能材料,2017,25(4):321-325.
WEI H,JIAO Q J,GUO X Y. Desensitizing technology of CL-20 by coating wax and Estane 5703[J].Chinese Journal of Energetic Materials,2017,25(4):321-325.
[25]尚凤琴,金韶华,王霞,等.CL-20的降感包覆研究[J].四川兵工学报,2015,36(1):25-27.
SHANG F Q,JIN S H,WANG X,et al.Research of -reduced- sensitivity with coated CL-20 [J].Journal of -Sichuan- Ordnance, 2015,36(1):25-27.
[26]邢江涛,徐文峥,王晶禹,等.丙烯酸酯橡胶对CL-20的包覆降感及改性[J].火炸药学报,2017,40(1):34-39.
XING J T,XU W Z,WANG J Y ,et al.Sensitivity reduction and modification of CL-20 coated with ACM[J].Chinese Journal of Explosives & Propellants,2017,40(1):34-39.
[27]叶宝云,王晶禹,安崇伟,等.CL-20基复合含能材料的制备及性能[J].固体火箭技术,2017,40(2):199-203.
YE B Y,WANG J Y,AN C W,et al. Preparation and properties of CL-20 based composite energetic material[J].Journal of Solid Rocket Technology,2017,40(2):199-203.
[28]廖肃然,罗运军,孙杰,等.水性聚氨酯的合成及其对CL-20的包覆[J].含能材料,2006,15(5):336-339.
LIAO S R,LUO Y J,SUN J,et al.Synthesis of waterborne polyurethane and its coating on CL-20[J].Chinese Journal of Energetic Materials,2006,15(5):336-339.
[29]LIAO S R,LUO Y J,SUN J,et al. Synthesis of waterborne polyurethane for coating on HNIW[J].Advanced Materials Research,2011,194: 2425-2428.
[30]廖肃然,罗运军,孙杰,等.WPU-g-SAN的合成及其对HNIW的包覆[J].含能材料,2012,20(2):155-160.
LIAO S R,LUO Y J,SUN J,et al.Preparation of WPU-g-SAN and its coating on HNIW[J].Chinese Journal of Energetic Materials,2012,20(2):155-160.
[31]YANG Z J, DING L, WU P, et al.Fabrication of RDX, HMX and CL-20 based microcapsules via in situ polymerization of melamine-formaldehyde resins with reduced sensitivity[J].Chemical Engineering Journal,2015,268:60-66.
[32]王保国,张景林,彭英健.配位键合剂-603对亚微米CL-20撞击感度的影响[J].火炸药学报,2008,31(4):39-42.
WANG B G,ZHANG J L,PENG Y J. Effect of ligand bonding agent-603 on the impact sensitivity of sub-micron- CL-20[J].Chinese Journal of Explosives & Propellants,2008,31(4):39-42.
[33]李海兴,王晶禹,安崇伟.表面活性剂对CL-20基浇注传爆药流变性能的影响[J].火工品,2013(6):27-31.
LI H X,WANG J Y, AN C W.Effects of surface-active agents on the rheological properties of CL-20 based on casting booster[J].Initiators & Pyrotechnics,2013(6): 27-31.
[34]金韶华,于昭兴,欧育湘,等.六硝基六氮杂异伍兹烷包覆钝感的探索[J].含能材料,2004,12(3):147-150.
JIN S H,YU Z X, OU Y X, et al. Investigation of -coating-desensitization- of hexanitrohexaazaisowurtzitane(HNIW)[J].Chinese Journal of Energetic Materials, 2004,12(3): 147-150.
[35]宋振伟,严启龙,李笑江,等.溶剂中ε-CL-20的晶型变化[J].含能材料,2010,18(6):648-653.
SONG Z W,YAN Q L, LI X J, et al. Crystal transition of ε-CL-20 in different solvent[J].Chinese Journal of Energetic Materials, 2010,18(6): 648-653.
[36]徐金江,蒲柳,刘渝,等.HTPB基粘结体系中ε-CL-20的晶型转变规律[J].含能材料,2015,23(2):113-119.
XU J J, PU L, LIU Y, et al. Polymorphic transformation of ε-CL-20 in different HTPB-based composite systems[J].Chinese Journal of Energetic Materials,2015,23(2): 113-119.
[37]蔡兴旺,杨继华,张景林.反溶剂液态CO2包覆ε-HNIW的工艺研究[J]材料导报,2016,30(5):134-137.
CAI X W, YANG J H, ZHANG J L. Process study on coating ε-HNIW using liquid CO2 as an anti-solvent [J]. Materials Review,2016,30(5):134-137.
[38]边桂珍,郭效德,刘开伟,等.BAMO-THF共聚醚原位结晶包覆HMX[J].火炸药学报,2014,37(1):35-38.
BIAN G Z, GUO X D, LIU K W, et al. In-situ crystallization coating HMX by BAMO-THF copolyether [J]. Chinese Journal of Explosives & Propellants, 2014,37(1):35-38.
[39]张斌,罗运军,谭惠民.多种键合剂与CL-20界面的相互作用机理[J].火炸药学报,2005,28(3):23-26.
ZHANG B, LUO Y J,TAN H M. Interactional mechanism of the interface between CL-20 and some bonding agents[J].Chinese Journal of Explosives & Propellants, 2005,28(3):23-26.
[40]黄菊,王伯良,刘伟,等.添加剂对黑索今颗粒包覆度和机械感度的影响[J].爆炸与冲击,2015,35(4) :454-458.
HUANG J,WANG B L,LIU W,et al. Influence of additives on the coverage degree and mechanical sensitivity of RDX [J].Explosion and Shock Waves, 2015,35(4):454-458.
[41]蒋跃强,刘永刚,张建虎.造型粉包覆质量表征及其对机械感度的影响[J].四川兵工学报,2014,35(7):118-120.
JIANG Y Q, LIU Y G, ZHANG J H. Coating quality characterizing and effect on mechanical sensitivity of molding powder [J].Journal of Sichuan Ordnance, 2014,35(7): 118-120.
[42]宋华杰,董海山,郝莹.对用XPS技术评价塑料粘结炸药造型粉包覆度的几点看法[J].兵工学报,2002,23(1):132-135.
SONG H J,DONG H S,HAO Y.Some views on the -evaluation- of degrees of coverage of plastics-bonded explosive-s molding powder using X-ray photoelectron spectroscopy[J]. Acta Armamentarii, 2002,23(1):132-135.

相似文献/References:

[1]王彩玲,赵省向,戴致鑫,等.CL-20晶体粒度和形貌对其机械感度及火焰感度的影响[J].爆破器材,2014,43(05):1.[doi:10.3969/j.issn.1001-8352.2014.05.001]
 WANG Cailing,ZHAO Shengxiang,DAI Zhixin,et al.Effect of the Particle Size and Surface Appearance on Mechanical Sensitivity and Flame Sensitivity of CL-20[J].EXPLOSIVE MATERIALS,2014,43(04):1.[doi:10.3969/j.issn.1001-8352.2014.05.001]
[2]席鹏,王晓峰,李媛媛,等.浇注型PBX混合工艺参数优化[J].爆破器材,2015,44(05):5.[doi:10.3969/j.issn.1001-8352.2015.05.002]
 XI Peng,WANG Xiaofeng,LI Yuanyuan,et al.Optimization of Mixing Process Parameters for Casting PBX Charge[J].EXPLOSIVE MATERIALS,2015,44(04):5.[doi:10.3969/j.issn.1001-8352.2015.05.002]

备注/Memo

备注/Memo:
收稿日期:2019-11-13
第一作者:席鹏(1985-),男,硕士,高级工程师,主要从事炸药配方及工艺研究。E-mail:xipeng-57@163.com
更新日期/Last Update: 2020-07-02