[1]章文义①,李玉艳②,张建新③,等.棉花的热危险性及其影响因素的研究[J].爆破器材,2019,48(03):7-12.[doi:10.3969/j.issn.1001-8352.2019.03.002]
 ZHANG Wenyi,LI Yuyan,ZHANG Jianxin,et al.Study on Thermal Hazard and Its Influence Factors of Cotton[J].EXPLOSIVE MATERIALS,2019,48(03):7-12.[doi:10.3969/j.issn.1001-8352.2019.03.002]
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棉花的热危险性及其影响因素的研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
48
期数:
2019年03
页码:
7-12
栏目:
基础理论
出版日期:
2019-05-20

文章信息/Info

Title:
Study on Thermal Hazard and Its Influence Factors of Cotton
文章编号:
5332
作者:
章文义李玉艳张建新徐 森②③潘 峰②③郑俊杰②③
①江苏警官学院警务指挥与战术系(江苏南京,210031)
②南京理工大学化工学院(江苏南京,210094)
③国家民用爆破器材质量监督检验中心(江苏南京,210094)
Author(s):
ZHANG Wenyi LI Yuyan ZHANG Jianxin XU Sen②③ PAN Feng②③ ZHENG Junjie②③
①Department of Command and Tactic, Jiangsu Police Institute (Jiangsu Nanjing, 210094)
②School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
③National Quality Supervision and Inspection Center for Industrial Explosive Materials (Jiangsu Nanjing, 210094)
关键词:
棉花自热自燃温度金属网篮热危险性
Keywords:
cotton self-heating spontaneous ignition temperature wire mesh baskets thermal hazard
分类号:
X932
DOI:
10.3969/j.issn.1001-8352.2019.03.002
文献标志码:
A
摘要:
为评估棉花的热危险性,采用自热和自燃点测试装置,研究了含水量、含油量、堆积密度等对棉花自热性能的影响规律,以及立方体金属网篮的不同体积对棉花自燃温度的影响。结果表明:含水量、含油量及堆积密度越高,棉花内部温度越高,热危险性越大。但水的质量分数在0~50%的范围内,脱脂棉和长绒棉两种棉花均不属于自热物质;当油的质量分数为5%和10%时,长绒棉发生自燃时最高温度分别为635.6 ℃和539.7 ℃,属于自热物质;当油的质量分数为5%、10%和15%时,脱脂棉最高温度分别上升至161.7、169.8 ℃和184.1 ℃。立方体金属网篮的体积越大,棉花的自燃温度越低;研究发现,立方体网篮体积的对数(logV)和自燃温度的倒数(1/T)成线性关系,根据拟合曲线可预测不同体积下棉花的自燃温度。
Abstract:
To evaluate the thermal hazard of cotton, the effects of different moisture content, oil content and packing density on the self-heating of cotton were studied using self-heating and spontaneous ignition temperature tests. The thermal hazard increases with the increase of the moisture content, oil content and bulk density of the cotton. However, spontaneous ignition doesnt occur for degrease cotton and long staple cotton under the moisture content in the range of 0-50%. With 5% and 10% oil content, the highest temperature of the long staple cotton reaches to 539.7 ℃ and 635.6 ℃, respectively, therefore they are categorized into self-heating substance. When the oil content of absorbent cotton is 5%, 10% and 15%, the highest temperature of the degrease cotton rises to 161.7 ℃, 169.8 ℃ and 184.1 ℃. The larger the volume of the metal basket, the lower the auto ignition temperature of the cotton is. It is found that the logarithm (logV) of the cube basket volume is linearly related to the reciprocal of the auto ignition temperature (1/T). According to the fitting curve, the auto ignition temperature of cotton bale with various volumes can be predicted.

参考文献/References:

[1]HARTZELLLAWSON M M, HSIEH Y L. Characterizing the non cellulosics in developing cotton fibers [J]. Textile Research Journal, 2000, 70(9): 810-819.
[2]RJIBA N, NARDIN M, DRAN J Y,et al. A study of the surface properties of cotton fibers by inverse gas chromatography [J]. Journal of Colloid and Interface Science, 2007, 314(2):373-380.
[3]RJIBA N, NARDIN M, DREAN J Y, et al. Comparison of surfaces properties of different types of cotton fibers by inverse gas chromatography [J]. Journal of Polymer Research, 2010, 17: 25-32.
[4]Dangerous Goods Regulations [M]. Recognized by the world’s airlines, 58th, 2017.
[5]朱江.棉花堆垛火灾扑救对策探讨:以临汾中储棉仓库火灾扑救为例 [J]. 武警学院学报, 2014, 30(12): 27-29.
ZHU J. On the fire-fighting countermeasure of the cotton stacking[J]. Journal of Chinese Peoples Armed Police Force Academy, 2014, 30(12): 27-29.
[6]汤进. 棉花加工企业火灾成因及消防安全对策[J]. 中国棉花加工, 2013 (5): 41-42.
[7]WORDEN J T. Spontaneous ignition of linseed oil soaked cotton using the oven basket and crossing point methods[D]. College Park: University of Maryland, 2011.
[8]KHATTAB M A, EL-ASHAEL A A, KANDIL S H. Effect of contamination of cotton fabric with linseed oil on the activation energies of pyrolysis and oxidation of the fabric [J]. Fire and Materials, 1999, 23:131-137.
[9]THOMPSON N J. The spontaneous heating of oils [J]. Journal of the American Oil Chemists Society, 1928, 5(11), 317-326.
[10]BOURBIGOT S, CHLEBICKI S, MAMLEEV V. Thermal degradation of cotton under linear heating[J].Poly-mer Degradation & Stability, 2002, 78(1):57-62.
[11]ZHU P, SUI S Y, WANG B, et al. A study of pyrolysis and pyrolysis products of flame-retardant cotton fabrics by DSC, TGA, and PY-GC-MS [J]. Journal of Analytical and Applied Pyrolysis, 2004, 71(2):645-655.
[12]WANG Q S, SUN J H, GUO S. Spontaneous combustion identification of stored wet cotton using a C80 calorimeter [J]. Industrial Crops and Products, 2008, 28(3):268-272.
[13]ZHAO X J, XIAO H H, WANG Q S, et al. Study on spontaneous combustion risk of cotton using a micro-calorimeter technique [J]. Industrial Crops and Products, 2013, 50:383-390.
[14]CEYLAN O, VAN LANDUYT L,RAHIER H, et al. The effect of water immersion on the thermal degradation of cotton fibers [J]. Cellulose, 2013, 20(4):1603-1612.
[15]WAKELYN P J, HUGHS S E. Evaluation of the flammability of cotton bales [J]. Fire and Materials, 2002, 26(4/5):183-189.
[16]包任烈, 张永丰, 顾海昕, 等. 棉花自燃风险性的热分析研究 [J]. 消防科学与技术, 2012, 31(1):100-103.
?BAO R L, ZHANG Y F, GU H X, et al. The research of cotton's self-ignition risk by thermal analysis[J]. Fire Science and Technology, 2012, 31(1):100-103.
[17]ALONGI J, CAMINO G, MALUCELLI G. Heating rate effect on char yield from cotton, poly(ethylene terephthalate) and blend fabrics [J]. Carbohydrate Poly-mers, 2013, 92(2):1327-1334.
[18]张成梁, 冯显英, 杨丙生, 等. 基于相对湿度的棉花回潮率在线检测 [J]. 沈阳工业大学学报, 2013,35(4):445-450.
ZHANG C L ,FENG X Y, YANG B S, et al.Online detection of cotton moisture regain based on relative humi-dity[J].Journal of Shenyang University of Technology, 2013,35(4):445-450.
[19]Recommendations on the transport of dangerous goods:manual of tests and criteria [M]. New York and Geneva: United Nations, 2015.
[20]全国塑料标准化技术委员会.塑料燃烧性能试验方法 闪燃温度和自燃温度的测定:GB/T 9343—2008[S].北京:中国标准出版社,2008.
[21]潘田震, 邵学民. 对一起棉花堆垛自燃火灾的调查[J]. 消防科学与技术, 2004, 23(6): 604-605.
[22]顾海昕, 张永丰, 曹丽英. 不同温湿度下棉花分解气体测试实验研究[C]//2013中国消防协会科学技术年会论文集. 合肥,2013:298-304.
[23]HAGEN B C, FRETTE V, KLEPPE G, et al. Onset of smoldering in cotton: effects of density [J]. Fire Safety Journal, 2011, 46(3):73-80.

备注/Memo

备注/Memo:
收稿日期:2019-02-28
第一作者:章文义(1972-),男,博士研究生,主要从事爆炸防控技术教学科研工作。E-mail:171355553@qq.com
通信作者:郑俊杰(1973-),女,高级工程师,主要从事含能材料方面的研究。E-mail:839829396@qq.com
更新日期/Last Update: 2019-05-17