[1]孟子纯①,仲倩①②,徐森①②,等.乳化炸药最小自持燃烧压力的影响因素研究[J].爆破器材,2018,47(02):12-16.[doi:10.3969/j.issn.1001-8352.2018.02.003]
 MENG Zichun,ZHONG Qian,XU Sen,et al.Research on Influencing Factors of Minimum Burning Pressure of Emulsion Explosives[J].EXPLOSIVE MATERIALS,2018,47(02):12-16.[doi:10.3969/j.issn.1001-8352.2018.02.003]
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乳化炸药最小自持燃烧压力的影响因素研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
47
期数:
2018年02
页码:
12-16
栏目:
基础理论
出版日期:
2018-03-23

文章信息/Info

Title:
Research on Influencing Factors of Minimum Burning Pressure of Emulsion Explosives
文章编号:
5210
作者:
孟子纯;仲倩①②;徐森①②;刘大斌①②;田曜恺;李文海
①南京理工大学化工学院(江苏南京,210094)
②国家民用爆破器材质量监督检验中心(江苏南京,210094)
Author(s):
MENG Zichun ZHONG Qian①② XU Sen①② LIU Dabin①② TIAN Yaokai LI Wenhai
①School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
②National Quality Supervision and Inspection Center for Industrial Explosive Materials (Jiangsu Nanjing, 210094)
关键词:
安全工程乳化炸药最小自持燃烧压力水的质量分数消焰剂
Keywords:
safety engineering emulsion explosives minimum burning pressure water content flame inhibitor
分类号:
TQ56
DOI:
10.3969/j.issn.1001-8352.2018.02.003
文献标志码:
A
摘要:
为研究乳化炸药能发生自持燃烧的最低压力(MBP)的影响因素,通过压力容器研究6种不同配方乳化炸药的MBP。结果表明:乳化炸药中水质量分数分别为9.0%、10.0%、11.0%、15.0%时,在空气中测得乳化炸药的MBP的平均值分别为1.02、1.33、1.76 MPa和4.88 MPa,表明随着配方中水质量分数的增加,乳化炸药的MBP相应变大,即水质量分数对乳化炸药的MBP有显著影响。煤矿许用乳化炸药的试验结果表明,消焰剂含量的改变对乳化炸药的MBP无显著影响。当试验气氛改为氮气时,水质量分数为9.0%、10.0%的煤矿许用乳化炸药的MBP平均值分别为1.77、1.95 MPa,由此可见,测试气氛的改变对煤矿许用乳化炸药的MBP有一定影响,在氮气气氛中的MBP高于在空气气氛中的MBP。
Abstract:
In order to research the influencing factors on minimum burning pressure (MBP) of emulsion explosives, MBP of six kinds of emulsion explosives have been tested by pressurized vessel. Results show that the average MBP of emulsion explosives are 1.02, 1.33, 1.76 MPa and 4.88 MPa while the mass fraction of water are 9.0%, 10.0%, 11.0%, and 15.0%. It indicates that water content had a significant effect on the MBP of emulsion explosives, and the MBP of emulsion explosives increases linearly with water content. Results of coalmining permissible emulsion explosives show that the content of flame inhibitor has minor effect on the MBP of emulsion explosives. When the test atmosphere are nitrogen, the average MBP of coal-mining permissible emulsion explosives are 1.77 MPa and 1.95 MPa while the mass fraction of water are 9.0% and 10.0%. It can be seen that different test atmosphere has certain influence on the results of coal-mining permissible emulsion explosives. MBP of coal-mining permissible emulsion explosives measured in nitrogen is slightly higher than that measured in air.

参考文献/References:

[1]赵杰.对连续式乳化炸药生产工艺中泵送过程安全及质量问题的探讨[J]. 爆破器材, 2001,30 (4):8-12.
ZHAO J.An investigation of safety and product guality in pumping procedure in continuous technology of emulsion[J]. Explosive Materials,2001,30(4):8-12.
[2]CHAN S K, TURCOTTE R. Empirical correlation of minimum burning pressures of ammonium nitrate emulsions[J]. Propellants Explosives Pyrotechnics, 2016, 41(2):207-211.
[3]TURCOTTE R, GOLDTHORP S, BADEEN C M, et al. Influence of physical characteristics and ingredients on the minimum burning pressure of ammonium nitrate emulsions[J]. Propellants, Explosives, Pyrotechnics, 2010, 35(3): 233-239.
[4]汪旭光. 乳化炸药[M]. 北京:冶金工业出版社, 1986:181-184.
WANG X G.Emulsion explosive[M].Beijing:Metallurgical Industry Press,1986:181-184.
[5]徐志祥. 乳化炸药泵送过程热安全性研究[D]. 南京:南京理工大学, 2014.
 XU Z X. Research on thermal safety of emulsion explosive of pumping process[D]. Nanjing:Nanjing University of Science and Technology,2014.
[6]HIROSAKI Y, SUZUKI S, TAKAHASHI Y, et al. Burning characteristics of emulsion explosives (I):pressurized  vessel test[J]. Journal of Japan Explosives Society, 2000, 61:124128.
[7]吕春绪. 工业炸药理论[M]. 北京: 兵器工业出版社, 2003: 38-41.
[8]VARMA M, PANDEY M, GUPTA B L. Pressure dependence of thermal decomposition of ammonium nitrate oxidizer[J]. Journal of the India Chemical Society, 2003, 80(5):569-574.
[9]XU Z X, LIU D B, HU Y T. Investigation of ammonium nitrate based emulsion ignition characteristic[J]. Journal of Loss Prevention in the Process Industries, 2013, 26(6): 994-1001.
[10]TURCOTTE R, GOLDTHORP S, BADEEN C M, et al. Hot-wire ignition of AN-based emulsions[J]. Propellants, Explosives, Pyrotechnics, 2008, 33(6): 472-481.
[11]CHAN S K, TURCOTTE R. Onset temperature in hot wire ignition of ANbased emulsions[J]. Propellants, Explosives, Pyrotechnics, 2009, 34(1): 41-49.
[12]TURCOTTE R, UNDERWOOD B. Compression-ignition hazards in explosives pumping operations[C]//28th International Pyrotechnics Seminar. Adelaide, South Australia, 2001.
[13]GOLDTHORP S, BADEEN C M, TURCOTTE R, et al. The effect of common formulation changes on the minimum burning pressure of emulsion explosives and their precursors[C]//Combustion Institute/Canadian Section Spring Technical Meeting. Ottawa, Canada, 2010.
[14]GOLDTHORP S, TURCOTTE R, BADEEN C M, et al. Minimum pressure for sustained combustion in AN-based emulsions[C]//35th International Pyrotechnics Seminar. Fort Collins, Colorado,USA, 2008.
[15]SINDITSKII V P, EGORSHEV V Yu, LEVSHENKON A I,et al. Ammonium nitrate: combustion mechanism and the role of additives[J]. Propellants, Explosives, Pyrotechnics, 2005, 30(4):269-280.
[16]BADEEN C M, GOLDTHORP S, TURCOTTE R, et al. Effect of formulation changes on the minimum burning pressure of ammonium nitrate emulsions[C]//37th International Pyrotechnics Seminar.Reims, France, 2011.
[17]TURCOTTE R, GOLDTHORP S, BADEEN C M, et al. Behavior of AN-based emulsions in hotwire ignition experiments[C]//34th International Pyrotechnics Seminar. Beaune, France, 2007.
[18]WANG J. Ignition and combustion characteristics of emulsion explosives under pressure[D]. New Mexico:New Mexico Institute of Mining and Technology, 1991.
[19]CHAN S K. Quantitative hazard testing techniques for water-based explosives[C]//International Symposium on Pyrotechnics and Explosives. Beijing, 1987.
[20]TURCOTTE R, LIGHTFOOT P D, BADEEN C M, et al. A pressurized vessel test to measure the minimum burning pressure of waterbased explosives[J]. Propellants, Explosives, Pyrotechnics, 2005, 30(2): 118-126.

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备注/Memo

备注/Memo:
收稿日期:2017-08-31
基金项目:工信部安全专项
作者简介:孟子纯(1993-),男,硕士研究生,主要从事乳化炸药的安全性研究。E-mail:736093311@qq.com
通信作者:仲倩(1981-),女,主要从事含能材料的安全性研究。E-mail:bh4rbc@163.com
更新日期/Last Update: 2018-03-23