[1]张凯铭①,倪欧琪①②,俞珍权②,等.醇胺乳化剂的合成及其在乳化炸药中的应用[J].爆破器材,2013,42(04):6-9.[doi:10.3969/j.issn.1001-8352.2013.04.002]
　ZHANG kaiming,NI Ouqi,YU zhenquan,et al.Synthesis of Alkylol Amine Emulsifiers and Their Application in Emulsion Explosive[J].EXPLOSIVE MATERIALS,2013,42(04):6-9.[doi:10.3969/j.issn.1001-8352.2013.04.002]
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醇胺乳化剂的合成及其在乳化炸药中的应用()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
42
期数:
2013年04
页码:
6-9
栏目:
基础理论
出版日期:
2013-08-20

文章信息/Info

Title:
Synthesis of Alkylol Amine Emulsifiers and Their Application in Emulsion Explosive
文章编号:
4615
作者:
张凯铭①; 倪欧琪①②; 俞珍权②; 唐淑娟②
①南京理工大学化工学院(江苏南京，210094)
②国家民用爆破器材质量监督检验中心(江苏南京，210094)
 
Author(s):
ZHANG kaiming①;  NI Ouqi①②;  YU zhenquan②; TANG Shujuan②
①School of Chemical Engineering, Nanjing University of science and technology (Jiangsu Nanjing, 210094)
 ②National Quality Supervision and Inspection Center for Industrial Explosive Materials (Jiangsu Nanjing, 210094)
关键词:
乳化剂; 聚异丁烯丁二酸酐; 三乙醇胺; 乳化炸药
Keywords:
emulsifier;  triethanolamine;  ethanolamine;  emulsion explosive
分类号:
TD235.2+1 TQ560.72
DOI:
10.3969/j.issn.1001-8352.2013.04.002
文献标志码:
A
摘要:
采用聚异丁烯丁二酸酐分别与三乙醇胺和乙醇胺反应合成了两种醇胺乳化剂。用乳化剂制备了乳化基质，并测试了乳化基质的微观结构、黏度和储存稳定性。通过测定乳化剂在乳化炸药中的相容性及含醇胺乳化剂乳化炸药的爆轰性能，对它们在乳化炸药中的应用进行了研究。相比于失水山梨醇单油酸酯和聚异丁烯丁二酰亚胺类乳化剂，两种醇胺乳化剂均体现出较强的乳化能力，制备的乳化炸药具有更长的储存期。在两种醇胺乳化剂中，聚异丁烯丁二酸酐—三乙醇胺乳化剂显示了更强的乳化性能。
Abstract:
Two alkylol amine emulsifiers were synthesized through the reaction of polyisobutylene succinic anhydride with triethanolamine and ethanolamine, respectively. They were then used for the preparation of emulsion bases and tested in terms of microstructure, viscosity and storage stability. Their compatibility with emulsion explosive and the detonation velocity of modified emulsion explosive were inspected for their practical applications. The results show that both of alkylol amine emulsifiers have good emulsifying capacity and the emulsion explosives made from them have longer storage period in comparison with T152 and Span80. For this two emulsifiers, polyisobutylene succinic anhydridetriethanolamine emulsifier had better emulsifying ability.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2013-03-28
作者简介：张凯铭（1983~），男，博士，主要从事工业炸药相关研究。E-mail：cggzkm@163.com
通信作者：倪欧琪（1953~），男,教授,主要从事工业炸药相关研究。E-mail:niouqimmm@163.com
更新日期/Last Update: 2013-08-25