[1]王晨晨,王伯良,黄菊,等.混合炸药中RDX对其热安全性的影响研究[J].爆破器材,2012,41(02):8-10、15.
 WANG Chenchen,WANG Boliang,HUANG Jü,et al.Influence of RDX on Thermal Safety of Composite Explosive[J].EXPLOSIVE MATERIALS,2012,41(02):8-10、15.
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混合炸药中RDX对其热安全性的影响研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
41
期数:
2012年02
页码:
8-10、15
栏目:
基础理论
出版日期:
2012-04-20

文章信息/Info

Title:
Influence of RDX on Thermal Safety of Composite Explosive
文章编号:
4432
作者:
王晨晨王伯良黄菊刘伟
南京理工大学化工学院(江苏南京,210094)
Author(s):
WANG Chenchen WANG Boliang HUANG Jü LIU Wei
School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
DSCRDX热分解性能热安全性
Keywords:
DSC RDX thermal decomposition thermal safety
分类号:
TD235.2+1 TQ560.7
文献标志码:
A
摘要:
采用差示扫描量热仪(DSC)研究了RDX对混合炸药体系的热分解性能的影响,用Kissinger法和Ozawa法计算并分析了其热分解动力学参数。结果表明,加入RDX后的混合炸药体系的初始反应温度、峰温、表观活化能、指前因子、自加速分解温度、热爆炸临界温度均随着RDX含量的增大而降低,说明了RDX的加入使混合炸药的热安全性变差了。
Abstract:
The influence of RDX on the thermal decomposition behaviors of composite explosive system were studied by differential scanning calorometry (DSC), and the thermal decomposition kinetic parameters were calculated by Kissinger and Ozawa methods. It was found that the initial and the peak temperature, the apparent activation energy, frequency factor, selfaccelerating decomposition and critical temperature of the thermal explosion all decrease with the increase of RDX amount. The results showed that the thermal safety become lower after the adding of RDX.

参考文献/References:

[1]《炸药理论》编写组.炸药理论[M].北京:国防工业出版社,1982:68~74.
[2]张柏生.火药燃烧导论[M].南京:华东工学院,1988:183~201.
[3]高大元,何松伟,沈永兴,等.GI—920炸药的热分解动力学研究[J].含能材料,2008,16(1):1~4.
[4]刘子如,阴翠梅,刘艳,等.RDX和HMX的热分解Ⅱ:动力学参数和动力学补偿效应[J].火炸药学报,2004,27(4):72~75,79.
[5]赵永涛,白春华,张奇,等.温压弹爆炸超压场实验研究[J].爆破,2004,21(4):15~17.
[6]徐皖育,何卫东,张颖.含RDX高能太根发射药的热分解性能[J].火炸药学报,2006,29(2):63~65.
[7]孙业斌,惠君明,曹欣茂.军用混合炸药[M].北京:兵器工业出版社,1995.
[8]胡荣祖,史启祯.热分析动力学[M].北京:科学出版社,2001:127~132.
[9]周新利,刘祖亮,吕春绪.岩石乳化炸药绝热分解安全性的加速量热法分析[J].火炸药学报,2003,26(2):62~65.
[10]李建军,汪旭光,欧育湘,等.乳化炸药热分解动力学研究[J].北京理工大学学报,1996,16(6):636~642.

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备注/Memo

备注/Memo:
收稿日期:2011-11-28
基金项目:国防科工局火炸药专项
作者简介:王晨晨(1987~),女,硕士研究生,主要从事混合炸药的固体化工艺研究。
通讯作者:王伯良(1964~),男,教授,主要从事燃料空气炸药的工艺与理论研究。
更新日期/Last Update: 2012-04-27