[1]朱晶,谢兴华,罗伟,等.含有二价铁离子乳化炸药基质的热分解动力学研究[J].爆破器材,2011,40(03):8-10.
　Zhu Jing,Xie Xinghua,Luo Wei,et al.Thermal Decomposition Kinetics of Emulsion Explosive Containing Ferrous Ion[J].EXPLOSIVE MATERIALS,2011,40(03):8-10.
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含有二价铁离子乳化炸药基质的热分解动力学研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
40
期数:
2011年03
页码:
8-10
栏目:
基础理论
出版日期:
2011-06-20

文章信息/Info

Title:
Thermal Decomposition Kinetics of Emulsion Explosive Containing Ferrous Ion
文章编号:
4356
作者:
朱晶; 谢兴华; 罗伟; 邸云信
（安徽理工大学化学工程学院,安徽淮南232001）
Author(s):
Zhu Jing;  Xie Xinghua;  Luo Wei;  Di Yunxing
School of Chemical Engineering, Anhui University of Science and Technology (Anhui Huainan, 231001)
关键词:
乳化炸药; TG—DSC; 指前因子; 活化能
Keywords:
emulsion explosive;  TG—DSC;  pre-exponential factor;  activation energy
分类号:
TJ450.1
文献标志码:
A
摘要:
利用TG-DSC研究乳化炸药基质和含有二价铁离子的乳化炸药基质的热分解过程。利用Kissinger法计算了2种样品的活化能E和指前因子A，比较二者的活化能E。研究表明Fe2+对乳化炸药基质的热分解反应具有一定的催化作用，Fe2+能够使乳化基质的热分解反应受温度的影响更为显著。
Abstract:
Thermal decomposition of the emulsion matrix and that of containing divalent iron was studied by TG-DSC. The activation energy E and pre-exponential factor A of the two samples were calculated by the Kissinger method, and the two activation energy E was compared as well. Rusults indicate that Fe2+shows some catalysis to the thermal decomposition of emulsion matrix, and the ion could enhance the influence of the temperature on thermal decomposition of the emulsion matrix.

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2011-01-23 基金项目：安徽省科技厅安徽省攻关项目（07010302189）、安徽省教育厅重点项目（KJ2010A102）作者简介：朱晶（1984~），女，硕士，从事民用爆破器材及技术方面的研究。
更新日期/Last Update: 2011-06-27