[1]李俊杰①②③,董云①③,赵华平①③,等.基于EPE-3021高分子乳化剂的混装一体化油相配方设计及性能[J].爆破器材,2026,55(01):25-31.[doi:10.3969/j.issn.1001-8352.2026.01.004]
　LI Junjie,DONG Yun,ZHAO Huaping,et al.Formula Design and Performances of Mixed Integrated Oil Phase Based on EPE-3021 Polymeric Emulsifier[J].EXPLOSIVE MATERIALS,2026,55(01):25-31.[doi:10.3969/j.issn.1001-8352.2026.01.004]
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基于EPE-3021高分子乳化剂的混装一体化油相配方设计及性能()

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
55
期数:
2026年01
页码:
25-31
栏目:
爆炸材料
出版日期:
2026-01-19

文章信息/Info

Title:
Formula Design and Performances of Mixed Integrated Oil Phase Based on EPE-3021 Polymeric Emulsifier
文章编号:
6059
作者:
李俊杰①②③; 董云①③; 赵华平①③; 刘大维①③④; 周宇①; 陈世雄①③④; 刘承美②
①易普力股份有限公司（湖南长沙，410000）
②华中科技大学化学与化工学院（湖北武汉，430074）
③安全绿色民爆技术与智能装备湖南省工程研究中心（湖南长沙，410000）
④南京理工大学化学与化工学院（江苏南京，210094）
Author(s):
LI Junjie①②③;  DONG Yun①③;  ZHAO Huaping①③;  LIU Dawei①③④;  ZHOU Yu①;  CHEN Shixiong①③④;  LIU Chengmei②
① E-Pulse Co., Ltd. (Hu’nan Changsha, 410000)
② School of Chemistry and Chemical Engineering, Huazhong University of Science and Technology (Hubei Wuhan, 430074)
③ Hu’nan Provincial Engineering Research Center for Safe and Green Civil Explosive Technology and Intelligent Equipment (Hu’nan Changsha, 410000)
④ School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
混装; 一体化; 油相; 乳胶基质; 黏温特性; 储存稳定性
分类号:
TQ560.1；TQ423
DOI:
10.3969/j.issn.1001-8352.2026.01.004
文献标志码:
A
摘要:
为了研究基于EPE-3021高分子乳化剂的混装一体化油相配方乳化炸药性能，采用不同型号的基础油和SO-1合成油组合，制备了8种混装一体化油相配方，通过黏度测试、粒径分布分析和常温储存实验，系统评价了各油相配方制备的乳胶基质的性能。结果表明：以BO-2和BO-1基础油为主要组分的配方制备的乳胶基质的黏度较柴、机油配方明显增大，SO-1合成油的添加可有效地降低乳胶基质的黏度，但会在一定程度上影响储存稳定性；所有配方的乳胶基质的析晶面积均小于10%，具有良好的储存稳定性。综合考虑乳胶基质的稳定性和黏度性能，推荐E3、E7、E8配方作为乳化炸药混装一体化油相的优选方案。

参考文献/References:

［1］ZHANG K M, ZHAO H R. Perspectives in the stability of emulsion explosive ［J］. Advances in Colloid and Interface Science, 2022, 307: 102745.

［2］ZHAO H R, WU J, XU M X, et al. Advances in the rheology of emulsion explosive ［J］. Journal of Molecular Liquids, 2021, 336: 116854.
［3］程扬帆, 朱守军, 李子涵, 等. 钻孔爆破条件下乳化炸药的压力减敏现象研究进展 ［J］. 金属矿山, 2023(5): 77-85.
CHENG Y F, ZHU S J, LI Z H, et al. Study progresses on the pressure desensitization of emulsion explosives in the drilling and blasting operation ［J］. Metal Mine, 2023(5): 77-85.
［4］卢军. 乳化炸药生产过程的质量控制［J］. 当代化工研究, 2021(8): 165-166.
LU J. Quality control of emulsion explosive production process ［J］.Modern Chemical Research, 2021(8): 165-166.
［5］谢瑶. 矿山现场混装乳化炸药中一体化油相应用研究［J］.世界有色金属, 2022(23): 229-231.
XIE Y. Study on application of integrated oil in field mixed emulsion explosives ［J］.World Nonferrous Metals, 2022(23): 229-231.
［6］夏光. 工业炸药现场混装技术应用与影响因素研究［J］. 煤矿爆破, 2023, 41(1): 23-26.
XIA G. Study on application and influence factors of industrial explosive field mixing technology ［J］. Coal Mine Blasting, 2023, 41(1): 23-26.
［7］何楠, 吴龙祥. 我国乳化炸药工艺及设备的现状与发展趋势［J］. 爆破器材, 2006, 35(3): 17-21.
HE N, WU L X. Present condition and development prospects of the technology and equipment of emulsion explosives in China ［J］. Explosive Materials, 2006, 35(3): 17-21.
［8］何祥, 刘锋, 陈皓楠, 等. 不同油相材料对现场混装乳化炸药抗挤压能力的影响［J］. 火炸药学报, 2022,45(3): 425-431.
HE X, LIU F, CHEN H N, et al. Effect of different oil phase materials on the anti-extrusion ability of on-site mixed emulsion explosive ［J］. Chinese Journal of Explosives & Propellants, 2022, 45(3): 425-431.
［9］齐红雪, 刘大维, 代泽军, 等. 混装乳化炸药在高寒高海拔地区的应用研究［J］. 爆破, 2022, 39(4): 144-147, 163.
QI H X, LIU D W, DAI Z J, et al. Application study of mixed emulsion explosive in cold and high-altitude area ［J］. Blasting, 2022, 39(4): 144-147, 163.
［10］管众, 韩军, 张春风, 等. 烷基芳烃润滑基础油的合成及应用［J/OL］. 化工进展, 2025: 1-13. ［2025-07-18］. https://doi.org/10.16085/j.issn.1000-6613.2025-0709.
GUAN Z, HAN J, ZHANG C F, et al. Synthesis and application of alkyl aromatic lubricating base oils［J/OL］.Chemical Industry and Engineering Progress, 2025: 1-13.［2025-07-18］. https://doi.org/10.16085/j.issn.1000-6613.2025-0709.
［11］李宏兵. 乳胶远程配送系统相关技术研究［J］. 爆破, 2010, 27(2): 88-91.
LI H B. Research on related techniques of long-distance deliverying system of emulsion matrix［J］. Blasting, 2010, 27(2): 88-91.
［12］苏明阳. 一种适宜远程配送乳胶基质的研究［J］. 工程爆破, 2014, 20(6): 43-46, 60.
SU M Y. Research on long-distance delivery emulsion matrix ［J］. Engineering Blasting, 2014, 20(6): 43-46, 60.
［13］闫国斌, 汪旭光, 王尹军. 乳化炸药微观结构对其宏观性能的影响分析［J］. 工程爆破, 2016, 22(5): 40-44.
YAN G B, WANG X G, WANG Y J. Influence of microstructure of emulsion explosive on macro performance ［J］. Engineering Blasting, 2016, 22(5): 40-44.
［14］AL-SABAGH A M, HUSSIEN M A, MISHRIF M R, et al. Preparation and investigation of emulsion explosive matrix based on gas oil for mining process ［J］. Journal of Molecular Liquids, 2017, 238: 198-207.
［15］魏国, 刘锋, 吴攀宇, 等. 油相配比对现场混装乳胶基质黏度及爆轰参数的影响［J］. 工程爆破, 2022,28(2): 105-110.
WEI G, LIU F, WU P Y, et al. Effect of oil phase ratio on viscosity and detonation parameters of on-site mixed emulsion matrix ［J］. Engineering Blasting, 2022, 28(2): 105-110.
［16］缪志军. 乳化炸药油相特性的研究［D］. 淮南: 安徽理工大学, 2016.
MIAO Z J. Study on emulsion explosive oil phase characteristics ［D］. Huainan: Anhui University of Science and Technology,2016.
［17］ZHANG K M, NI O Q, HUANG J D, et al. A facile and efficient method to investigate the effect of the nature of surfactant and continuous phase on the performance of emulsion explosive ［J］. Journal of Molecular Liquids, 2018, 249: 203-210.
［18］SHARU B K, SIMON G P, CHENG W L, et al. Development of microstructure and evolution of rheological characteristics of a highly concentrated emulsion during emulsification ［J］. Colloids and Surfaces. A, Physicochemical and Engineering Aspects, 2017, 532: 342-350.
［19］IVAN B, SZANKA I, SZABO A, et al. Chapter 2: Endfunctional polyisobutylenes by quasiliving carbocationic polymerization and bi- and multicomponent macromolecular architectures therefrom ［J］. Macromolecular Engineering, 2021: 23-49.
［20］吴攀宇, 刘锋, 魏国, 等. 动态挤压对现场混装乳化炸药稳定性的影响［J］. 含能材料, 2021, 29(12): 1160-1167.
WU P Y, LIU F, WEI G, et al. Influence of dynamic extrusion on stability of field mixed emulsion explosive［J］. Chinese Journal of Energetic Materials, 2021, 29(12): 1160-1167.
［21］魏国, 刘锋, 吴攀宇, 等. 振动作用对现场混装乳化炸药稳定性的影响［J］. 火炸药学报, 2022, 45(1): 90-96.
WEI G, LIU F, WU P Y, et al. Influence of vibration on the stability of on-site mixed emulsion explosive ［J］. Chinese Journal of Explosives & Propellants, 2022, 45(1): 90-96.
［22］王璐, 刘天生. 低温乳化炸药稳定性实验研究［J］. 工程爆破, 2014, 20(2): 40-42, 56.
WANG L, LIU T S. Experimental study on the stability of emulsion explosive emulsifild at low temperature ［J］. Engineering Blasting, 2014, 20(2): 40-42, 56.
［23］周建敏, 汪旭光, 周桂松, 等. 高稳定性现场混装炸药爆炸性能试验研究［J］. 矿业研究与开发, 2020, 40(4): 41-45.
ZHOU J M, WANG X G, ZHOU G S, et al. Experimental study on explosive performance of high-stability emulsion explosive ［J］. Mining Research and Development, 2020, 40(4): 41-45.
［24］弓启祥. 乳胶基质体系分散相粒度分布研究［J］. 露天采矿技术, 2012(3): 94-95, 98.
GONG Q X. Study on dispersed phase size distribution of the emulsion matrix system ［J］. Opencast Mining Technology, 2012(3): 94-95, 98.
［25］曹耿, 但小凤, 程昌敬, 等. 煤油/水体系乳状液的制备及其稳定性研究［J］. 西南民族大学学报(自然科学版), 2014,40(2): 228-232.
CAO G, DAN X F, CHENG C J, et al. The preparation and stability of kerosene/water emulsion ［J］. Journal of Southwest Minzu University (Natural Science Edition), 2014, 40(2): 228-232.
［26］MASALOVA I, TSHILUMBU N N, MAMEDOV E, et al. Stabilisation of highly concentrated water-in-oil emulsions by polyhedral oligomeric silsesquioxane nanomolecules［J］. Journal of Molecular Liquids, 2019, 279: 351-360.

备注/Memo

备注/Memo:
收稿日期：2025-07-28
第一作者：李俊杰（1990—），男，硕士，高级工程师,主要从事工业炸药材料与工艺的研究。E-mail: junjie_li@hust.edu.cn
通信作者：刘承美（1967—），男，博导，教授，主要从事高分子化工材料方面的研究。E-mail: 282455590@qq.com
更新日期/Last Update: 2026-01-19