[1]解佳妮,徐林冲,闫华,等.耐高温射孔弹用LLM-105基黏结炸药的制备与性能[J].爆破器材,2025,54(06):34-38，44.[doi:10.3969/j.issn.1001-8352.2025.06.005]
　XIE Jiani,XU Linchong,YAN Hua,et al.Preparation and Properties of LLM-105 Based Bonded Explosives for High Temperature Resistant Perforating Charge[J].EXPLOSIVE MATERIALS,2025,54(06):34-38，44.[doi:10.3969/j.issn.1001-8352.2025.06.005]
点击复制

耐高温射孔弹用LLM-105基黏结炸药的制备与性能()
分享到：

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
54
期数:
2025年06
页码:
34-38，44
栏目:
爆炸材料
出版日期:
2025-12-09

文章信息/Info

Title:
Preparation and Properties of LLM-105 Based Bonded Explosives for High Temperature Resistant Perforating Charge
文章编号:
6005
作者:
解佳妮; 徐林冲; 闫华; 刘波; 李聪颖; 王卫星
山西北化关铝化工有限公司（山西运城，044500）
Author(s):
XIE Jiani;  XU Linchong;  YAN Hua;  LIU Bo;  LI Congying;  WANG Weixing
Shanxi Beihua Guanlv Chemical Co., Ltd. (Shanxi Yuncheng, 044500)
关键词:
含能材料; 晶形; LLM-105炸药; 耐热性; 射孔弹
分类号:
TQ560.5
DOI:
10.3969/j.issn.1001-8352.2025.06.005
文献标志码:
A
摘要:
为提高超高温油气井的采收率，提高射孔弹的穿孔性能，提出了一种射孔弹用耐高温的高聚物黏结炸药（PBX）的制备方法。首先，通过重结晶技术制备了长棒状和块状2种晶形的2,6-二氨基-3,5-二硝基吡嗪-1-氧化物（LLM-105）单质炸药；其次，采用理论计算确定了LLM-105基PBX的配方；再次，利用水悬浮法制备了LLM-105基PBX，并对热稳定性进行测试；最后，采用地面静破甲试验对所制备PBX的爆炸性能进行测试。结果显示：LLM-105基PBX的松装密度达到0.80 g/cm3以上，装填密度达到1.75 g/cm3；与以HNS为基的S992和以PYX为基的Y971这2种炸药相比，所制备的LLM-105基PBX装药的穿深提高了16%以上，具有良好的穿孔性能。

参考文献/References:

［1］朱中钦, 邵艳丽, 林秋汉, 等. 耐热炸药六硝基茋的制备及应用研究进展［J］. 火炸药学报, 2018, 41(4): 319-325.

ZHU Z Q, SHAO Y L, LIN Q H, et al. Research progress in the preparation and application of hexanitrostilbene ［J］. Chinese Journal of Explosives & Propellants, 2018, 41(4): 319-325.
［2］LIU S T, LI Y, HAN D C, et al. Thermal runaway procedure and residue analysis of LiFePO4 batteries with different charging states under nail penetrating ［J］. Journal of Applied Electrochemistry, 2024, 54(7): 1485-1500.
［3］张哲, 雷红兵, 郝嘎子, 等. TATB对AP的包覆降感［J］. 火炸药学报, 2019, 42(3): 284-288.
ZHANG Z, LEI H B, HAO G Z, et al. Desensitization of AP coated with TATB ［J］. Journal of Explosives & Propellants, 2019, 42(3): 284-288.
［4］CHANG S J, WANG J N, WU H, et al. Investigation into the crystal morphology and acidity of LLM-105 in recrystallization ［J］. Journal of Energetic Materials, 2024, 42(2): 249-272.
［5］李凤生, 刘杰. 微纳米含能材料研究进展［J］. 含能材料, 2018, 26(12): 1061-1073.
LI F S, LIU J. Advances in micro-nano energetic materials［J］. Chinese Journal of Energetic Materials, 2018, 26(12): 1061-1073.
［6］SIKDER A K, SIKDER N. A review of advanced high performance, insensitive and thermally stable energetic materials emerging for military and space applications ［J］. Journal of Hazardous Materials, 2004, 112(1/2): 1-15.
［7］WANG H J, LIU S S. Study on coating and technological conditions of LLM-105 ［J］. Advanced Materials Research, 2011, 328/329/330: 1161-1166.
［8］陈鹏万, 黄风雷. 含能材料损伤理论及应用［M］. 北京: 北京理工大学出版社, 2006.
［9］WANG J K, SUN X Y, GAO C, et al. Pressure-modulated dissolution behavior of LLM-105 crystals in hightemperature water ［J］. ACS Omega, 2023, 8(27): 24654-24662.
［10］LAN Q H, ZHANG H G, NI Y X, et al. Thermal decomposition mechanisms of LLM-105/HTPB plastic-bonded explosive: ReaxFF-lg molecular dynamics simulations ［J］. Journal of Energetic Materials, 2023, 41(3): 269-290.
［11］MIRKARIMI P B, PEASE S T, MOUA Y, et al. Mechanical and thermomechanical properties of an LLM-105 based PBX high explosive with and without accelerated aging ［J］. Propellants, Explosives, Pyrotechnics, 2023, 48(7): e202200337.
［12］赖康华, 雷新华, 赵世华, 等. LLM-105炸药在超高温射孔弹中的应用［J］. 爆破器材, 2018, 47(3): 42-45.
LAI K H, LEI X H, ZHAO S H, et al. Application of LLM-105 explosive in ultra-high temperature perforating charge ［J］. Explosive Materials, 2018, 47(3): 42-45.
［13］刘梦雅, 徐聪, 侯聪花, 等. CL-20/LLM-105/Estane-5703复合粒子的性能研究［J］. 火工品, 2022(5): 46-50.
LIU M Y, XU C, HOU C H, et al. Study on the properties of CL-20/LLM-105/Estane 5703 composite particles ［J］. Initiators & Pyrotechnics, 2022(5): 46-50.
［14］李玉斌, 黄辉, 李金山, 等. 一种含LLM-105的HMX基低感高能PBX炸药［J］. 火炸药学报, 2008, 31(5): 1-4.
LI Y B, HUANG H, LI J S, et al. A new HMX-based low-sensitive high energy PBX explosive containing LLM-105 ［J］. Chinese Journal of Explosives & Propellants, 2008, 31(5): 1-4.
［15］詹乐武, 张一帆, 李营, 等. 超声辅助微流控技术制备纳米LLM-105［J］. 含能材料, 2022, 30(5): 446-450.
ZHAN L W, ZHANG Y F, LI Y, et al. Preparation of nano-LLM-105 by ultrasonicassisted microfluidic technology ［J］. Chinese Journal of Energetic Materials, 2022, 30(5): 446-450.
［16］谭迎新, 赵玉鑫, 张硕, 等. 2,6-二氨基-3,5-二硝基吡嗪-1-氧化物的热安全特性分析［J］. 爆破器材, 2021, 50(3): 13-18.
TAN Y X, ZHAO Y X, ZHANG S, et al. Thermal safety analysis of 2, 6-diamino-3, 5-dinitropyrazine-1-oxide ［J］. Explosive Materials, 2021, 50(3): 13-18.
［17］郭蓉, 杨志剑, 段晓惠, 等. LLM-105与高聚物黏结剂界面相互作用及力学性能的分子动力学模拟［J］. 含能材料, 2019, 27(8): 644-651.
GUO R, YANG Z J, DUAN X H, et al. Molecular dynamics simulations for interfacial interactions and mechanical properties of LLM-105 with polymers ［J］.Chinese Journal of Energetic Materials, 2019, 27(8): 644-651.
［18］单军辉, 周小清, 李洪珍, 等. 诱导期法研究过饱和度对LLM-105成核的影响［J］. 含能材料, 2020, 28(9): 841-847.
SHAN J H, ZHOU X Q, LI H Z, et al. Effect of supersaturation on nucleation of LLM-105 based on induction period measurement method ［J］. Chinese Journal of Energetic Materials, 2020, 28(9): 841-847.
［19］雷英春. TATB基钝感传爆药配方设计及制备研究［D］.太原: 中北大学, 2015.
LEI Y C. Formulation and preparation of insensitive booster based on TATB ［D］. Taiyuan: North University of China, 2015.
［20］ KAMLET M J, JACOBS S J. Chemistry of detonations. I. A simple method for calculating detonation properties of C—H—N—O explosives ［J］. The Journal of Chemical Physics, 1968, 48: 23-35.

相似文献/References:

[1]薛艳,任小明,解瑞珍,等.硅基含能材料爆炸性能研究[J].爆破器材,2011,40(05):12.
　XUE Yan,REN Xiaoming,XIE Ruizhen,et al.Explosion Properties of Nanosiliconbased Energetic Materials[J].EXPLOSIVE MATERIALS,2011,40(06):12.
[2]张涛,陈明华,贾昊楠,等.热分解动力学在含能材料中的应用[J].爆破器材,2013,42(06):52.[doi:10.3969/j.issn.1001-8352.2013.06.011]
　ZHANG Tao,CHEN Minghua,JIA Haonan,et al.Application of Thermal Decomposition Kinetics in Energetic Materials[J].EXPLOSIVE MATERIALS,2013,42(06):52.[doi:10.3969/j.issn.1001-8352.2013.06.011]
[3]陈言坤①,甄建伟①,武慧恩②,等.粒状发射药动态破碎研究进展[J].爆破器材,2014,43(01):41.[doi:10.3969/j.issn.1001-8352.2014.01.009]
　CHEN Yankun,ZHEN Jianwei,WU Huien,et al.Research Progress of Dynamic Fracture of Granular Propellant[J].EXPLOSIVE MATERIALS,2014,43(06):41.[doi:10.3969/j.issn.1001-8352.2014.01.009]
[4]马宁,苏杨,秦能,等.1L慢烤燃装置温场分布数值模拟与试验研究[J].爆破器材,2014,43(03):14.[doi:10.3969/j.issn.1001-8352.2014.03.004]
　MA Ning,SU Yang,QIN Neng,et al.Numerical Simulation and Experimental Study of Temperature Field Distribution in 1L Slow Cook-off Device[J].EXPLOSIVE MATERIALS,2014,43(06):14.[doi:10.3969/j.issn.1001-8352.2014.03.004]
[5]葛亚庆,许田田,杨君龙,等.5-氨基四唑/氧化铜气体发生剂燃烧性质的研究[J].爆破器材,2014,43(06):35.[doi:10.3969/j.issn.1001-8352.2014.06.008]
　GE Yaqing,XU Tiantian,YANG Junlong,et al.Study on Combustion Performance of 5Aminotetrazole/Copper Oxide Gasgenerating Agent[J].EXPLOSIVE MATERIALS,2014,43(06):35.[doi:10.3969/j.issn.1001-8352.2014.06.008]
[6]鲁学峰①,卫延安①②.N,N-双四唑胺的合成工艺改进与研究[J].爆破器材,2015,44(02):14.[doi:10.3969/j.issn.1001-8352.2015.02.004]
　LU Xuefeng,WEI Yanan.Study and Improvement of the Synthesis of N,N-Bis(1H-tetrazol-5-yl)amine[J].EXPLOSIVE MATERIALS,2015,44(06):14.[doi:10.3969/j.issn.1001-8352.2015.02.004]
[7]盛涤伦,陈利魁,朱雅红,等.耐高温起爆药叠氮化镉的合成与性能研究[J].爆破器材,2015,44(03):12.[doi:10.3969/j.issn.1001-8352.2015.03.003]
　SHENG Dilun,CHEN Likui,ZHU Yahong,et al.Synthesis and Performance of a Primary Explosive Resisting High Temperature Named Cadmium Azide[J].EXPLOSIVE MATERIALS,2015,44(06):12.[doi:10.3969/j.issn.1001-8352.2015.03.003]
[8]屈可朋,沈飞,肖玮,等.一种RDX基PBX炸药力学性能和本构关系研究[J].爆破器材,2015,44(03):31.[doi:10.3969/j.issn.1001-8352.2015.03.007]
　QU Kepeng,SHEN Fei,XIAO Wei,et al.Mechanical Behavior and Constitutive Model of one RDXbased PBX Explosive[J].EXPLOSIVE MATERIALS,2015,44(06):31.[doi:10.3969/j.issn.1001-8352.2015.03.007]
[9]李家宽,马小霞,胡艳,等.KNO3/GO复合含能材料的制备与表征[J].爆破器材,2016,45(02):1.[doi:10.3969/j.issn.1001-8352.2016.02.001]
　LI Jiakuan,MA Xiaoxia,HU Yan,et al.Preparation and Characterization of KNO3/GO Composite Energetic Materials[J].EXPLOSIVE MATERIALS,2016,45(06):1.[doi:10.3969/j.issn.1001-8352.2016.02.001]
[10]屈可朋,王晓峰,何超,等.撞击条件下分步压装装药的点火机理[J].爆破器材,2016,45(03):22.[doi:10.3969/j.issn.1001-8352.2016.03.005]
　QU Kepeng,WANG Xiaofeng,HE Chao,et al.Ignition Mechanism of Step Press Loading Charge under Impact Loading[J].EXPLOSIVE MATERIALS,2016,45(06):22.[doi:10.3969/j.issn.1001-8352.2016.03.005]

备注/Memo

备注/Memo:
收稿日期：2025-01-06
第一作者：解佳妮（1996—），女，硕士，工程师，主要从事混合炸药的工艺技术研究。E-mail: 957862249@qq.com
通信作者：闫华（1975—），女，正高级工程师，主要从事混合炸药的工艺技术研究。E-mail: Yanh2008.good@163.com
更新日期/Last Update: 2025-12-09