[1]王光兵①②,吴红波①,汪鑫齐①,等.含氨基添加剂的现场混装乳化炸药的性能研究[J].爆破器材,2025,54(06):39-44.[doi:10.3969/j.issn.1001-8352.2025.06.006]
 WANG Guangbing,WU Hongbo,WANG Xinqi,et al.Performances of Field-Mixed Emulsion Explosives Containing Amino Additives[J].EXPLOSIVE MATERIALS,2025,54(06):39-44.[doi:10.3969/j.issn.1001-8352.2025.06.006]
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含氨基添加剂的现场混装乳化炸药的性能研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
54
期数:
2025年06
页码:
39-44
栏目:
爆炸材料
出版日期:
2025-12-09

文章信息/Info

Title:
Performances of Field-Mixed Emulsion Explosives Containing Amino Additives
文章编号:
5998
作者:
王光兵①②吴红波汪鑫齐和铁柱邹宗山黄菓树李天浩
①安徽理工大学化工与爆破学院(安徽淮南,232001)
②保利民爆哈密有限公司(新疆哈密,839000)
Author(s):
WANG Guangbing①② WU Hongbo WANG Xinqi HE Tiezhu ZOU Zongshan HUANG Guoshu LI Tianhao
① School of Chemical and Blasting Engineering, Anhui University of Science and Technology (Anhui Huainan, 232001)
② Poly Explosive Hami Co., Ltd. (Xinjiang Hami, 839000)
关键词:
乳胶基质氨基添加剂稳定性抗振动
分类号:
TQ56; TD561
DOI:
10.3969/j.issn.1001-8352.2025.06.006
文献标志码:
A
摘要:
通过控制氨基添加剂的含量、利用振动台模拟运输车振动、光学显微镜观察、电导率仪测试、高低温循环箱试验、激光粒度仪试验和爆速测试试验,研究了不同含量的氨基添加剂对现场混装乳化炸药的稳定性和爆轰性能的影响。实验结果表明,氨基添加剂在炸药水相中形成的氢键能够使乳胶基质的结构更加稳定,降低了乳胶基质的电导率,减少了振动产生的析晶,增强了乳胶基质的抗颠簸性。乳胶基质经过高低温循环未发生奥氏熟化、聚合等现象,含氨基添加剂的乳胶基质的粒径相对较小。现场混装乳化炸药中,随着氨基添加剂的含量增高,炸药的爆速呈现先升高、后降低的趋势。氨基添加剂质量分数为0.2%时,爆速最高,达到4 208.5m/s。

参考文献/References:

[1]ZHAO H R, ZHANG K M. The structure recovery capacity of highly concentrated emulsions under shear flow via studying their rheopexy [J]. Journal of Dispersion Science and Technology, 2018, 39(7): 970-976.

[2]MASALOVA I, MALKIN A Y. Peculiarities of rheological properties and flow of highly concentrated emulsions:the role of concentration and droplet size [J]. Colloid Journal, 2007, 69(2): 185-197.
[3]TSHILUMBU N N, MASALOVA I. Stabilization of highly concentrated emulsions with oversaturated dispersed phase: effect of surfactant/particle ratio [J]. Chemical Engineering Research and Design, 2015, 120: 216-233.
[4]匡照. 氮化铝含量对现场混装乳化炸药性能的影响[D]. 淮南: 安徽理工大学, 2024.
KUANG Z. Effect of aluminum nitride content on the performance of field-mixed emulsion explosives [D]. Huainan: Anhui University of Science and Technology, 2024.
[5]潘长鑫, 刘锋, 毕如洁, 等.密闭环境中压力对现场混装乳化炸药微观结构和热稳定性的影响[J].含能材料, 2024, 32(10): 1080-1090.
PAN C X, LIU F, BI R J, et al. Effect of confined environment pressure on the microstructure and thermal stability of on-site mixed emulsion explosives [J]. Chinese Journal of Energetic Materials, 2024, 32(10): 1080-1090.
[6]陈皓楠. 酰化磷脂复合乳化剂对现场混装乳化炸药基质稳定性能的影响[D]. 淮南: 安徽理工大学, 2023.
CHEN H N. Effect of acylated phospholipid emulsifier on properties of field mixed emulsion explosive [D]. Huainan: Anhui University of Science and Technology, 2023.
[7]吴攀宇. 内相粒径对现场混装乳化炸药稳定性的影响[D]. 淮南: 安徽理工大学, 2022.
WU P Y. Effect of internal phase particle size on the stability of field mixed emulsion explosive [D]. Huainan: Anhui University of Science and Technology, 2022.
[8]张阳, 王利军, 龚兵, 等. 乳化炸药现场混装技术在掘进爆破作业中的优势浅析[J]. 中国矿业, 2022, 31(增刊1): 376-380.
ZHANG Y, WANG L J, GONG B, et al. Analysis on the advantages of emulsion explosives on-site mixing technology in excavation blasting [J]. China Mining Magazine, 2022, 31(Supply.1): 376-380.
[9]黄胜松, 赵明生, 张义平, 等. 水相pH对现场混装乳化炸药基质储存稳定性的影响研究[J].矿业研究与开发, 2020, 40(7): 111-114.
HUANG S S, ZHAO M S, ZHANG Y P, et al. Effect of pH value of aqueous phase on storage stability of on-site mixed emulsion explosives matrix [J]. Mining Research and Development, 2020, 40(7): 111-114.
[10]卢文川, 孟昭禹, 马军, 等. 乳化剂和油相材料对现场混装乳化炸药基质稳定性的影响[J].爆破器材, 2019, 48(6): 7-13.
LU W C, MENG Z Y, MA J, et al. Effects of emulsifier and oil on the stability of bulk emulsified explosive matrix [J]. Explosive Materials, 2019, 48(6): 7-13.
[11]武海英. 高分子乳化剂对现场混装乳化炸药稳定性的影响[D]. 北京: 北京理工大学, 2016.
WU H Y. Effect of polymer emulsifier on stability of site-mixed emulsified explosives [D]. Beijing: Beijing Institute of Technology, 2016.
[12]宋家良. 乳化炸药的几何稳定性理论研究[C]//第2届全国煤矿安全生产论坛文集. 2006: 262-265.
[13]MCCLEMENTS D J. Critical review of techniques and methodologies for characterization of emulsion stability[J]. Critical Reviews in Food Science and Nutrition, 2007, 47(7): 611-649.
[14]BIBETTE J, LEAL-CALDERON F, SCHMITT V, et al. Emulsion science: basic principle. An overview [M]. Berlin, Heidelberg: Springer Berlin Heidelberg, 2002.
[15]张功震,何志伟, 冉宪文, 等. ANPyO@PDA复合材料的制备、表征及热分解性能[J].高压物理学报, 2023, 37(6): 063402.
ZHANG G Z, HE Z W, RAN X W, et al. Preparation, characterization and thermal decomposition properties of ANPy@PDA composites [J]. Chinese Journal of High Pressure Physics, 2023, 37(6): 063402.

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备注/Memo

备注/Memo:
收稿日期:2024-12-13
基金项目:巴里坤县科学研究与技术开发计划(blkkj23-01);新疆维吾尔自治区“天池英才”领军人才计划[XJTCYC2023(2)-BLMB2];新疆维吾尔自治区“天池英才”青年博士计划[XJTCYC2022(1)-BLMB1]
第一作者:王光兵(1988—),男,高级工程师,从事现场混装炸药性能及矿山工程应用研究。E-mail: 18299366929@163.com
通信作者:吴红波(1975—),男,博士,教授,主要从事爆破器材与安全研究。E-mail: hbwu@aust.edu.cn
更新日期/Last Update: 2025-12-09