[1]徐敏潇①,吕萍②,陈虎③,等.聚异丁烯丁二酸酯类乳化剂对乳化炸药稳定性的影响[J].爆破器材,2026,55(02):1-7.[doi:10.3969/j.issn.1001-8352.2026.02.001]
　XU Minxiao,L Ping,CHEN Hu,et al.Influence of Polyisobutylene Succinate Emulsifiers on the Stability of Emulsion Explosives[J].EXPLOSIVE MATERIALS,2026,55(02):1-7.[doi:10.3969/j.issn.1001-8352.2026.02.001]
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聚异丁烯丁二酸酯类乳化剂对乳化炸药稳定性的影响()

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
55
期数:
2026年02
页码:
1-7
栏目:
基础理论
出版日期:
2026-04-13

文章信息/Info

Title:
Influence of Polyisobutylene Succinate Emulsifiers on the Stability of Emulsion Explosives
文章编号:
6000
作者:
徐敏潇①; 吕萍②; 陈虎③; 张凯铭③
①江苏警官学院警务指挥与战术系（江苏南京，210031）
②上海航天动力技术研究所（上海，200003）
③南京工程学院材料科学与工程学院（江苏南京，211167）
Author(s):
XU Minxiao①;  Lǔ Ping②;  CHEN Hu③;  ZHANG Kaiming③
① Department of Police Command and Tactics, Jiangsu Police Institute (Jiangsu Nanjing, 210031)
② Shanghai Aerospace Power Technology Research Institute (Shanghai, 200003)
③ School of Material Science and Engineering, Nanjing Institute of Technology (Jiangsu Nanjing, 211167)
关键词:
现场混装乳化炸药; 稳定性; 聚异丁烯丁二酸酯类乳化剂
分类号:
TQ560.7
DOI:
10.3969/j.issn.1001-8352.2026.02.001
文献标志码:
A
摘要:
研究了聚异丁烯丁二酸酯类乳化剂对混装车乳化炸药基质稳定性的影响。通过改变多元醇的类型,合成了4种具有相同疏水链长度、不同亲水基结构的聚异丁烯丁二酸酯类乳化剂。分析4种聚异丁烯丁二酸酯类乳化剂制备的乳化基质的静态稳定性、动态稳定性可知，聚异丁烯丁二酸酐(PIBSA)-聚乙二醇展现出了较好的乳化效果和改善乳化基质稳定性的能力，形成的乳化基质在静置储存、动态挤压后的黏度变化率分别为26%和9%。PIBSA -乙二醇、PIBSA -丙三醇、PIBSA-山梨醇制备的乳化基质静置储存后的黏度变化率分别为57%、 70%和33%；动态挤压后的黏度变化率分别为40%、 54%和22%。PIBSA -聚乙二醇制备的乳化基质的黏度变化率均低于其他3种乳化剂制备的乳化基质，且远低于目前常用的T152乳化剂制备的乳化基质（105%和59%）。为进一步探索聚异丁烯丁二酸酯类乳化剂在混装车乳化炸药中的应用提供了一定的技术基础。

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备注/Memo

备注/Memo:
收稿日期：2025-09-01
基金项目：国家自然科学基金青年基金(51604155)
第一作者：徐敏潇（1982—），男，副教授，主要从事火炸药及爆炸防控技术研究。E-mail: xuminxiao@163.com
通信作者：张凯铭（1983—）,男，副教授，主要从事工业炸药及含能材料技术研究。E-mail: cggzkm@163.com
更新日期/Last Update: 2026-04-10