[1]李玉艳①,徐森②,蒋榕培③,等.氧化亚氮基单元复合推进剂的燃烧热性能研究[J].爆破器材,2024,53(02):22-28.[doi:10.3969/j.issn.1001-8352.2024.02.004]
　LI Yuyan,XU Sen,JIANG Rongpei,et al.Study on Combustion Heat and Performances of Nitrous Oxide Based Composite Monopropellant[J].EXPLOSIVE MATERIALS,2024,53(02):22-28.[doi:10.3969/j.issn.1001-8352.2024.02.004]
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氧化亚氮基单元复合推进剂的燃烧热性能研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
53
期数:
2024年02
页码:
22-28
栏目:
基础理论
出版日期:
2024-04-03

文章信息/Info

Title:
Study on Combustion Heat and Performances of Nitrous Oxide Based Composite Monopropellant
文章编号:
5880
作者:
李玉艳①; 徐森②; 蒋榕培③; 李智鹏③
①常州大学安全科学与工程学院（江苏常州，213164）
②南京理工大学化学与化工学院（江苏南京，210094）
③北京航天试验技术研究所航天绿色推进剂研究与应用北京市重点实验室（北京，100074）
Author(s):
LI Yuyan①;  XU Sen②;  JIANG Rongpei③;  LI Zhipeng③
①School of Safety Engineering, Changzhou University (Jiangsu Changzhou, 213164)
②School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
③Beijing Key Laboratory of Research and Application for Aerospace Green Propellants, Beijing Institute of Aerospace Testing Technology (Beijing, 100074)
关键词:
氧化亚氮; 推进剂; 燃烧热; 添加剂
Keywords:
nitrous oxide;  propellant;  combustion heat;  additive
分类号:
TQ560.7； V512+.3
DOI:
10.3969/j.issn.1001-8352.2024.02.004
文献标志码:
A
摘要:
为了研究氧化亚氮基单元复合推进剂的燃烧热性能，以几种典型推进剂配方为研究对象，利用Hess定律对燃烧热进行了理论计算。采用全自动绝热量热仪（氧弹）和恒温式爆热量热仪（爆热弹）对燃烧热进行了实验，探讨了不同添加剂与容器几何尺寸对部分配方燃烧热的影响规律。结果表明：相同条件下，N2O/C2H4、N2O/C3H8、N2O/NH3的燃烧热依次减小；随着CO2含量的增加，N2O/C2H4的燃烧热逐渐减小；随着C3H8含量的增加，爆热弹中N2O/NH3的燃烧热先增大、后减小，C3H8质量分数为3.8%时，燃烧热最大；容器几何尺寸增大，燃烧热呈增大趋势。
Abstract:
In order to study the combustion heat performance of nitrous oxide based composite monopropellants, several typical propellant formulations were taken as research objects, and theoretical calculations of combustion heat were carried out using Hess law. An automatic adiabatic calorimeter (oxygen bomb) and a constant temperature explosive heat calorimeter (detonation bomb) were used to investigate the influence of different additives and container geometry on the combustion heat of some formulations. The results show that, under the same conditions, the combustion heat of N2O/C2H4, N2O/C3H8 and N2O/NH3 decreases sequentially. With the increase of CO2 content, the combustion hea of N2O/C2H4?decreases gradually. With the increase of C3H8 content, the combustion heat of N2O/NH3 increases first and then decreases, and it reaches the maximum when the mass fraction of C3H8 is 3.8%. The combustion heat increases with the increase of the container geometry size.

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备注/Memo

备注/Memo:
收稿日期：2023-09-20
基金项目：常州市科技局应用基础研究计划项目（CJ20235032）
第一作者：李玉艳（1985—），女，博士研究生，主要从事推进剂安全性能相关研究。E-mail: lyysyf@cczu.edu.cn
通信作者：徐森（1981—），男，教授，主要从事含能材料相关研究。E-mail: xusen@njust.edu.cn
更新日期/Last Update: 2024-04-02