[1]韩明浩①,刘威①,张联社②,等.废旧HTPB固体推进剂转化制备乳化炸药的配方设计[J].爆破器材,2023,52(06):27-33.[doi:10.3969/j.issn.1001-8352.2023.06.005]
　HAN Minghao,LIU Wei,ZHANG Lianshe,et al.Formula Design of Emulsion Explosive Prepared from Waste HTPB Solid Propellant[J].EXPLOSIVE MATERIALS,2023,52(06):27-33.[doi:10.3969/j.issn.1001-8352.2023.06.005]
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废旧HTPB固体推进剂转化制备乳化炸药的配方设计()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
52
期数:
2023年06
页码:
27-33
栏目:
爆炸材料
出版日期:
2023-12-05

文章信息/Info

Title:
Formula Design of Emulsion Explosive Prepared from Waste HTPB Solid Propellant
文章编号:
5855
作者:
韩明浩①; 刘威①; 张联社②; 董辰华②; 王浩③; 沈文龙②
①中北大学环境与安全工程学院（山西太原，030051）
②中国融通资源开发集团有限公司（北京，100000）
③辽宁庆阳特种化工有限公司（辽宁辽阳，111001）
Author(s):
HAN Minghao①;  LIU Wei①;  ZHANG Lianshe②;  DONG Chenhua②;  WANG Hao③;  SHEN Wenlong②
①School of Environment and Safety Engineering, North University of China (Shanxi Taiyuan, 030051)
②China Rongtong Resources Development Group Co., Ltd. (Beijing, 100000)
③Qingyang Chemical Industry Co., Ltd. (Liaoning Liaoyang, 111001)
关键词:
废旧固体推进剂; 配方设计; 乳化炸药; 资源化再利用
Keywords:
wasted solid propellant;  formula design;  emulsion explosive;  resource reuse
分类号:
TQ560.9； X789
DOI:
10.3969/j.issn.1001-8352.2023.06.005
文献标志码:
A
摘要:
针对废旧固体推进剂绿色、安全、高效处理的问题，设计了废旧HTPB固体推进剂转化制备乳化炸药的基础配方，以实现资源化再利用的目的。假定化学式和撰写爆炸反应方程式,建立目标函数，根据工业炸药的一般性能确定约束条件，规划求解后得到转化制备的乳化炸药的最佳配方，并对不同固体推进剂添加量下转化制备的乳化炸药的爆热、爆速、爆温、爆容进行了理论计算。结果表明：当固体推进剂质量分数为24.62%、乳化基质质量分数为75.38%时，转化制备的乳化炸药的综合性能最佳，理论爆热为3 351.935 kJ/kg，爆速为5 182.02 m/s，爆温为2 728.81 K，爆容为919.59 L/kg。为废旧固体推进剂的资源化再利用提供了理论参考。
Abstract:
A basic formula for preparing converted emulsion explosives by waste solid propellants has been designed to achieve the goal of resource utilization of waste solid propellants. The objective function was established by calculating the assumed chemical formula and writing the explosion reaction equation. The constraint conditions were determined based on the general performance of industrial explosives. After planning and solving, the optimal formula for converted emulsion explosives was obtained. And theoretical calculations were conducted on the detonation heat, detonation velocity, detonation temperature, and detonation volume of converted emulsion explosives under different solid propellant additions. The results show that, when the mass fraction of solid propellant is 24.62% and the mass fraction of emulsion matrix is 75.38%, the comprehensive performance of converted emulsion explosive is the best. The theoretical detonation heat is 3 351.935 kJ/kg, the detonation velocity is 5 182.02 m/s, the detonation temperature is 2 728.81 K, and the detonation volume is 919.59 L/kg. It provides a theoretical reference for the resource reuse of waste solid propellants.

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备注/Memo

备注/Memo:
收稿日期：2023-06-20
第一作者：韩明浩（2001-），男，学士，主要从事工业炸药的制备与应用研究。E-mail：1466704537@qq.com
通信作者：刘威（1992-），男，博士，副教授，主要从事含能材料的制备与应用研究。E-mail:1104054142@st.nuc.edu.cn
更新日期/Last Update: 2023-12-04