[1]李婧①,潘永飞②,汪营磊②,等.绿色起爆药的研究进展[J].爆破器材,2019,48(04):1-10.[doi:10.3969/j.issn.1001-8352.2019.04.001]
 LI Jing,PAN Yongfei,WANG Yinglie,et al.Research Progress of Green Primary Explosive[J].EXPLOSIVE MATERIALS,2019,48(04):1-10.[doi:10.3969/j.issn.1001-8352.2019.04.001]
点击复制

绿色起爆药的研究进展()
分享到:

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
48
期数:
2019年04
页码:
1-10
栏目:
基础理论
出版日期:
2019-07-04

文章信息/Info

Title:
Research Progress of Green Primary Explosive
文章编号:
5357
作者:
李婧潘永飞汪营磊刘亚静
①中国兵器科学研究院(北京,100089)
②西安近代化学研究所(陕西西安,710065)
Author(s):
LI Jing PAN Yongfei WANG Yinglie LIU Yajing
① China Academy of Ordnance Science (Beijing, 100089)
② Xi’an Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
关键词:
绿色起爆药四唑类起爆药呋咱类起爆药叠氮类起爆药含能材料
Keywords:
green primary explosive tetrazole primary explosive furazan primary explosive azide primary explosive energetic material
分类号:
TJ55;O62
DOI:
10.3969/j.issn.1001-8352.2019.04.001
文献标志码:
A
摘要:
斯蒂芬酸铅和叠氮化铅等传统起爆药含有重金属,对环境污染大,其应用受到了很大的限制。绿色起爆药是一类不含铅、汞等重金属,具有一定安定性且爆轰性能优异的起爆药品种,是当前火工药剂研究领域里的热门课题之一。从绿色起爆药的合成、性能及应用等角度对其近年来的研究进展进行了综述,梳理了绿色起爆药研究的发展方向和趋势,指出今后研究的几点重要方向:努力探索、寻找新的合成线路,并优化其工艺条件,实现绿色起爆药安全化、规模化、稳定化制备;进一步建立、健全绿色起爆药理论设计、性能评估、演示验证等方面的规范和标准;继续开发新型绿色高能起爆药的设计、合成与应用基础研究,进一步改善起爆药的综合性能;设计和选择合适的配体与金属离子以及控制反应条件等因素,对系统研究高氮杂环配位化合物类绿色起爆药的结构与性能具有重要的意义。
Abstract:
Traditional primers such as lead azide and lead stefanate have great pollution to the environment due to their heavy metals, and their application is greatly limited. Green primer is a kind of primer that does not contain lead, mercury and other heavy metals. It has certain stability and explosive performance. It is one of the hot topics in the field of pyrotechnics research. In this paper, the research progress of green primary explosive in recent years is briefly reviewed from the perspectives of its formulation, performance and application. The development direction and trend of green primary explosive research are clarified. Several important directions for future research were pointed out. It needs to explore new synthetic routes and optimize its technological conditions, realize safe, large-scale and stable preparation of green primary explosive, further establish and perfect the norms and standards for theoretical design, performance evaluation, demonstration and verification of green primary explosive. It is needed to continue to develop the basic research on design, synthesis and application of new green high-energy primary explosive, further improve the comprehensive performance of primary explosive and realize its application in initiating explosive device as soon as possible. Design and selection of suitable ligands and metal ions and the control of reaction conditions are of great significance to the systematic study of the structure and properties of high nitrogen heterocyclic coordination compound green primary explosive.

参考文献/References:

[1]劳允亮,盛涤伦.火工药剂学[M].北京:北京理工大学出版社,2011.
?LAO Y L,SHENG D L.The science of initiating explosive and relative composition[M].Beijing: Beijing Institute of Technology Press,2011.
[2]王昕.绿色火炸药及相关技术的发展与应用[J].火炸药学报,2006,29(5):69-71.
WANG X. Development and application of green propellants and explosives and related technologies[J].Chinese Journal of Explosives & Propellants,2006,29(5):69-71.
[3]孙艳苓,颜冬林,朱顺官,等.5,5’-偶氮四唑锌的合成及表征[J].含能材料,2012,22(3):297-301.
SUN Y L,YAN D L,ZHU S G,et al.Synthesis and cha-racterization of zinc 5,5’-azotetrazolate[J].Chinese Journal of Energetic Materials,2012,22(3):297-301.
[4]盛涤伦,朱雅红,陈利魁.绿色火工含能材料的发展与评述[C]//第十六届中国科协年会.昆明,2014:1-9.
SHENG D L,ZHU Y H,CHEN L K. Development and comment on green loading materials for initiating devices[C]//The 16th China Association for Science and Technology Annual Meeting. Kunming,2014:1-9.
[5]FENDT T,FISCHER N,KLAPOTKE T M,et al.N-rich salts of 2-methyl-5-nitraminotetrazole: secondary explosives with low sensitivities[J].Inorganic Chemistry,2011,50(4):1447-1458.
[6]蒲彦利,盛涤伦,朱雅红,等. 新型起爆药5-硝基四唑亚铜工艺优化及性能研究[J].含能材料,2010,18(6): 654-659.
PU Y L, SHENG D L, ZHU Y H, et al. Synthesis process and property of new primary explosive copper nitrotetrazolate [J].Chinese Journal of Energetic Materials,2010,18(6):654-659.
[7]GILES J.Green explosives: collateral damage[J]. Nature,2004,427:580-581.
[8]HUYNH M H,HISKEY M A,MEYER T J,et al. Green primaries: environmentally friendly energetic complexes[J].Proceedings of the National Academy of Sciences of the United States of America,2006,103(14):5409-5412.
[9]KOCH E C. Chemistry of high-energy materials[J]. Propellants, Explosives, Pyrotechnics,2011, 36(2):187.
[10]BICHAY M, FRONABARGER J, WILLIAMS M, et al. Lead azide replacement program[C]//NDIA 49th Annual Fuze Conference. Miami,USA,2005.
[11]HUTSON S.Green explosiveis afriend ofthe each[J].New Scientist,2006(12):5-6.
[12]MEHTA N. Performance testing of green initiating explosives[C]//NDIA 49th Annual Fuze Conference. Miami, USA,2005.
[13]MEHTA N. Alternates to lead azide and lead based materials:green replacement[C]//The 36th International Pyrotechnics Seminar and Symposium. Rotterdam, the Netherlands, 2009.
[14]CHENG G.Development of a heavy metal-free electric detonator[C]//NDIA 48th Annual Fuze Conference. Charlotte, USA,2004.
[15]ROSTLUND S,VORDE C. Lead free pyrotechnic initiating composition based on energetic oxidizers[C]//The 38th International Annual Conference of ICT. Karlsruhe, Germany,2007.
[16]HUYNH V.Green primary explosives:5-nitrotetrazo-lato-N2-ferrate hierarchies[C]//Proceeding of the National Academy of Sciences(PNAS).Silicon Valley:Stanford University High Wire Press,2006.
[17]FISCHER D, KLAPOTKE T M, STIERSTORFER J. Synthesis and characterization of guanidinium difluoroiodate, [C(NH2)3+[IF2O2 and its evaluation as an ingredient in agent defeat weapons[J]. Journal of Inorganic and General Chemistry,2011,637(6):660-665.
[18]CARRINGTON D.Environmentally friendly explosives get ready for ignition [J].New Scientist, 2001(42):12-13.
[19]ILYUSHIN M A, TSELINSKY I V, ZHILIN A Y, et al. Coordination complexes as inorganic explosives for initiation systems[J]. Energetic Materials,2004,12(1):15-19.
[20]UGRJUMOV I A, ILYUSHIN M A, TSELINSKY I V. Study of nanostructured photosensitive primary explosives for laser initiation systems[C]//International Autumn Seminar on Propellants, Explosives & Pyrotecnics.Guilin, 2003.
[21]张裕峰,盛涤伦,马凤娥,等.新型起爆药双呋咱硝基酚钾盐的研究[J].含能材料,2007,15(6): 600-603.
?ZHANG Y F,SHENG D L,MA F E, et al. New primary explosive bisfuroxanonitrophenol potassium salt[J].Chinese Journal of Energetic Materials,2007,15(6):600-603.
[22]陈利魁,盛涤伦,朱雅红,等.FSFH共沉淀起爆药的合成及其主要性能[J].含能材料,2010,18(6):660-664.
CHEN L K,SHENG D L, ZHU Y H, et al. Synthesis and performance of coprecipitating primary explosive FSFH[J].Chinese Journal of Energetic Materials, 2010,18(6):660-664.
[23]柴玉萍,张同来,姚俊.双四唑盐的合成及表征[J].固体火箭技术,2007,3(3):248-252.
CHAI Y P, ZHANG T L, YAO J. Synthesis and characterization of bitetrazole salts[J].Journal of Solid Rocket Technology,2007,3(3):248-252.
[24]张同来.北京理工大学GTX起爆药技术通过科学成果鉴定[J].含能材料,2010,18(3):294.
[25]张光全.绿色四唑起爆药研究的最新进展[J].含能材料,2011,19(4):473-478.
ZHANG G Q. Recent progress in green tetrazoles primary explosives[J].Chinese Journal of Energetic Materials, 2011,19(4):473-478.
[26]MATYAS R, PACHMAN J. Primary explosives[M].Berlin Heidelberg:Springer-Verlag, 2013.
[27]HISKEY M A,HUYNH M H V.Primary explosives:US,7875725 B2[P].2011.
[28]谢兴兵.二水偶氮四唑四氨合铜(II)的合成与性能研究[D].南京:南京理工大学,2015.
?XIE X B. Synthesis and characterization of tetraamminecopper(II) azo tetrazolate dihydrate[D].Nanjing:Nanjing University of Science & Technology,2015.
[29]HUYNH M H, COBURN MD, MEYER T J, et al. Green primary explosives:5-nitrotetrazolato-N2-ferrate hierarchies[J].Proceedings of the National Academy of Sciences of the United States of America, 2006, 103(27):10322-10327.
[30]HUYNH M H.Lead-free primary explosives:US,0091029[P].2008.
[31]朱雅红,盛涤伦,王燕兰,等.环保起爆药四(5硝基四唑)?二水合铁(Ⅱ)化钠的合成和特性[J].含能材料,2012,20(6):726-730.
ZHU Y H, SHENG D L, WANG Y L, et al. Synthesis and performances of green primary explosive sodium tetra(5nitrotetrazolate) diaquate ferrate(Ⅱ)[J].Chinese Journal of Energetic Materials,2012,20(6):726-730.
[32]仝辉,盛涤伦.近十年单质起爆药的研究进展[C]//中国科协年会.长春,2017.
TONG H, SHENG D L. Research progress of elementary primers in recent ten years[C]//Annual Meeting of China Association for Science and Technology.Changchun,2017.
[33]GEISBERGER G, KLAPOTKE T M, STIERSTORFER J.Copper bis(1-methyl-5-nitriminotetrazolate):a promising new primary explosive[J].European Journal of Inorganic Chemistry,2007(30):4743-4750.
[34]FISCHER N,KLAPOTKE T M,STIERSTORFER J.Calcium 5-nitriminotetrazolate:a green replacement for lead azide in priming charges[J].Journal of Energetic Materials,2011,29(1):61-74.
[35]KLAPOTKE T M,SABATE C M, WELCH J M. Alkali metal 5-nitrotetrazolate salts:prospective replacements for service lead(II) azide in explosive initiators[J].Dalton Transactions,2008(45):6372-6380.
[36]FRONABARGER J W,WILLIAMS M D,SANBORN W B.Lead-free primary explosive composition and method of preparation:WO 2008048351(A2)[P].2008-04-24.
[37]MEHTA N,OYLER K,CHENG G ,et al.Synthesis of copper(I) 5-nitrotetrazolate:US 9440934[P].2016-09-13.
[38]董岩.多氨基多硝基苯并氧化呋咱及其金属配合物的合成与性能研究[D].南京:南京理工大学,2014.
DONG Y. Research on synthesis and performance of polyamino and polynitro benzofuroxan and their metal complex[D].Nanjing: Nanjing University of Science & Technology,2014. [39]MEHILAL A K S, PAWAR S, SIKDER N. Synthesis, characterization, thermal and explosive properties of 4,6-dinitrobenzofuroxan salts[J]. Journal of Hazardous Materials,2002,90(3):221-227.
[40]LUR’E B A,SINDITSKII V P, SMIRNOV S P.Thermal decomposition of 2,4-dinitrofuroxan and some of its compounds with metal hydroxides[J].Combustion, Explosion and Shock Waves, 2003, 39(5):534-543.
[41]盛涤伦,朱雅红,蒲彦利.新一代起爆药设计与合成研究进展[J].含能材料,2012,20(3):263-272.
SHENG D L, ZHU Y H, PU Y L. Development of a new-generation primary explosives designing and synthesis[J].Chinese Journal of Energetic Materials,2012,20(3):263-272.
[42]冯金玲,张建国,张同来,等.KDNBF形貌控制及其对热分解行为和感度的影响[J].物理化学学报,2010,26(10): 2613-2618.
?FENG J L, ZHANG J G, ZHANG T L, et al. Morphology control and its influence on the decomposition behavior and sensitivity of KDNBF[J].Acta Physico-Chimica Sinica, 2010,26(10):2613-2618.
[43]FRONABARGER J W,WILLIAMS M D,SANBORN W B,et al. KDNP:a lead free replacement for lead styphnate[J]. Propellants, Explosives, Pyrotechnics, 2011,36(5):459-470.
[44]TANG Y X, HE C L, MITCHELL L A, et al. Potassium 4,4’-bis(dinitromethy1)-3,3’-azofurazanate:a highly energetic 3D metal-organic framework as a promising primary[J]. Angewandte Chemie:International Edition,2016,55:5565-5567.
[45]任晓雪,彭翠枝.国外起爆药技术发展研究[J].飞航导弹, 2011(5):90-95.
REN X X,PENG C Z. Research on the development of foreign explosive drugs[J]. Winged Missiles Journal, 2011(5):90-95.
[46]CHENG G.Development of a heavy metal-free electric detonator[C]//NDIA 48th Annual Fuze Conference. Charlotte, USA, 2004.
[47]BICHAY M,HIRLINGER J .New primary explosives development for medium caliber stab detonators:PP1364[R].US Army ARDEC,2004.
[48]FISCHER N,FISCHER D,KLAPOTKE T M,et al.Pushing the limits of energetic materials the synthesis and characterization of dihydroxylammonium 5,5-bistetrazole-1,1-diolate[J].Journal of Material Chemistry,2012,22:20418-20422.
[49]王小军,苏强,张广源,等.二叠氮基乙二肟合成及表征[J].含能材料,2014,22(6):741-743.
WANG X J,SU Q, ZHANG G Y,et al. Synthesis and characterization of diazidoglyoxime[J]. Chinese Journal of Energetic Materials,2014,22(6):741-743.
[50]捷克开发出新型绿色起爆药[J].化学推进剂与高分子材料, 2014(3):91.
Czech developed a new green primary explosive [J]. Chemical Propellants & Polymeric Materials, 2014(3):91.
[51]史胜楠,倪德彬,庞丛丛,等.绿色起爆药2,4,6-三叠氮-1,3,5-三嗪的制备及性能研究[J].火工品,2017(4):33-36.
SHI S N, NI D B, PANG C C, et al. Synthesis and characterization of green primary explosive of 2,4,6-triazido-1,3,5-triazine(TAT)[J]. Initiators & Pyrotechnics,2017(4):33-36.
[52]MEHTA N,CHENG G,CORDARO E A,et al.Lead free detonator and composition:US 7981225 B1[P].2011-07-19.
[53]李志敏,张建国,张同来,等.硝基四唑及其高氮化合物[J].化学进展,2010,22(4):639-647.
?LI Z M, ZHANG J G, ZHANG T L, et al. Nitro-tetrazole and its high nitrogen-contented compounds[J].Progress in Chemistry,2010,22(4):639-647.
[54]蒲彦利,盛涤伦,朱雅红,等.新型起爆药5-硝基四唑亚铜工艺优化及性能研究[J].含能材料,2010,18(6):654-659.
PU Y L,SHENG D L, ZHU Y H, et al. Synthesis process and property of new primary explosive copper(I) nitrotetrazolate[J]. Chinese Journal of Energetic Mate-rials, 2010,18(6):654-659.
[55]PU Y L,SHENG D L.Synthesis, characterization and performance evaluation of copper(I) 5-nitrotetrazole (CuNT)[C]//2011 IASPEP. Nanjing, 2011.
[56]任晓雪,彭翠枝.国外新型火工药剂技术发展研究[J].爆破器材,2012, 41(2):20-23.
REN X X,PENG C Z. Analysis on the development of foreign pyrotechnic composition technology[J]. Explosive Materials, 2012, 41(2):20-23.
[57]LOPATA F G. Lead-free primer mix:US 5684268[P].1997.
[58]SANDERS V E,ASAY B W, FOLEY T J, et al.Combustion and reaction propagation on metastable intermolecular composites(MIC) [C]//The 33th International Pyrotechnics Seminar. Ford Collins, USA, 2006.
[59]CLEMENT D. Nanosiliconbased composite energetic materials: primary explosive or additive[C]//The 36th International Annual Conference of ICT.Karlsruhe, Germany, 2005.
[60]DU PLESSIS M. Nanoporous silicon explosive devices[J].Materials Science and Engineering,2008,B147:226-229.

相似文献/References:

[1]高耸松,谢兴兵,王元和.多种绿色起爆药的合成方法研究进展[J].爆破器材,2022,51(02):1.[doi:10.3969/j.issn.1001-8352.2022.02.001]
 GAO Songsong,XIE Xingbing,WANG Yuanhe.Research Progress on the Synthesis of Various Green Primary Explosives[J].EXPLOSIVE MATERIALS,2022,51(04):1.[doi:10.3969/j.issn.1001-8352.2022.02.001]

备注/Memo

备注/Memo:
收稿日期:2019-05-10
第一作者:李婧(1985-),女,博士,科研助理,研究方向为含能材料。E-mail:xiaojingzi238@126.com
更新日期/Last Update: 2019-07-04