[1]张程刚,胡艳,郭锐,等.填充叠氮化铜的碳纳米管纳米材料的制备研究[J].爆破器材,2017,46(01):1-5.[doi:10.3969/j.issn.1001-8352.2017.01.001]
　ZHANG Chenggang,HU Yan,GUO Rui,et al.Preparation of Copper Azide Filled Carbon Nanotubes[J].EXPLOSIVE MATERIALS,2017,46(01):1-5.[doi:10.3969/j.issn.1001-8352.2017.01.001]
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填充叠氮化铜的碳纳米管纳米材料的制备研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
46
期数:
2017年01
页码:
1-5
栏目:
基础理论
出版日期:
2017-01-10

文章信息/Info

Title:
Preparation of Copper Azide Filled Carbon Nanotubes
文章编号:
5119
作者:
张程刚; 胡艳; 郭锐; 叶迎华; 沈瑞琪
南京理工大学化工学院（江苏南京，210094）
Author(s):
ZHANG Chenggang;  HU Yan;  GUO Rui;  YE Yinghua;  SHEN Ruiqi
School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
碳纳米管; 叠氮化铜; 电化学沉积法
Keywords:
canbon nanotubes;  copper azide;  electrochemical deposition method
分类号:
TB332
DOI:
10.3969/j.issn.1001-8352.2017.01.001
文献标志码:
A
摘要:
首先采用电化学沉积法在碳纳米管中沉积铜，再利用叠氮化反应制备填充叠氮化铜的碳纳米管纳米材料。利用扫描电子显微镜（SEM）、透射电子显微镜（TEM）、高分辨透射电镜（HRTEM）和X射线能谱（EDS）对样品的微观形貌和晶体结构进行表征。结果表明，利用电化学沉积方法在定向碳纳米管中空管腔内合成了针状纳米枝晶铜，非连续的枝晶结构有利于后续的气固叠氮化反应，最终制备得到填充叠氮化铜晶体的碳纳米管纳米材料。
Abstract:
Copper azide filled carbon nanotubes were prepared by azide reaction on carbon nanotubes electrochemically deposited with copper. The morphology and crystal structure of the product were characterized by using scanning electron microscopy (SEM), transmission electron microscopy (TEM), high-resolution transmission electron microscopy (HRTEM) and X-ray energy spectrum (EDS). Results show that the formation of dendritic-coppers within the aligned carbon nanotubes by electrochemical deposition and the discontinuous distribution of dendritic structure would be in favor of further gas-solid azide reaction and the resultant copper azide filled carbon nanotubes.

参考文献/References:

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相似文献/References:

[1]石城宽,许湘宁,董成,等.内嵌叠氮化铜碳纳米管复合含能材料的制备与表征[J].爆破器材,2019,48(05):19.[doi:doi:10.3969/j.issn.1001-8352.2019.05.004]
　SHI Chengkuan,XU Xiangning,DONG Cheng,et al.Preparation and Characterization of a Composite Energetic Material of Carbon Nanotubes Embedded with Copper Azide[J].EXPLOSIVE MATERIALS,2019,48(01):19.[doi:doi:10.3969/j.issn.1001-8352.2019.05.004]

备注/Memo

备注/Memo:
收稿日期：2016-10-11
基金项目：江苏省自然科学基金青年基金项目（BK20140788）;预研基金项目（9140A05070114BQ02073）
作者简介：张程刚（1991－），男，硕士，主要从事碳纳米管等含能材料方面的研究。E-mail:1289788348@qq.com
通信作者：胡艳（1977－），女，副研究员，主要从事含能材料应用技术研究。E-mail:huyan@njust.edu.cn
更新日期/Last Update: 2017-01-09