[1]崔凤霞①,覃况②,石磊②,等.全氟己酮灭火剂高温热裂解性能研究[J].爆破器材,2015,44(06):5-8，14.[doi:10.3969/j.issn.1001-8352.2015.06.002]
　CUI Fengxia,QIN Kuang,SHI Lei,et al.Study on Thermal Pyrolysis of C6F-ketone Fire Extinguishant at High Temperatures[J].EXPLOSIVE MATERIALS,2015,44(06):5-8，14.[doi:10.3969/j.issn.1001-8352.2015.06.002]
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全氟己酮灭火剂高温热裂解性能研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
44
期数:
2015年06
页码:
5-8，14
栏目:
基础理论
出版日期:
2015-12-03

文章信息/Info

Title:
Study on Thermal Pyrolysis of C6F-ketone Fire Extinguishant at High Temperatures
文章编号:
4933
作者:
崔凤霞①; 覃况②; 石磊②; 张品②; 潘仁明②
①南京消防支队（江苏南京，210008）
②南京理工大学化工学院（江苏南京，210094）
Author(s):
CUI Fengxia①;  QIN Kuang②;  SHI Lei②;  ZHANG Pin②;  PAN Renming②
①Nanjing Firefighting Department (Jiangsu Nanjing, 210000)
②School of Chemical Engineering, Nanjing University of Science & Technology (Jiangsu Nanjing, 210094)
关键词:
灭火剂; 全氟己酮; 裂解; 裂解温度; 滞留时间; 气体产物
Keywords:
fire extinguishant;  C6F-ketone;  pyrolysis;  pyrolysis temperature;  residence time;  gaseous product
分类号:
TJ53+3；O621.2
DOI:
10.3969/j.issn.1001-8352.2015.06.002
文献标志码:
A
摘要:
基于GC、GC-MS和KM900手持式烟气分析仪测试手段，研究了全氟己酮在管式反应器中滞留时间为2 s和5 s、裂解温度为500~750 ℃时的热裂解规律。结果表明：全氟己酮在550 ℃时开始分解，超过650 ℃裂解剧烈；主要裂解气体产物为十氟丁烷、六氟丙烯和全氟异戊烷；随着裂解温度和滞留时间的增加，全氟己酮裂解程度加剧，十氟丁烷和六氟丙烯生成量增加，全氟异戊烷的生成量先增加后减少；值得重视的是全氟己酮高温热裂解时有剧毒气体全氟异丁烯和毒性气体一氧化碳产生。
Abstract:
The thermal pyrolysis of C6F-ketone was studied in a stainless tubular reactor under atmospheric pressure and attemperatures between 500 ℃ and 750 ℃ with residence times of 2 s and 5 s. The pyrolysis gaseous products were analyzedby on-line gas chromatography (GC), gas chromatographymass spectrometry (GC-MS) and KM900 handheld combustion analyzer. The results indicate that the thermal pyrolysis of C6F-ketone initiates at about 550 ℃ and becomes intense at 650 ℃. As both pyrolysis temperature and residence time increase, the thermal pyrolysis of C6F-ketone is triggered, which makes the concentration of C6F-ketone plummet, the yields of main gaseous products perflubutane, hexafluoropropylene increase and 1,1,1,2,2,3,4,4,4-nonafluoro-3-(trifluoromethyl) butane decrease after its peak. Besides, highly toxic gaseous products,perfluoroisobutene and carbon monoxide, were detected in the thermal pyrolysis process.

参考文献/References:

［1］王余胜，贾雯．新型洁净减火剂——氟化酮的性能分析［J］．亚洲消防，2006（1）：77-79.
［2］PAGLIARO J L, LINTERIS G T, SUNDERLAND P B, et al. Combustion inhibition and enhancement of premixed methaneair flames by halon replacements［J］. Combustion and Flame, 2015, 162(1): 41-49.
［3］BABUSHOK V I, LINTERIS G T, MEIER O C. Combustion properties of halogenated fire suppressants［J］. Combustion and Flame, 2012, 159(12): 3569-3575.
［4］LINTERIS G T, BABUSHOK V I, SUNDERLAND P B, et al. Unwanted combustion enhancement by C6F12O fire suppressant［J］. Proceedings of the Combustion Institute, 2013, 34(2): 2683-2690.
［5］ANDERSSON B, BLOMQVIST P. Experimental study of thermal breakdown products from halogenated extinguishing agents［J］. Fire Safety Journal， 2011, 46（3）:104-115.
［6］KIM A, CRAMPTON G. Performance of Novec1230 in electronic facility fire protection［C］//A Technical Working Conference Proceedings of SUPDET 2010.Orlando,Florida, 2010: 1-6.
［7］DITCH B D. Thermal decomposition products testing with 1,1,1,2,2,4,5,5,5 nonafluoro-4-trifluoromethyl pentan-3-one (C6Fketone) during fire extinguishing［D］. Worcester,Massachusetts: Worcester Polytechnic Institute, 2002.
［8］DITCH B D, RIVERS P, THOMAS S. A continuation of thermal decomposition product testing with C6F-ketone, increased concentrations［C］//Proceedings of Halon Options Technical Working Conference. Albuquerque, 2002.
［9］张品. 哈龙替代型含氟灭火剂高温热解特性研究［D］. 南京：南京理工大学, 2013.
ZHANG P. Study on the pyrolysis of the fluorinecontaining fire extinguishing agents as halon alternates ［D］.Nanjing:Nanjing University of Science & Techonolgy, 2103.
［10］SU J Z, KIM A K, KANABUSKAMINSKA M. FTIR spectroscopic measurement of halogenated compounds produced during fire suppression tests of two halon replacements［J］. Fire Safety Journal, 1998, 31(1): 1-17.
［11］ROBIN M L. Suppression of class a fires with HFC-227ea［J］. Process Safety Progress, 1998, 17(3): 209-212.
［12］WILLIAMS B A, LESPRANCE D M, FLEMING J W. Intermediate species profiles in lowpressure methane/oxygen flames inhibited by 2-H heptafluoropropane: comparison of experimental data with kinetic modeling［J］. Combustion and Flame, 2000, 120(1): 160-172.

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备注/Memo

备注/Memo:
收稿日期：2015-02-17
作者简介：崔凤霞（1965~），女，高级工程师，长期从事消防技术研究与管理。E-mail:1120461979@qq.com
通信作者：潘仁明(1963~)，男，博士，研究员，从事含能材料与消防方向科研。E-mail:prmnjust@126.com
更新日期/Last Update: 2015-11-30