[1]黄宇麒,万炜涵,张朋瑞,等.一步硝化法制备本质安全型双基药及其性能研究[J].爆破器材,2026,55(02):30-36.[doi:10.3969/j.issn.1001-8352.2026.02.005]
　HUANG Yuqi,WAN Weihan,ZHANG Pengrui,et al.Preparation and Performances of an Intrinsically Safe Double-Base Propellant by One-Step Nitration[J].EXPLOSIVE MATERIALS,2026,55(02):30-36.[doi:10.3969/j.issn.1001-8352.2026.02.005]
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一步硝化法制备本质安全型双基药及其性能研究()

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
55
期数:
2026年02
页码:
30-36
栏目:
爆炸材料
出版日期:
2026-04-13

文章信息/Info

Title:
Preparation and Performances of an Intrinsically Safe Double-Base Propellant by One-Step Nitration
文章编号:
6080
作者:
黄宇麒; 万炜涵; 张朋瑞; 田懿光; 王乃宏; 庞宇高; 郭传祥; 蔺向阳
南京理工大学化学与化工学院（江苏南京，210094）
Author(s):
HUANG Yuqi;  WAN Weihan;  ZHANG Pengrui;  TIAN Yiguang;  WANG Naihong;  PANG Yugao;  GUO Chuanxiang;  LIN Xiangyang
School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
关键词:
双基药; 一步法合成; 本质安全; 硝化纤维素; 硝化甘油
分类号:
TQ560.7
DOI:
10.3969/j.issn.1001-8352.2026.02.005
文献标志码:
A
摘要:
针对双基药（NC/NG）传统制备工艺中因游离硝化甘油（NG）积聚而存在的重大安全隐患问题，采用一种创新的一步法合成工艺，通过在低温混酸体系中实现纤维素与甘油的同步硝化及产物的原位吸收，制备了一种新型双基药。实验结果表明：该工艺从源头上杜绝了游离NG的生成与积聚；形成了与典型双基药化学结构一致的纯净、均质的NC/NG复合体系。性能表征证实，产物在保持与典型双基药相当的热分解特性与能量水平的同时，展现出更优的批次稳定性。通过同步硝化原位吸收形成的致密、无缺陷的微观结构，有效消除了可诱发意外的热点，可提升产品的安全性能。

参考文献/References:

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备注/Memo

备注/Memo:
收稿日期：2025-09-02
基金项目：国家级大学生创新创业训练计划项目（202410288024Z）
第一作者：黄宇麒（2004—），男，学士，主要从事含能聚合物的研究。E-mail: 2595936901@qq.com
通信作者：蔺向阳（1969—），男，博导，主要从事新型含能材料的研究。E-mail: linxiangyang@njust.edu.cn
更新日期/Last Update: 2026-04-10