[1]王景澄,谢中元,刘晶.双螺杆捏合方式制备的三基发射药的流变性研究[J].爆破器材,2025,54(01):1-6.[doi:10.3969/j.issn.1001-8352.2025.01.001]
　WANG Jingcheng,XIE Zhongyuan,LIU Jing.Study on Rheological Properties of TriBase Gun Propellants Prepared by the Twin-Screw Kneading Method[J].EXPLOSIVE MATERIALS,2025,54(01):1-6.[doi:10.3969/j.issn.1001-8352.2025.01.001]
点击复制

双螺杆捏合方式制备的三基发射药的流变性研究()
分享到：

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
54
期数:
2025年01
页码:
1-6
栏目:
基础理论
出版日期:
2025-01-09

文章信息/Info

Title:
Study on Rheological Properties of TriBase Gun Propellants Prepared by the Twin-Screw Kneading Method
文章编号:
5956
作者:
王景澄; 谢中元; 刘晶
西安近代化学研究所(陕西西安，710065)
Author(s):
WANG Jingcheng;  XIE Zhongyuan;  LIU Jing
Xi’an Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
关键词:
三基发射药; 双螺杆挤出机; 毛细管流变仪; 流变性
Keywords:
tri-base gun propellant;  twin-screw extruder;  capillary rheometer;  rheological property
分类号:
TQ560.7； TJ410.4
DOI:
10.3969/j.issn.1001-8352.2025.01.001
文献标志码:
A
摘要:
为掌握三基发射药连续化捏合工艺中药料的流变特性，提高工艺模型的准确性，按照三基发射药代料配方制备了预混药料，使用双螺杆挤出机对预混药料进行捏合，并通过专用双料筒毛细管流变仪测试捏合后药料的流变特性。分别改变双螺杆挤出机的螺杆转速和捏合温度、药料的固含量和溶剂比，分析以上变量对三基发射药流变学参数的影响规律。结果表明：双螺杆捏合后，药料的本构方程与Carreau-Yasuda本构模型拟合程度较高；一定范围内，螺杆转速或捏合温度的提高会使捏合后的药料的剪切黏度降低；同时，螺杆转速的提高会使药料的停留时间减少，而过短的停留时间会导致捏合后的药料的黏度上升；固含量的增加或溶剂比的减小会使捏合后的药料的剪切黏度增大，而黏度增大会使药料的停留时间增长，一定程度上使药料受到更充分的捏合作用。
Abstract:
In order to understand rheological properties of tri-base gun propellants in the continuous kneading process and improve the accuracy of the process model, a kind of pre-mixed propellant was prepared according to the formula of the tri-base gun propellant substitute. The pre-mixed propellant was kneaded using a twin-screw extruder, and rheological properties of the kneaded propellant were tested by the special double-barrel capillary rheometer. Screw speed and kneading temperature of the twin-screw extruder, the solid content and solvent ratio of the propellant were changed to analyze the influence of these variables on rheological parameters of the tribase gun propellant. The results show that after twin-screw kneading, the constitutive equation of the tested material fits well with Carreau-Yasuada constitutive model. Within a certain range, an increase in screw speed or kneading temperature will reduce the shear viscosity of the kneaded material. At the same time, increasing the screw speed will reduce the residence time of the material, and the excessively short residence time will lead to an increase in the viscosity of the kneaded material. An increase in solid content or a decrease in solvent ratio will increase the shear viscosity of the kneaded material, and an increase in viscosity will lead to an increase in the residence time of the material. To a certain extent, it can enable the material to be more thoroughly kneaded.

参考文献/References:

［1］刘晶, 谢中元, 王琼林, 等. 三基发射药单螺杆压伸模具流场仿真及实验验证［J］. 爆破器材, 2022, 51(1): 1-8.
LIU J, XIE Z Y, WANG Q L, et al. Simulation and experimental verification of flow field of single screw extrusion mold used in three-based gun propellant ［J］. Explosive Materials, 2022, 51(1): 1-8.
［2］黄振亚, 罗运军, 赵省向. 火炸药成型加工工艺学［M］. 北京: 国防工业出版社, 2020.
［3］郑双, 魏学涛, 魏伦, 等. 高能硝胺发射药流变性能研究［J］. 火工品, 2016(3): 35-38.
ZHENG S, WEI X T, WEI L, et al. Study on the rheological property of high energy nitramine propellant ［J］. Initiators & Pyrotechnics, 2016(3): 35-38.
［4］赵凯晨. 高黏度双料筒流变仪的研制与三基发射药流变性能的研究［D］. 太原: 中北大学, 2021.
［5］谢中元, 李萌, 赵凯晨, 等. 硝基胍发射药制备工艺过程中的流变本构方程研究［J］. 爆破器材, 2023, 52(6): 34-38.
XIE Z Y, LI M, ZHAO K C, et al. Rheological constitutive equation of nitroguanidine-based gun propellant during production ［J］. Explosive Materials, 2023, 52(6): 34-38.
［6］张丹丹, 何卫东. 硝基胍七孔发射药挤压成型过程的数值模拟［J］. 火炸药学报, 2015, 38(1): 82-86.
ZHANG D D, HE W D. Numerical simulation of 7-hole nitroguanidinebased gun propellant in extrusion forming process ［J］. Chinese Journal of Explosives & Propellants, 2015, 38(1): 82-86.
［7］马秀清, 金律, 张亚军, 等. 含能材料连续挤出技术的应用现状及发展［J］. 塑料, 2018, 47(5): 8-11.
?MA X Q, JIN L, ZHANG Y J, et al. Application status and development of continuous extrusion technology for energetic materials ［J］. Plastics, 2018, 47(5): 8-11.
［8］DOMBE G, MEHILAL D, BHONGALE C, et al. Application of twin screw extrusion for continuous processing of energetic materials ［J］. Central European Journal of Energetic Materials, 2015, 12(3): 507-522.
［9］OZKAN S, GEVGILILI H, KALYON D M, et al. Twin-screw extrusion of nano-alumina-based simulants of energetic formulations involving gel-based binders ［J］. Journal of Energetic Materials, 2007, 25(3): 173-201.
［10］韩民园, 张振伟, 李瑞勤, 等. 浅析双螺杆挤出工艺在火炸药研制中的安全问题［J］. 化学推进剂与高分子材料, 2020, 18(3): 31-35.
HAN M Y, ZHANG Z W, LI R Q, et al. Security problems of twin screw extrusion process in preparation of propellants and explosives ［J］. Chemical Propellants & Polymeric Materials, 2020, 18(3): 31-35.
［11］岳梦岩, 张军, 李明娟, 等. 锥形双螺杆加工含能材料熔融过程数值模拟［J］. 塑料, 2024, 53(1): 163-171.
YUE M Y, ZHANG J, LI M J, et al. Numerical simulation of melting process of energetic materials in conical twin-screw processing ［J］. Plastics, 2024, 53(1): 163-171.
［12］刘青烽, 马秀清. 同向双螺杆挤出过程不同螺杆构型的混合性能分析［J］. 橡塑技术与装备, 2006, 32(9): 1-6.
LIU Q F, MA X Q. A mixing performance analysis on the different screw configuration in the process of twin screw codirectional extrusion ［J］. China Rubber/Plastics Technology and Equipment, 2006, 32(9): 1-6.
［13］李雪珍, 薛平, 宋秀铎, 等. 含能材料加工过程模拟仿真的研究进展［J］. 塑料工业, 2021, 49(1): 1-6.
LI X Z, XUE P, SONG X D, et al. Research progress in numerical simulation of energetic material processing ［J］. China Plastics Industry, 2021, 49(1): 1-6.
［14］岳梦岩, 薛平, 宋秀铎, 等. 螺杆挤出技术加工火炸药的研究进展［J］.中国塑料, 2015, 29(12): 1-7.
YUE M Y, XUE P, SONG X D, et al. Research progress in screw extrusion technology of explosives ［J］. China Plastics, 2015, 29(12): 1-7.
［15］李成, 薛晓俊, 胡建树, 等. 啮合同向双螺杆挤出机结构参数对混合关键参量的影响［J］. 兵工学报, 2022, 43(10): 2640-2648.
LI C, XUE X J, HU J S, et al. Effects of structural parameters of intermeshing co-rotating twin screw extruders on key mixing parameters ［J］. Acta Armamentarii, 2022, 43(10): 2640-2648.
［16］孙振知, 金志明, 宋秀铎, 等. 基于超声波检测改性双基推进剂代料塑化程度的机理研究［J］. 固体火箭技术, 2020, 43(6): 782-787.
SUN Z Z, JIN Z M, SONG X D, et al. Study on mechanism of plasticizing degree of modified propellant substitutes based on ultrasonic testing ［J］. Journal of Solid Rocket Technology, 2020, 43(6): 782-787.
［17］万磊, 张骋昊, 顾晗, 等. SC-CO2辅助发射药代料挤出过程中物料流动性与制品冲击强度［J］. 含能材料, 2021, 29(9): 803-810.
WAN L, ZHANG C H, GU H, et al. Impact strength and rheological properties of propellant substitutes assisted with SC-CO2［J］. Chinese Journal of Energetic Materials, 2021, 29(9): 803-810.

相似文献/References:

[1]黄亚峰,王晓峰,王红星,等.火炸药双螺杆挤出工艺的研究现状与发展[J].爆破器材,2013,42(04):41.[doi:10.3969/j.issn.1001-8352.2013.04.010]
　HUANG Yafeng,WANG Xiaofeng,WANG Hongxing,et al.Research Status and Development of the Twin Screw Extrusion Technology on the propellants and explosives[J].EXPLOSIVE MATERIALS,2013,42(01):41.[doi:10.3969/j.issn.1001-8352.2013.04.010]
[2]刘晶①②,谢中元①②,王琼林①②,等.三基发射药单螺杆压伸模具流场仿真及实验验证[J].爆破器材,2022,51(01):1.[doi:10.3969/j.issn.1001-8352.2022.01.001]
　LIU Jing,XIE Zhongyuan,WANG Qionglin,et al.Simulation and Experimental Verification of Flow Field of Single Screw Extrusion Mold Used in Three-Based Gun Propellant[J].EXPLOSIVE MATERIALS,2022,51(01):1.[doi:10.3969/j.issn.1001-8352.2022.01.001]

备注/Memo

备注/Memo:
收稿日期：2024-07-15
第一作者：王景澄 (2000— )，男，硕士研究生，主要从事火炸药制备工艺及装备研究。E-mail:13633888877@163.com
通信作者：谢中元 (1981—)，男，博士，研究员，主要从事火炸药制备工艺研究。E-mail:18626324257@163.com
更新日期/Last Update: 2025-01-10