[1]杜宇轩①,司振宽①②,王帅③,等.含添加剂水雾抑灭单基药火焰的小尺度实验研究[J].爆破器材,2024,53(03):31-37.[doi:10.3969/j.issn.1001-8352.2024.03.005]
 DU Yuxuan,SI Zhenkuan,WANG Shuai,et al.Small-Scale Experimental Study on the Suppression of Single Base Propellant Flames by Water Mist Containing Additives[J].EXPLOSIVE MATERIALS,2024,53(03):31-37.[doi:10.3969/j.issn.1001-8352.2024.03.005]
点击复制

含添加剂水雾抑灭单基药火焰的小尺度实验研究()
分享到:

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
53
期数:
2024年03
页码:
31-37
栏目:
爆炸材料
出版日期:
2024-06-04

文章信息/Info

Title:
Small-Scale Experimental Study on the Suppression of Single Base Propellant Flames by Water Mist Containing Additives
文章编号:
5863
作者:
杜宇轩司振宽①②王帅杨满江李权威
①南京理工大学化学与化工学院(江苏南京,210094)
②中国航天科工集团伺服技术研究所(江苏南京,210006)
③中国舰船研究设计中心(湖北武汉,430064)
Author(s):
DU YuxuanSI Zhenkuan①②WANG ShuaiYANG ManjiangLI Quanwei
①School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
②Servo Technology Institute of China Aerospace Science and Industury Corporation (Jiangsu Nanjing, 210006)
③China Ship Development and Design Center (Hubei Wuhan, 430064)
关键词:
单基火药水雾抑灭性能灭火机理
Keywords:
single base propellant water mist fire suppression performance fire extinguishing mechanism
分类号:
TQ560.7
DOI:
10.3969/j.issn.1001-8352.2024.03.005
文献标志码:
A
摘要:
为探究含不同性质添加剂的水雾对单基火药燃烧抑灭性能的影响,在自主搭建的火药燃烧及灭火平台上开展纯水雾与含Na2SO3、FeCl2、K2CO?2024/6/3、KHCO3添加剂的水雾对单基火药燃烧抑灭性能的对比实验,研究灭火过程中温度、辐射热流、火焰形态等的变化。结果表明:含还原性(Na2SO3、FeCl2)和非还原性(K2CO3、KHCO3)添加剂的水雾抑灭性能明显优于纯水雾,灭火时间更短。含非还原性添加剂的水雾在低浓度下抑灭效果较差,当添加质量分数提升至3%以上时,抑灭效果显著提升;含还原性添加剂水雾对单基药的抑灭性能在各添加剂浓度下均优于含非还原性添加剂的水雾,且随着添加剂浓度的增大,抑灭性能表现出饱和性。
Abstract:
In order to investigate the influence of additives with different properties on the fire suppression performance of water mist on single base propellant, a comparative experiment of single base propellant combustion and suppression was conducted on a self-built platform. It compared the performance of pure water mist and water mist containing Na2SO3, FeCl2, K2CO3 and KHCO3 additives in suppressing the combustion of single base propellants. Changes in temperature, radiant heat flux, and flame morphology during the fire suppression process were studied. The results show that the fire suppression performances of water mist containing reducing additives (Na2SO3, FeCl2) or non-reducing additives (K2CO3, KHCO3) are significantly better than that of pure water mist, with shorter extinguishing time. The performances of water mist containing non-reducing additives in suppressing single base propellant fires is poor at low concentrations. When the mass fraction of nonreducing additives rises above 3%, the fire extinguishing ability is significantly improved. The fire suppression performances of water mist containing reducing additive are superior to that of water mist containing nonreducing additive at all concentrations. In addition, as the increase of the concentration of reducing additive, the fire suppression performance is saturated.

参考文献/References:

[1]罗运军, 李生华, 李国平, 等. 新型含能材料[M]. 北京: 国防工业出版社, 2015.
LUO Y J, LI S H, LI G P, et al. Novel engergetic materials[M]. Beijing: National Defence Industry Press, 2015.
[2]代淑兰. 火炸药燃烧与爆轰物理学[M]. 北京: 国防工业出版社, 2020.
[3]WELLS S P, CARR V, COZART K S. Advanced fire protection deluge system (AFPDS): Phase II report: AFRL-ML-TY-TR-2000-4521[R]. Tyndall AFB, FL, US: Air Force Research Laboratory, 2000.
[4]WELLS S. AFPDS bagged propellant fire suppression evaluations: AFRL-ML-TY-TR-2004-4528[R].Tyndall AFB, FL, US: Air Force Research Laboratory, 2004.
[5]DIERDORF D, HAWK J. Blast initiated deluge system: an ultra-high-speed fire suppression system: AFRL-ML-TY-TP-2006-4511[R]. Tyndall AFB, FL, US: Air Force Research Laboratory, 2006.
[6]HAWK J, CARR V J, Jr. Evaluation of Fike (trademark) Corporation’s explosion suppression system for ultra-high speed fire suppression applications: ADA 480288[R]. Springfield: NTIS, 2007.
[7]WILLAUER H D, ANANTH R, FARLEY J P, et al. Mitigation of TNT and Destex explosion effects using water mist [J]. Journal of Hazardous Materials, 2009, 165(1/2/3): 1068-1073.
[8]程山, 丁涛, 刘佳. 固体推进剂安全灭火问题的研究现状[J]. 化工中间体, 2013(4): 15-18.
CHENG S, DING T, LIU J. The current research status of the problems of solid propellant fire-fighting safety [J]. Chemical Intermediate, 2013(4): 15-18.
[9]陈战斌. 固体推进剂火灾灭火技术研究[D]. 南京:南京理工大学, 2010.
CHEN Z B. Study on extinguishing technology of the fire of solid propellant [D]. Nanjing: Nanjing University of Science and Technology, 2010.
[10]司振宽, 李权威, 杜宇轩. 水喷雾对NCNG双基火药燃烧的抑制作用[J]. 爆破器材, 2023, 52(3): 39-44.
SI Z K, LI Q W, DU Y X. Inhibitory effect of water spray on combustion of NCNG doublebase gunpowder[J]. Explosive Materials, 2023, 52(3): 39-44.
[11]卫欣欣, 胡双启, 董国强, 等. 水雾对黏塑性炸药PBXN-5燃烧的抑制作用研究[J]. 爆破器材, 2021, 50(6): 14-20.
WEI X X, HU S Q, DONG G Q, et al. Research on combustion inhibition of water mist on PBXN-5 [J]. Explosive Materials, 2021, 50(6): 14-20.
[12]KIDA H. Extinction of fires of liquid fuel with sprays of salt solutions[C]//Fire Research Abstracts and Reviews. Washington DC: The National Acadanies Press, 1969, 11: 212.
[13]CHOW W K, JIANG Z, LI S F, et al. Improving fire suppression of water mist by chemical additives[J]. PolymerPlastics Technology and Engineering, 2007, 46(1): 51-60.
[14]张天巍. 含钾盐添加剂细水雾的灭火有效性及机理研究[D]. 北京: 北京理工大学, 2017.
ZHANG T W. Fire-extinguishing performance and mechanism study on water mist with potassium additives[D]. Beijing: Beijing Institute of Technology, 2017.
[15]严启龙, 刘林林. 含能材料前沿导论[M]. 北京: 科学出版社, 2022.
[16]堵平, 廖昕, 王泽山. 表面处理对单基药燃烧性能的影响[J]. 含能材料, 2010, 18(3): 348-350.
DU P, LIAO X, WANG Z S. Effect of surface treatment on burning performance of single-base gun propellant[J]. Chinese Journal of Energetic Materials, 2010, 18(3): 348-350.
[17]LINTERIS G, RUMMINGER M, BABUSHOK V, et al. Final report: effective non-toxic metallic fire suppressants: NISTIR 6875[R]. Gaithersburg, MD, US: NIST, 2002.
[18]BABUSHOK V, TSANG W. Relative flame inhibition effectiveness of metallic compounds [J]. Chemical and Physical Processes in Combustion, 1997: 79-82.
[19]CHELLIAH H K, WANIGARATHNE P C, LENTATI A M, et al. Effect of sodium bicarbonate particle size on the extinction condition of non-premixed counterflow flames [J]. Combustion and Flame, 2003, 134(3): 261-272.
[20]LINTERIS G T, RUMMINGER M D, BABUSHOK V I. Catalytic inhibition of laminar flames by transition metal compounds [J]. Progress in Energy and Combustion Science, 2008, 34(3): 288-329.
[21]KING M D, YANG J C, CHIEN W S, et al. Evaporation of a small water droplet containing an additive[C]//Proceedings of the ASME National Heat Transfer Conference. Baltimore MD, US, 1997.
[22]CUI Q, CHANDRA S, MCCAHAN S. The effect of dissolving salts in water sprays used for quenching a hot surface: part 1, boiling of single droplets [J]. Journal of Heat Transfer: Transactions of the ASME, 2003, 125(2): 326-332.
[23]李光俊, 赵伟, 闫满利, 等. 一种结合湿法脱硫技术降低中小型工业燃煤锅炉烟气中氮氧化物的方法: CN104801160A [P]. 2015-07-29.
[24]李国平, 王晓青, 罗运军. 火炸药物理化学性能[M]. 北京: 国防工业出版社, 2020.
[25]KUBOTA N. Propellants and explosives : thermochemical aspects of combustion [M]. 2nd ed. Wiley-VCH, 2007.

相似文献/References:

[1]卫欣欣①②,胡双启①,董国强②,等.水雾对黏塑性炸药PBXN-5燃烧的抑制作用研究[J].爆破器材,2021,50(06):14.[doi:10.3969/j.issn.1001-8352.2021.06.003]
 WEI Xinxin,HU Shuangqi,DONG Guoqiang,et al.Research on Combustion Inhibition of Water Mist on PBXN-5[J].EXPLOSIVE MATERIALS,2021,50(03):14.[doi:10.3969/j.issn.1001-8352.2021.06.003]

备注/Memo

备注/Memo:
收稿日期:2023-07-13
第一作者:杜宇轩(1997—),男,硕士,主要从事含能材料火灾消防技术研究。E-mail:dyx9810@163.com?
通信作者:李权威(1983—),男,副教授,主要从事含能材料火灾防治原理及技术等方面的研究。E-mail:liqw83@163.com
更新日期/Last Update: 2024-06-03