[1]王栋嵘①,王锡杰①,廉鹏①,等.基于丙二腈的含能化合物的合成研究进展[J].爆破器材,2023,52(04):1-13,19.[doi:10.3969/j.issn.1001-8352.2023.04.001]
　WANG Dongrong,WANG Xijie,LIAN Peng,et al.Progress in Synthesis of Energetic Compounds Based on Malononitrile[J].EXPLOSIVE MATERIALS,2023,52(04):1-13,19.[doi:10.3969/j.issn.1001-8352.2023.04.001]
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基于丙二腈的含能化合物的合成研究进展()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
52
期数:
2023年04
页码:
1-13,19
栏目:
基础理论
出版日期:
2023-07-19

文章信息/Info

Title:
Progress in Synthesis of Energetic Compounds Based on Malononitrile
文章编号:
5811
作者:
王栋嵘①; 王锡杰①; 廉鹏①; 刘宁①②; 陈松①; 王伯周①②
①西安近代化学研究所（陕西西安，710065）
②氟氮化工资源高效开发与利用国家重点实验室（陕西西安，710065）
Author(s):
WANG Dongrong①;  WANG Xijie①;  LIAN Peng①;  LIU Ning①②;  CHEN Song①;  WANG Bozhou①②
①Modern Chemistry Research Institute (Shaanxi Xi’an, 710065)
②State Key Laboratory of Fluorine & Nitrogen Chemicals (Shaanxi Xi’an, 710065)
关键词:
丙二腈; 含能化合物; 合成; 反应机理; 爆轰性能
Keywords:
malononitrile;  energetic material;  synthesis;  reaction mechanism;  detonation performance
分类号:
TQ 560.6; TJ 55; O 621.3
DOI:
10.3969/j.issn.1001-8352.2023.04.001
文献标志码:
A
摘要:
丙二腈是一种重要的有机合成原料。介绍了丙二腈分子中亚甲基和氰基的反应特性。利用氰基的反应活性可以构建氮杂环母体骨架，可进一步赋予能量，设计并合成多种性能优异的含能化合物。丙二腈作为原料可以合成3, 4-二(3’-硝基呋咱-4’-基)氧化呋咱(DNTF)和1, 1’-二羟基-5, 5’-联四唑二羟胺盐(HATO)等新型含能材料。系统综述了构建呋咱、四唑、异呋咱、偶氮桥联、醚桥联等含氮含能化合物的合成方法。同时，重点介绍了典型含能化合物的爆轰性能等物理化学性能。对基于丙二腈的含能化合物的合成思路和方法进行总结并提出建议，为未来设计、合成具有自主知识产权且性能优异的新型含能材料提供参考。
Abstract:
Malononitrile is an important raw material for organic synthesis. The reactivity characteristics of methylene and cyan groups in malononitrile molecule were introduced. Reactivity of cyan group can be used to construct the nitrogen-heterocyclic parent skeleton, which can be further energized to design and synthesize a variety of energetic compounds with excellent properties. Malononitrile can be used as raw material to synthesize new energetic materials such as 3,4-dinitrofurazanfuroxan (DNTF) and dihydroxyl ammonium 5,5’-bistetrazole-1,1’-diolate (HATO). The synthetic methods for constructing nitrogen-containing energetic compounds such as furazan, tetrazole, isofurazan, azo-bridged and ether-bridged compounds were systematically reviewed. The physical and chemical properties of typical energetic compounds, such as detonation properties, were introduced emphatically. The synthesis ideas and methods of malononitrilebased energetic compounds were summarized and suggestions were made, which will provide reference for the future design and synthesis of new energetic materials with independent intellectual property rights and excellent performance.

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备注/Memo

备注/Memo:
收稿日期：2023-02-02
基金项目：国家自然科学基金（22175139）
第一作者：王栋嵘（1998－），男，硕士研究生，主要从事含能材料合成研究。E-mail：1025622085@qq.com：
通信作者：廉鹏（1977－），男，研究员，博导，主要从事含能材料合成工艺研究。E-mail：hmt13042298016@163.com
更新日期/Last Update: 2023-07-19