[1]李金鑫①,勾莉①,张争争①,等.CL-20基高爆热含铝压装混合炸药的研究[J].爆破器材,2020,49(03):33-36,42.[doi:10.3969/j.issn.1001-8352.2020.03.006]
 LI Jinxin,GOU Li,ZHANG Zhengzheng,et al.Study on CL-20 Based Aluminized PBX with High Detonation Heat[J].EXPLOSIVE MATERIALS,2020,49(03):33-36,42.[doi:10.3969/j.issn.1001-8352.2020.03.006]
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CL-20基高爆热含铝压装混合炸药的研究()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
49
期数:
2020年03
页码:
33-36,42
栏目:
爆炸材料
出版日期:
2020-05-22

文章信息/Info

Title:
Study on CL-20 Based Aluminized PBX with High Detonation Heat
文章编号:
5424
作者:
李金鑫勾莉张争争邹浩明①②
①甘肃银光化学工业集团有限公司含能材料分公司(甘肃白银,730900)
②北京理工大学化学与化工学院(北京,100081)
Author(s):
LI Jinxin GOU Li ZHANG Zhengzheng ZOU Haoming①②
① Gansu Yinguang Chemical Industry Group (Gansu Baiyin, 730900)
② School of Chemistry and Chemical Engineering, Beijing Institute of Technology (Beijing, 100081)
关键词:
CL-20高爆热含铝炸药工艺优化性能表征
Keywords:
CL-20 high detonation heat aluminized explosive process optimization performance characterization
分类号:
TJ55
DOI:
10.3969/j.issn.1001-8352.2020.03.006
文献标志码:
A
摘要:
为了提高CL-20基高爆热含铝压装混合炸药配方的成型性能,使用了新的黏结剂体系。通过工艺优化研究,获得了最佳的机械干混工艺条件:混合温度70~85 ℃,混合时间20~30 min;最佳的压药条件:压药温度85 ℃、比压3 300 kg/cm2、保压时间60 min。对新配方的爆热、真空安定性、爆发点和环境适应性进行了测试,结果显示,新配方具有很高的爆热,良好的热安全性、环境适应性和可靠性。新配方密度为2.041 g/cm3,爆热为8 834.3 J/g。
Abstract:
A new binder system was used to improve the forming performance of CL-20 based aluminized PBX explosive with high detonation heat. Through the study of process optimization, the optimal mechanical dry mixing process condition was obtained as duration of 20-30 min within the temperature range of 70-85 ℃ and the best pressuring operation was confirmed as holding time of 60 minutes at charge temperature of 85 ℃ and under specific pressure of 3 300 kg/cm2. Detonation heat, vacuum stability, explosion point and environmental adaptability of the new formula were tested. Results show that the new formula has high detonation heat, good thermal safety, environmental adaptability and reliability. Density and detonation heat of the new formula are 2.041g/cm3 and 8 834.3J/g respectively.

参考文献/References:

[1]WHELAN D J, SWINTON R, BOCKSTEINER G. Velocity of detonation and charge diameter in some RDX-driven heterogenous explosives: PBXW-115, PBXN-111, H-6 and Composition B [J]. Journal of Energetic Materials, 1996, 14(3/4): 257-270.
[2]GEISS D A. Development of IM grenade submunitions [C]//NDIA 2003 IM/EM Technology Symposium. Miami, FL: 2003.
[3]BALAS W, HATCH R. CL-20 aluminized PAX explosives formulation development, characterization and testing [C]//NDIA 2003 IM/EM Technology Symposium. Miami, FL: 2003.
[4]项传林, 吕荣华. 新型高能含铝炸药的研究[C]//中国兵工学会火炸药学术讨论会论文集. 北京: 中国兵工学会, 1994: 167-171.
XIANG C L, Lǔ R H. Research on new high energy aluminized explosive [C]//Proceedings of the Symposium on Explosives of the Chinese Ordnance Society. Beijing: Chinese Ordnance Society, 1994: 167-171.
[5]万晓智, 马宏昊, 沈兆武, 等. 新型含铝炸药水下爆炸性能研究[C]//2015中国力学大会论文集. 上海: 中国力学学会, 2015: 266.
[6]王世英, 李向东. 新型压装含铝炸药应用于大口径榴弹发射安全性模拟研究[J]. 计测技术, 2013, 33(增刊): 37-40.
[7]黄勇, 黄辉, 李尚斌, 等. PBX含铝炸药[Z]//中国工程物理研究院科技年报(2000). 绵阳: 中国工程物理研究院, 2000: 315-316.
HUANG Y, HUANG H, LI S B, et al. PBX aluminized explosive [Z]//The Annual Report of Science and Technology of China Academy of Engineering Physics (2000). Mianyang: China Academy of Engineering Physics, 2000: 315-316.
[8]张峰, 韩超, 周旭辉, 等. TATB基含铝PBX炸药成型性能[C]//2014年(第六届)含能材料与钝感弹药技术学术研讨会. 成都: 中国兵工学会爆炸与安全技术专业委员会, 2014: 152-155.
[9]LIU R, ZHOU Z, YIN Y, et al. Dynamic vacuum stability test method and investigation on vacuum thermal decomposition of HMX and CL-20 [J]. Thermochimica Acta, 2012, 537(3): 13-19.
[10]邹浩明, 陈树森, 李鑫, 等. 一种CL-20 基PBX 炸药的热分析及热危险性评估[C]//2016年第七届含能材料与钝感弹药技术研讨会. 绵阳: 《含能材料》编辑部, 2016: 743-746.
ZOU H M, CHEN S S, LI X, et al. Thermal analysis and risk assessment of a CL-20 based PBX explosive [C]//2016 The Seventh Academic Symposium on Energetic Materials and Insensitive Ammunition Technology. Mianyang: Editorial Department of Chinese Journal of Energetic Materials, 2016: 743-746.
[11]ZOU H M, CHEN S S, JIN S H, et al. Preparation, thermal investigation and detonation properties of ε-CL-20 based polymer bonded explosives with high energy and reduced sensitivity [J]. Materials Express, 2017, 7:199-208.
[12]LAN G C, JIN S H, JING B C, et al. Investigation into the temperature adaptability of HNIW-based PBXs [J]. Propellants, Explosives, Pyrotechnics, 2019, 44(3):327-336.
[13]陈鲁英, 赵省向, 杨培进, 等. CL-20炸药的包覆钝感研究[J]. 含能材料, 2006, 14(3): 171-173,199.
?CHEN L Y, ZHAO S X, YANG P J, et al. The coating and desensitization of CL-20 [J]. Chinese Journal of Energetic Materials, 2006, 14(3): 171-173,199.
[14]中国兵器工业总公司. 炸药试验方法:GJB 772A—1997[S]. 北京,1997.

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备注/Memo

备注/Memo:
收稿日期:2019-10-14
基金项目:专项基金(编号省略)
第一作者:李金鑫(1988-),工学学士,工程师,研究方向:混合炸药成型性工艺。E-mail: lijinxin441092388@126.com
通信作者:邹浩明(1988-),博士,研究方向:混合炸药配方及工艺。E-mail:shevchenkozou@sina.com
更新日期/Last Update: 2020-05-22