[1]李金懋①②,王 娟①②.含能增塑剂2,3-二羟甲基-2,3-二硝基-1,4-丁二醇四苯甲酸酯的合成及表征[J].爆破器材,2018,47(02):17-21.[doi:10.3969/j.issn.1001-8352.2018.02.004]
　LI Jinmao,WANG Juan.Synthesis and Characterization of Energetic Plasticizer-2,3-Bis(hydroxymethyl)-2,3-dinitro-1,4-butanediol Tetrabenzoate[J].EXPLOSIVE MATERIALS,2018,47(02):17-21.[doi:10.3969/j.issn.1001-8352.2018.02.004]
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含能增塑剂2,3-二羟甲基-2,3-二硝基-1,4-丁二醇四苯甲酸酯的合成及表征()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
47
期数:
2018年02
页码:
17-21
栏目:
基础理论
出版日期:
2018-03-23

文章信息/Info

Title:
Synthesis and Characterization of Energetic Plasticizer-2,3-Bis(hydroxymethyl)-2,3-dinitro-1,4-butanediol Tetrabenzoate
文章编号:
5201
作者:
李金懋①②; 王 娟①②
①湖北师范大学污染物分析与资源化湖北省重点实验室（湖北黄石，435002） 
②湖北师范大学化学化工学院（湖北黄石，435002）
Author(s):
LI Jinmao①②; WANG Juan①②
①Hubei Key Laboratory of Pollutant Analysis and Reuse Technology, Hubei Normal University (Hubei Huangshi, 435002)
②College of Chemistry and Chemical Engineering, Hubei Normal University (Hubei Huangshi, 435002)
关键词:
苯甲酸酯; 合成; 晶体结构; 表征
Keywords:
benzoate;  synthesized;  cystal structure;  characterization
分类号:
O621.3
DOI:
10.3969/j.issn.1001-8352.2018.02.004
文献标志码:
A
摘要:
以2,3-二羟甲基-2,3-二硝基-1,4-丁二醇（BHDB）和苯甲酸为原料，4-二甲氨基吡啶（DMAP）为活化剂，N,N＇二环己基碳二亚胺（DCC）为脱水剂，通过酯化反应得到含能增塑剂2,3-二羟甲基-2,3-二硝基-1,4-丁二醇四苯甲酸酯（BHDBTB），对产物进行了1H NMR、13C NMR、IR等结构表征。X-射线单晶衍射说明，BHDBTB晶系属于三斜晶系，空间群为P-1，Mr = 656.58。晶体的数据为：a=8.851 nm，b=9.373 nm，c=10.211 nm，α=82.61°，β=83.31°，γ=67.74°，V= 775.3 nm3，Z=2，Dc=1.406 g/cm3，R1=0.083 6，Rw2=0.086 1。
Abstract:
Synthesis of 2,3-bis(hydroxymethyl)-2,3-dinitro-1,4-butanediol tetrabenzoate (BHDBTB) with activator of 4-dimethylaminopyridine (DMAP) and dehydrant of N,N dicyclohexylcarbodiimide (DCC) has been carried out by esterification of 2,3- bis(hydroxymethyl)-2,3 dinitro -1,4-butanediol (BHDB) and benzoic acid. Structure of product was characterized by 1H NMR, 13C NMR and IR. The results of X-ray single-crystal diffraction show that BHDBTB belongs to triclinic system; the space group is P-1, Mr= 656.58. The crystal cell data of product were: a=8.851 nm，b=9.373 nm，c=10.211 nm，α=82.61°，β=83.31°，γ=67.74°，V=775.3 nm3，Z=2，Dc=1.406 g/cm3，R1=0.083 6，Rw2=0.086 1.

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备注/Memo

备注/Memo:
收稿日期：2017-08-06
基金项目：湖北省自然科学基金项目(2016CKC776)
作者简介：李金懋（1984－），男，硕士，实验师，主要从事材料学的研究。E-mail：jemolee@126.com
通信作者：王娟（1983－），女，博士，讲师，主要从事材料学的研究。E-mail：wangjuan830508@163.com
更新日期/Last Update: 2018-03-23