[1]施群荣①,刘祖亮①,成健①,等.LLM-105 Pb（Ⅱ）含能配合物的合成及对AP的热分解催化作用[J].爆破器材,2015,44(04):19-23.[doi:10.3969/j.issn.1001-8352.2015.04.005]
　SHI Qunrong,LIU Zuliang,CHENG Jian,et al.Synthesis of an Energetic Pb（Ⅱ）Complex of LLM-105 and Its Catalytic Effect on the Thermal Decomposition Behavior of AP[J].EXPLOSIVE MATERIALS,2015,44(04):19-23.[doi:10.3969/j.issn.1001-8352.2015.04.005]
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LLM-105 Pb（Ⅱ）含能配合物的合成及对AP的热分解催化作用()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
44
期数:
2015年04
页码:
19-23
栏目:
基础理论
出版日期:
2015-08-20

文章信息/Info

Title:
Synthesis of an Energetic Pb（Ⅱ）Complex of LLM-105 and Its Catalytic Effect on the Thermal Decomposition Behavior of AP
文章编号:
4901
作者:
施群荣①; 刘祖亮①; 成健①; 赵凤起②; 徐司雨②; 沈盼盼①
①南京理工大学化工学院（江苏南京，210094）
②西安近代化学研究所（陕西西安，710065）
Author(s):
SHI Qunrong①;  LIU Zuliang①;  CHENG Jian①; ZHAO Fengqi②;  XU Siyu②;  SHEN Panpan①
①School of Chemical Engineering, Nanjing University of Science and Technology (Jiangsu Nanjing, 210094)
②Xian Modern Chemistry Research Institute (Shaanxi Xian, 710065)
关键词:
2; 6-二氨基-3; 5-二硝基吡嗪-1-氧化物（LLM-105）; 含能配合物; 热分解行为; 高氯酸铵（AP）; 催化
Keywords:
2;  6-diamino-3;  5-dinitropyrazine-1-oxide(LLM-105);  energetic complex;  thermal decomposition behavior;  ammonium perchlorate(AP);  catalytic effect
分类号:
O69
DOI:
10.3969/j.issn.1001-8352.2015.04.005
文献标志码:
A
摘要:
合成了2,6-二氨基-3,5-二硝基吡嗪-1-氧化物（LLM-105）Pb（Ⅱ）含能配合物，采用FT-IR和元素分析表征并分析了其结构，该含能盐分子式为Pb(C4H2N6O5)。 测试了LLM-105 Pb（Ⅱ）含能配合物的撞击感度和摩擦感度，感度值分别为102 cm和18%。采用TG-DTG和DSC技术研究了LLM-105 Pb（Ⅱ）含能配合物的热分解行为，配合物有一个分解放热峰，峰温为240.7 ℃，热分解剩余残渣量为56.2%。采用TG-DTG和DSC技术研究了LLM-105 Pb（Ⅱ）含能配合物对高氯酸铵（AP）热分解的催化作用，结果表明：LLM-105 Pb（Ⅱ）含能配合物可使AP热分解速度加快，高温分解峰温提前63.8 ℃，对AP的热分解具有良好的催化效果。
Abstract:
An energetic Pb（Ⅱ） complex of 2,6-diamino-3,5-dinitropyrazine-1-oxide (LLM-105) was synthesized, and its structure was characterized with FT-IR spectroscopy and elemental analysis. The chemical composition of Pb（Ⅱ） complex of LLM-105 can be recognized as Pb (C4H2N6O5). Impact sensitivity and friction sensitivity of Pb（Ⅱ） complex of LLM-105 is 102 cm and 18%, respectively. The thermal decomposition process of the title complex and catalytic effect of Pb（Ⅱ）complex of LLM-105 on the thermal decomposition of ammonium perchlorate (AP) was studied by means of the TG, DTG and DSC. The energetic complex presents one violent exothermic peak (240.7 ℃) with 56.2% residues. Measurements show that the energetic complex could accelerate the thermal decomposition of AP for which the decomposition temperature is reduced by 63.8 ℃. The energetic complex has a good catalytic effect on the thermal decomposition of AP.

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备注/Memo

备注/Memo:
收稿日期：2014-12-15
基金项目：国家预研项目(62201070102) 
作者简介：施群荣（1983~ ），男，助理研究员，主要从事含能材料的研究。E-mail：shiqunrong@163.com
通信作者：刘祖亮（1951~ ），男，博导，研究员，主要从事含能材料、化学工艺等研究。E-mail：liuzuliang302@163.com
更新日期/Last Update: 2015-06-26