[1]裴江峰①,赵凤起①,焦建设②,等.含金属氢化物的p(BAMO-AMMO)基推进剂能量特性[J].爆破器材,2014,43(04):11-15.[doi:10.3969/j.issn.1001-8352.2014.04.003]
　PEI Jiangfeng,ZHAO Fengqi,JIAO Jianshe,et al.Energetic Characteristics of BAMOAMMO Based Propellants Containing Different Metal Hydride[J].EXPLOSIVE MATERIALS,2014,43(04):11-15.[doi:10.3969/j.issn.1001-8352.2014.04.003]
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含金属氢化物的p(BAMO-AMMO)基推进剂能量特性()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
43
期数:
2014年04
页码:
11-15
栏目:
基础理论
出版日期:
2014-08-20

文章信息/Info

Title:
Energetic Characteristics of BAMOAMMO Based Propellants Containing Different Metal Hydride
文章编号:
4814
作者:
裴江峰①; 赵凤起①; 焦建设②; 李猛①; 徐司雨①; 陈俊波①
①西安近代化学研究所燃烧与爆炸技术重点实验室(陕西西安,710065)
②炮兵防空兵装备技术研究所(北京,100012)
Author(s):
PEI Jiangfeng①;  ZHAO Fengqi①;  JIAO Jianshe②;  LI Meng①;  XU Siyu①;  CHEN Junbo①
①Science and Technology on Combustion and Explosion Laboratory, Xi＇an Modern Chemistry Research Institute (Shaanxi Xi＇an, 710065)
② Equipment and Technologies Research Institute of FA and ADA (Beijing, 100012)
关键词:
金属氢化物; BAMOAMMO共聚物;  推进剂; 能量特性; 理论计算
Keywords:
metal hydride (MH);  p(BAMO-AMMO);  propellants;  energy characteristics;  theoretical calculation
分类号:
TQ562;V512
DOI:
10.3969/j.issn.1001-8352.2014.04.003
文献标志码:
A
摘要:
为了考察金属氢化物（MH）对3,3-二叠氮甲基氧杂环丁烷(BAMO)与3-甲基-3-叠氮甲氧基氧杂环丁烷(AMMO)嵌段共聚物p(BAMO-AMMO)基推进剂的能量特性影响，设计了高氯酸铵（AP）、MH、p(BAMO-AMMO)组成的三组元推进剂配方体系，计算了用不同的MH逐步取代AP时的标准理论比冲变化规律，同时计算并比较了含六硝基六氮杂异伍兹烷（CL-20）的四组元p(BAMO-AMMO)基推进剂配方体系的标准理论比冲。研究发现AlH3对提升推进剂能量效果最为明显，以其取代25%（质量分数）AP的三组元推进剂和取代20%（质量分数）AP的四组元推进剂能量分别达到最高值（2764.9 N?s/kg和2829.3 N?s/kg）；当AlH3完全取代某实际推进剂配方中的Al时，推进剂的标准理论比冲提高了5.1%。
Abstract:
Formulas consisting of AP/MH/p(BAMO-AMMO) propellant was designed to study the effect of metal hydride (MH) on energetic characteristics of propellants based on copolymer of 3,3-bis(azidomethyl) oxetane (BAMO) and 3-azidomethyl-3- methyloxetane (AMMO). Through gradual substitution of MH for AP, the effect laws of MH to the theoretical specific impulse (ISP) of AP/MH/p(BAMO-AMMO) propellants was obtained.Results show that AlH3 was the most effective material for increasing the ISP of propellents. The ISP of AP/MH/p(BAMO-AMMO) propellant is up to 2764.9N?s/kg when 25% AP is replaced by AlH3, and the ISPof CL20/AP/MH/p(BAMO-AMMO) propellant is up to 2829.3N?s/kg when 20% AP is replaced. When all Al is redaced by AlH3, the ISP of a propellant containing p(BAMO-AMMO) is improved by 5.1%.

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备注/Memo

备注/Memo:
收稿日期：2014-05-15
基金项目：国家自然科学基金（No.2173163）
作者简介：裴江峰（1983~），男，博士研究生，工程师，主要从事固体火箭推进剂配方与工艺研究。E-mail：pjfpmt@163.com
通信作者：赵凤起（1963~），男，博士，研究员，主要从事含能材料研究。E-mail：npecc@163.com
更新日期/Last Update: 2014-08-25