[1]付小芬,马晓燕,刘晓亭,等.微乳液法制备CNTs/PbO、CNTs/CuO复合材料[J].爆破器材,2011,40(03):4-7.
　FU Xiaofen,MA Xiaoyan,LIU Xiaoting,et al.Perparation of Nanocomposite CNTs/PbO、CNTs/CuO via Microemulsion Process[J].EXPLOSIVE MATERIALS,2011,40(03):4-7.
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微乳液法制备CNTs/PbO、CNTs/CuO复合材料()
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《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
40
期数:
2011年03
页码:
4-7
栏目:
基础理论
出版日期:
2011-06-20

文章信息/Info

Title:
Perparation of Nanocomposite CNTs/PbO、CNTs/CuO via Microemulsion Process
文章编号:
4333
作者:
付小芬1; 马晓燕1; 刘晓亭2; 叶素艳3
（1.新时代（济南）民爆科技有限公司，山东济南250104；2.装甲兵工程学院 装备再制造技术国防科技重点实验室，北京100072；3.济宁华能制药厂，山东济宁272000）
Author(s):
FU Xiaofen1; MA Xiaoyan1; LIU Xiaoting2; YE Suya3
1.Minbao (Ji’nan) Energy and Equipment Co., Ltd. (Shandong Ji’nan, 250104) 2.National Key Laboratory for Remanufacturing, Academy of Armored Forces Engineering (Beijing, 100072)  3.Hua’neng Ji’ning Pharmaceuticals (Shandong Ji’ning, 272000)
关键词:
微乳液; 负载; 纳米催化剂
Keywords:
microemulsion;  load;  nano-catalyst
分类号:
TQ560.1
文献标志码:
A
摘要:
采用W/O型微乳液法制备出了CNTs/PbO和CNTs/CuO，利用电导率仪测量体系的溶水量，通过绘制三元相图研究了微乳液组成的表面活性剂和助表面活性剂的配比、温度以及盐的浓度等因素对W/O型微乳液相区的影响。分析得出最佳微乳液体系环己烷和活性剂的比为4：6，表面活性剂和助表面活性剂的比为2：3，反应温度为25℃。根据推进剂的成分，将一定量的燃烧催化剂和黑索今混合，通过热分析表征CNTs/PbO、CNTs/CuO对黑索今的催化热分解。结果表明，新的催化剂明显加快黑索今的热分解，分解峰位降低16.07℃。
Abstract:
CNTs/PbO and CNTs/CuO nanoparticles were prepared by the use of W/O microemulsion process, water content was mesured by conductivity meter, and the effect of some factors, such as the ratio of surfactant and cosurfactant, the temperature and the salt content, on the W/O type microemulsion phase was investigated by a ternary phase diagram. Analysis indicates a suitable microemulsion system is composed of cyclohexane and surfactant in the ratio of 46, surfactant and cosurfactant in 23, with the reaction temperature at 25℃. According to propellant components, a certain amount of combustion catalyst and RDX were mixed. The Characterization of the catalysis of CNTs/PbO、CNTs/CuO on thermal decomposition of RDX was done by thermal analysis. The results show that the new catalysts obviously accelerate the decomposition of RDX, and the peak temperature of decomposition reduce by 16.07℃.

参考文献/References:

［1］张海燕,陈红．国外关于纳米级固体推进剂材料的研究［J］．飞航导弹，2000 (8):59~61. ［2］Preckel R F．Plateau ballistics in nitrocellulode propellants ［J］．AIAA J, 1965, 3(2)：346~347.［3］Hewkin D J, Hicks J A, Powling J, et al．Thecombustion of nitricesterbased propellants:ballistic modification by lead compounds ［J］．Combustion Science and Technology, 1971(2):307~327.［4］张晓宏,龙村,王铁成,等．纳米级氧化铅对双基推进剂燃烧性能的研究［J］．火炸药学报，2002,25（2）：39~41. ［5］Kroto H W, Heath J R, O’Brien SC, et al．C60：Buckyministerfullerence［J］．Narure, 1985(318)：162~163.［6］Iijima S．Helical microrubules of grahitic carbon［J］．Narure, 1991(354)：56~58. ［7］李忠全,李玉莲.气体吸附法测定粉末比表面［J］.粉末冶金技术，1993(4)：53~58.

相似文献/References:

[1]开俊俊,申卫峰,雷鹏灿,等.乳胶基质微乳液低温快速发泡技术的研究[J].爆破器材,2013,42(02):31.[doi:10.3969/j.issn.1001-8352.2013.02.008]
　KAI Junjun,SHEN Weifeng,LEI Pengcan,et al.Research on the Low Temperature Rapid Foaming Technology of Microemulsion for Emulsion Matrix[J].EXPLOSIVE MATERIALS,2013,42(03):31.[doi:10.3969/j.issn.1001-8352.2013.02.008]

备注/Memo

备注/Memo:
收稿日期：2010-10-29 作者简介：付小芬（1979~），女，硕士，主要从事精细化工方面的研究。
更新日期/Last Update: 2011-06-27