[1]周建,李兆娜,张正金,等.高强度PBT叠氮四组元推进剂的制备工艺及力学性能[J].爆破器材,2026,55(03):18-23.[doi:10.3969/j.issn.1001-8352.2026.03.003]
 ZHOU Jian,LI Zhaona,ZHANG Zhengjin,et al.Preparation Process and Mechanical Properties of High-Strength PBT Azide Four-Component Propellant[J].EXPLOSIVE MATERIALS,2026,55(03):18-23.[doi:10.3969/j.issn.1001-8352.2026.03.003]
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高强度PBT叠氮四组元推进剂的制备工艺及力学性能()

《爆破器材》[ISSN:1001-8352/CN:32-1163/TJ]

卷:
55
期数:
2026年03
页码:
18-23
栏目:
基础理论
出版日期:
2026-06-13

文章信息/Info

Title:
Preparation Process and Mechanical Properties of High-Strength PBT Azide Four-Component Propellant
文章编号:
6093
作者:
周建李兆娜张正金屠仁举黄洪勇
上海航天动力技术研究所(浙江湖州,313000)
Author(s):
ZHOU Jian LI Zhaona ZHANG Zhengjin TU Renju HUANG Hongyong
Shanghai Space Propulsion Technology Research Institute (Zhejiang Huzhou, 313000)
关键词:
PBT高强度工艺性能力学性能
分类号:
V512
DOI:
10.3969/j.issn.1001-8352.2026.03.003
文献标志码:
A
摘要:
为解决PBT叠氮四组元推进剂药浆工艺性能差、力学性能低的问题,研究了工艺助剂、网络调节剂种类等对推进剂工艺性能和力学性能的影响。结果表明:以WL-02为网络调节剂、添加工艺助剂GZ-1时,加固化剂前混合机的扭矩可降低60%,加固化剂后药浆的初始黏度为314.7 Pa·s,使用期超过3 h;以WL-02为网络调节剂、JH-1+JH-2为组合键合剂,固化参数为0.95~1.00、交联参数为0.3时,推进剂20 ℃的抗拉强度≥2 000 kPa,-50、 20、 70 ℃的伸长率≥25%。所制备的PBT叠氮推进剂具有良好的工艺性能和力学性能,可满足常规自由装填结构发动机装药需求。

参考文献/References:

[1]韩晓娟, 苏昌银, 李雪飞, 等. 低燃速高固体含量HTPB推进剂[J]. 固体火箭技术, 2020, 43(3): 290-295.

HAN X J, SU C Y, LI X F, et al. HTPB propellant with low burning rate and high solid content [J]. Journal of Solid Rocket Technology, 2020, 43(3): 290-295.
[2]刘长宝, 刘云飞, 姚维尚.高固体含量丁羟推进剂性能研究[J]. 含能材料, 2007, 15(1): 42-46.
LIU C B, LIU Y F, YAO W S. Characteristics of HTPB propellant with high solid contents [J]. Chinese Journal of Energetic Materials, 2007, 15(1): 42-46.
[3]JIAN X X, HU Y W, ZHENG Q L. Effect of thermal processing temperature on the microphase separation and mechanical properties of BAMO/THF polyurethane [J]. Journal of Polymer Engineering, 2017, 37(2): 169-176.
[4]MENKE K, EISBLE S. Rocket propellants with reduced smoke and high burning rates [J]. Propellants, Explosives, Pyrotechnics, 1997, 22(3): 112-119.
[5]王旭, 徐森, 李苗苗, 等. 钝感氧化剂对PBT基推进剂低易损性的影响[J]. 兵器装备工程学报, 2022, 43 (6): 7-12, 18.
WANG X, XU S, LI M M, et al. Influence of insensitive oxidants on low vulnerability of PBT-based propellants[J]. Journal of Ordnance Equipment Engineering, 2022, 43 (6): 7-12, 18.
[6]沈业炜, 仉玉成, 童丽伦.中性键合剂在叠氮高能推进剂中应用工艺研究[J].上海航天, 2017, 34(6): 90-95.
SHEN Y W, ZHANG Y C, TONG L L.Study on application process of neutral polymeric bonding agent in high energy nitrine propellant [J].Aerospace Shanghai, 2017, 34(6): 90-95.
[7]沈业炜, 仉玉成, 童丽伦.PBT钝感高能推进剂高温力学性能调节技术研究[J].推进技术, 2018, 39(11): 2595-2600.
SHEN Y W, ZHANG Y C, TONG L L.Study on adjustment technology for high temperature mechanical properties of PBT insensitive high energy propellant [J].Journal of Propulsion Technology, 2018, 39(11): 2595-2600.
[8]张习龙, 甘露, 邓安华, 等. PBT基少烟推进剂配方性能研究[J].固体火箭技术, 2021, 44(1): 69-74.
ZHANG X L, GAN L, DENG A H, et al.Properties of reduced smoke propellant formulation based on PBT [J].Journal of Solid Rocket Technology, 2021, 44(1): 69-74.
[9]吴战武, 刘旭峰, 纪明卫, 等.少烟 PBT 推进剂制备及性能研究[J].爆破器材, 2019, 48(4): 17-22.
WU Z W, LIU X F, JI M W, et al. Preparation and properties of reduced smoke PBT propellant[J]. Explosive Materials, 2019, 48(4): 17-22.
[10]宋琴, 王艳萍, 廖菊平, 等.叠氮微烟推进剂宽温域力学性能研究[J].火炸药学报, 2021, 44(4): 521-525.
SONG Q, WANG Y P, LIAO J P, et al.Research on the mechanical property of azide low smoke propellant at broad temperature range [J].Chinese Journal of Explosives & Propellants, 2021, 44(4): 521-525.
[11]曾甲牙.固体填充剂对推进剂力学性能的影响[J].固体火箭技术, 2002, 25(1): 46-50.
ZENG J Y.Effect of solid filler on mechanical properties of propellants [J].Journal of Solid Rocket Technology, 2002, 25(1): 46-50.
[12]尹必文, 鲁国林, 吴京汉, 等.功能助剂对GAP微烟推进剂流变性能的影响[J].固体火箭技术, 2015, 38(5): 702-706.
YIN B W, LU G L, WU J H, et al.Study of slurry rheological behavior for GAP based minimum smoke composite propellant [J].Journal of Solid Rocket Technology, 2015, 38(5): 702-706.
[13]周水平, 吴芳, 唐根, 等.含能交联剂对PBT高能推进剂力学性能的影响[J].化学推进剂与高分子材料, 2016, 14(4): 54-59.
ZHOU S P, WU F, TANG G, et al.Influence of energetic crosslinking agents on mechanical performance of PBT-based high energy propellants [J].Chemical Propellants & Polymeric Materials, 2016, 14(4): 54-59.
[14]孟玲玲, 谢五喜, 蔚红建, 等.键合剂对硝酸酯增塑BAMO-THF推进剂力学性能的影响[J]. 化学推进剂与高分子材料, 2011, 9(2): 64-66.
MENG L L, XIE W X, YU H J, et al.Influence of bonding agents on mechanical properties of nitrate plasticized BAMO-THF propellants [J].Chemical Propellants & Polymeric Materials, 2011, 9(2): 64-66.
[15]李洋, 姜磊, 尹必文, 等. PBT 基钝感低特征信号推进剂的力学性能优化研究[J].固体火箭技术, 2021, 44 (4): 479-485.
LI Y, JIANG L, YIN B W, et al. Research on mechanical properties optimization of PBT-based insensitive low signature solid propellant [J]. Journal of Solid Rocket Technology, 2021, 44 (4): 479-485.

备注/Memo

备注/Memo:
收稿日期:2025-11-07
第一作者:周建(1981—),男,高级工程师,主要从事固体推进技术研究。E-mail: 727224965@qq.com
更新日期/Last Update: 2026-06-13